Search results for "Geochimica"
showing 10 items of 448 documents
Geochemical characterisation of the alkaline and hyperalkaline groundwater in the Othrys Ophiolite Massif, central Greece
2021
The complex geology of Greece includes two important parallel running ophiolitic belts. The Othrys Massif in central Greece belongs to the westernmost of them. In the current study, 33 water samples from cold hyperalkaline and hypothermal (T < 40°C) alkaline springs and 30 gas samples (either dissolved or free) were collected at 17 different sites in and around this wide ophiolite outcrop, aiming to determine the origin of fluids and evidence gas-water-rock interaction processes taking place in the area. Water samples were analysed for their chemical (major ions and trace elements) and isotope (d18O-H2O, d2H-H2O) composition. They can be subdivided into alkaline (pH <11) of both Mg-Ca…
Intercomparison of SO2 camera systems for imaging volcanic gas plumes
2015
Abstract SO 2 camera systems are increasingly being used to image volcanic gas plumes. The ability to derive SO 2 emission rates directly from the acquired imagery at high time resolution allows volcanic process studies that incorporate other high time-resolution datasets. Though the general principles behind the SO 2 camera have remained the same for a number of years, recent advances in CCD technology and an improved understanding of the physics behind the measurements have driven a continuous evolution of the camera systems. Here we present an intercomparison of seven different SO 2 cameras. In the first part of the experiment, the various technical designs are compared and the advantage…
Rapid oxidation of mercury (Hg) at volcanic vents: Insights from high temperature thermodynamic models of Mt Etna's emissions
2011
A major uncertainty regarding the environmental impacts of volcanic Hg is the extent to which Hg is deposited locally or transported globally. An important control on dispersion and deposition is the oxidation state of Hg compounds: Hg(0) is an inert, insoluble gas, while Hg(II) occurs as reactive gases or in particles, which deposit rapidly and proximally, near the volcanic vent. Using a new high temperature thermodynamic model, we show that although Hg in Etna's magmatic gases is almost entirely Hg(0) (i.e., gaseous elemental mercury), significant quantities of Hg(II) are likely formed at Etna's vents as gaseous HgCl2, when magmatic gases are cooled and oxidised by atmospheric gases. Thes…
Astronomical dating of two Pliocene alkaline volcanic ash layers in the Capo Rossello area (southern Sicily, Italy): implications for the beginning o…
2009
Key-words. - Sicily Channel rift, Biostratigraphy, Astronomical calibration, Pliocene, Volcanic ash layers. Abstract. - Two volcaniclastic ash layers (AL1 and AL2) are intercalated throughout the middle Pliocene sedimentary sequences of Punta Piccola and Capo Rossello exposed along the south coast of Sicily (Italy). Astronomical calibration of the Punta Piccola section provided an age of 2.676 Ma for the deposition of the AL1 layer. The high-resolution bio-cyclostratigraphy of the Capo Rossello section, in combination with detailed correlations with previously astrono- mically calibrated coeval sequences, provided an age of 2.225 Ma for the deposition of the AL2 layer. Mineralogical, petrog…
Interaction between the deep fluids and the shallow groundwaters on Vulcano island (Italy)
2001
The aim of this work is to study the interactions processes between the fluids of deep origin and the shallow groundwaters of the Vulcano Porto area. During 1995, 13 well waters were sampled three times (May, July and November) and analysed for major and some minor elements (B, Br and NH4) and for dissolved gases. The close relationship of these waters with the deep magmatic source is highlighted by the composition of the dissolved gases. Furthermore, the areal distribution of dissolved species is controlled mainly by the gas fluxes from depth and by the presence of a deeper thermal aquifer. The distribution of major anomalies in the parameters measured in the groundwaters, in fact, overlap…
Trace elements mobility in soils from the active hydrothermal area of Nisyros (Greece)
2014
Nisyros Island, Greece, is a stratovolcano known for its intense hydrothermal activity. On June 2013, during a multidisciplinary field campaign, soil samples were collected in the caldera area to determinate the main mineralogical paragenesis and to investigate the distribution of trace elements concentrations and the possible relationship to the contribution of deep originated fluids. Soil samples were analysed with XRD and for the chemical composition of their leachable (deionized water) and near total (microwave digestion) fraction both for major and trace elements. All data were compared to a local background soil. The results allow to divide the samples in 2 groups: Lakki Plain and Ste…
Volcanic CO2 flux measurement at Campi Flegrei by tunable diode laser absorption spectroscopy
2014
Near-infrared room-temperature Tunable Diode Lasers (TDL) have recently found increased usage in atmospheric chemistry and air monitoring research, but applications in volcanology are still limited to a few examples. Here, we explored the potential of a commercial infrared laser unit (GasFinder 2.0 from Boreal Laser Ltd) for measurement of volcanic CO2 mixing ratios, and ultimately for estimating the volcanic CO2 flux. Our field tests were conducted at Campi Flegrei near Pozzuoli, Southern Italy, where the GasFinder was used during three campaigns in October 2012, January 2013 and May 2013 to repeatedly measure the path-integrated mixing ratios of CO2 along cross-sections of the atmospheric…
CO2 release to the atmosphere from thermal springs of Sperchios Basin and northern Euboea (Greece): The contribution of “hidden” degassing
2020
Abstract Greece is a region characterised by intense geodynamic activity that favours the circulation of hydrothermal fluids in the crust transporting volatiles from either the deep crust or the mantle to the surface. Elevated heat flow values are detectable at Sperchios Basin and North Euboea (central Greece), two areas defined by a system of deeply rooted extensional faults and Quaternary volcanic activity. This setting contributed to the formation of numerous hydrothermal systems, which are mostly expressed as CO2-rich thermal springs with intense bubbling. The CO2 output from six bubbling pools has been determined by flux measurements with the use of the floating chamber method. The hig…
Active moss monitoring allows to identify and track distribution of metal(loid)s emitted from fumaroles on Vulcano Island, Italy
2014
Abstract Volatile metal(loid)s are known to be emitted from volcanoes worldwide. We tested the suitability of active moss monitoring for tracking volatile metal(loid)s released from the fumarolic field on Vulcano Island, Italy, and differentiated fumaroles from other sources of gaseous and particulate trace elements such as sea spray and soil. Metal(loid) accumulation on the mosses per day did depend neither on the state of the exposed moss (dead or living) nor exposure time (3, 6, or 9 weeks). After collection, mosses were digested with either HNO3/H2O2 or deionized water and analyzed by ICP-MS. While for most elements both extraction methods yielded similar concentrations, higher concentr…
Modelling groundwater processes in a carbonate catchment: a case study from the Madonie area (Northern Sicily)
2011
Abstract This study reports on the results of a hydrogeochemical survey carried out in the Madonie area, a carbonate massif located in Palermo Province, Northern Sicily. The large dataset (226 collected sites) is used to highlight the processes controlling the distribution of dissolved chemicals in groundwaters; and, more importantly, to develop a general model (based on reaction-path modelling, and using the EQ3/6 code) of rock–water reactions in a carbonate environment. The investigated groundwater samples have conductivity between 31.7 and 8220 μS/cm; their total dissolved solids (TDS) content is higher near the coast area, where the seawater contribution becomes important. Calcium and H…