Search results for "Geochemistry"

Late Archaean foreland basin deposits, Belingwe greenstone belt, Zimbabwe

2001

Abstract The c. 2.65 Ga old sedimentary Cheshire Formation of the Belingwe greenstone belt (BDB), central Zimbabwe, has been studied in detail for the first time to shed some light on the much debated evolution of this classical belt. The Cheshire Formation rests sharply on a mafic volcanic unit (Zeederbergs Formation) and comprises a basal, eastward-sloping carbonate ramp sequence built of shallowing-upward, metre-scale sedimentary cycles. The cycles strongly resemble Proterozoic and Phanerozoic carbonate cycles and might have formed by small-scale eustatic sea level changes. The top of the carbonate ramp is represented by a karst surface. The carbonates are overlain by and grade laterally…

2020

Abstract. New Zealand's Alpine Fault is a large, plate-bounding strike-slip fault, which ruptures in large (Mw>8) earthquakes. We conducted field and laboratory analyses of fault rocks to assess its fault zone architecture. Results reveal that the Alpine Fault Zone has a complex geometry, comprising an anastomosing network of multiple slip planes that have accommodated different amounts of displacement. This contrasts with the previous perception of the Alpine Fault Zone, which assumes a single principal slip zone accommodated all displacement. This interpretation is supported by results of drilling projects and geophysical investigations. Furthermore, observations presented here show th…

Eclogites within the Menderes Massif / western Turkey

1997

Metagabbros in the core series of the Menderes Massif, for some time considered as post orogenic Miocene intrusives, revealed a strong poly-metamorphic history. The metagabbro bodies exhibit a pronounced zonation. Within their cores, igneous minerals are still preserved. Coronitic textures are interpreted as results of a high temperature, possibly granulitic overprint. The outer parts of the metagabbro bodies mostly consist of strongly to completely retrograded gamet-amphibo-lites, but occasionally contain relies of eclogites. Petrologic investigations confirmed a high pressure overprint and allowed preliminary P, T estimates (650 degrees C, equal to or greater than 1.3 GPa). The intensity …

The building blocks of continental crust: Evidence for a major change in the tectonic setting of continental growth at the end of the Archean

2013

Abstract Oceanic arcs are commonly cited as primary building blocks of continents, yet modern oceanic arcs are mostly subducted. Also, lithosphere buoyancy considerations show that oceanic arcs (even those with a felsic component) should readily subduct. With the exception of the Arabian–Nubian orogen, terranes in post-Archean accretionary orogens comprise  50%) produced in continental arcs. Felsic igneous rocks in oceanic arcs are depleted in incompatible elements compared to average continental crust and to felsic igneous rocks from continental arcs. They have lower Th/Yb, Nb/Yb, Sr/Y and La/Yb ratios, reflecting shallow mantle sources in which garnet did not exist in the restite during m…

Age, geodynamic setting, and mantle enrichment processes of a K-rich intrusion from the Meissen massif (northern Bohemian massif) and implications fo…

1997

The plutonic complex of the Meissen massif (northern margin of the Bohemian massif) comprises dioritic to mainly monzonitic and granitic rocks. The diorite to monzonite intrusions show major and trace element patterns typical for shoshonitic series. The chemical signatures of less crustally contaminated diorites are similar to arc-related shoshonitic rocks derived from continental lithospheric mantle (CLM) sources previously enriched by subduction of altered oceanic crust. Laser step heating 40Ar/39Ar analyses on actinolitic to edenitic amphiboles from geographically different occurrences of the monzonitic intrusion yielded concordant plateau ages as well as total gas ages ranging from 329.…

Andean Cenozoic volcanic centers reflect basement isotopic domains

1992

Isotopic data for Quaternary volcanic centers from lat 17.5° to 22°S in northern Chile provide evidence for crustal contributions to arc magma genesis in the central Andes and delineate basement domains. Crustal thickness, distance from trench, height of volcanic edifices above the seismically active subduction zone, and sediment supply to the trench are all constant along this segment of the arc. The only significant variable is crustal age (Paleozoic in the south, Proterozoic in the north). Pb isotopic compositions of Quaternary lavas in the northern sector are lower ( 206 Pb/ 204 Pb = 17.89-18.28) and Sr and O isotope ratios are less variable ( 87 Sr/ 86 Sr = 0.7058-0.7077, δ 18 O = +6.5…

Recycling and transport of continental material through the mantle wedge above subduction zones: A Caribbean example

2016

Abstract Estimates of global growth rates of continental crust critically depend upon knowledge of the rate at which crustal material is delivered back into the mantle at subduction zones and is then returned to the crust as a component of mantle-derived magma. Quantification of crustal recycling by subduction-related magmatism relies on indirect chemical and isotopic tracers and is hindered by the large range of potential melt sources (e.g., subducted oceanic crust and overlying chemical and clastic sediment, sub-arc lithospheric mantle, arc crust), whose composition may not be accurately known. There is also uncertainty about how crustal material is transferred from subducted lithosphere …

Long-time variation of soil CO2 fluxes at the summit crater of Vulcano (Italy)

2012

Here, we report the first continuous data of geochemical parameters acquired directly from the active summit crater of Vulcano. This approach provides a means to better investigate deep geochemical processes associated with the degassing system of Vulcano Island. In particular, we report on soil CO2 fluxes from the upper part of Vulcano, a closed-conduit volcano, from September 2007 to October 2010. Large variations in the soil CO2 and plume SO2 fluxes (order of magnitude), coinciding with other discontinuous geochemical parameters (CO2 concentrations in fumarole gas) and physical parameters (increase of shallow seismic activity and fumarole temperatures) have been recorded. The results fro…

Volcanic CO2 flux measurement at Campi Flegrei by tunable diode laser absorption spectroscopy

2014

Near-infrared room-temperature Tunable Diode Lasers (TDL) have recently found increased usage in atmospheric chemistry and air monitoring research, but applications in volcanology are still limited to a few examples. Here, we explored the potential of a commercial infrared laser unit (GasFinder 2.0 from Boreal Laser Ltd) for measurement of volcanic CO2 mixing ratios, and ultimately for estimating the volcanic CO2 flux. Our field tests were conducted at Campi Flegrei near Pozzuoli, Southern Italy, where the GasFinder was used during three campaigns in October 2012, January 2013 and May 2013 to repeatedly measure the path-integrated mixing ratios of CO2 along cross-sections of the atmospheric…

Mercury fluxes from volcanic and geothermal sources: An update

2015

OVSICORI, IAMC-CNR We review the state of knowledge on global volcanogenic Hg emissions to the atmosphere and present new data from seven active volcanoes (Poás, Rincón de la Vieja, Turrialba, Aso, Mutnovsky, Gorely and Etna) and two geothermal fields (Las Pailas and Las Hornillas). The variability of Hg contents (c. 4-125 ng m-3) measured in gaseous emissions reflects the dynamic nature of volcanic plumes, where the abundances of volatiles are determined by the physical nature of degassing and variable air dilution. Based on our dataset and previous work, we propose that an average Hg/SO2 plume mass ratio of c. 7.8 × 10-6 (± 1.5 × 10-6; 1 SE, n = 13) is best representative of open-conduit …