Search results for "Glas"
showing 10 items of 1259 documents
Spark Plasma Sintering of Metallic Glasses
2019
Spark plasma sintering (SPS) of metallic glasses (MG) can be quite different from sintering crystalline metallic alloys. Indeed, MG behave differently with increasing temperature, as they encounter a glass transition and devitrification. Their shaping can thus be compared to what can be performed on thermoplastic polymers. SPS is a promising way to prepare bulk parts from amorphous powders, since it allows very fast heating and cooling rates. It gives an advantage to avoid or limit devitrification of the amorphous phase upon the thermal cycle. However, diffusion mechanisms, which generally control densification, are activated at temperatures that are not compatible with MG structural integr…
Reagent- and Metal-Free Anodic C-C Cross-Coupling of Aniline Derivatives.
2017
The dehydrogenative cross-coupling of aniline derivatives to 2,2′-diaminobiaryls is reported. The oxidation is carried out electrochemically, which avoids the use of metals and reagents. A large variety of biphenyldiamines were thus prepared. The best results were obtained when glassy carbon was used as the anode material. The electrosynthetic reaction is easily performed in an undivided cell at slightly elevated temperature. In addition, common amine protecting groups based on carboxylic acids were employed that can be selectively removed under mild conditions after the cross-coupling, which provides quick and efficient access to important building blocks featuring free amine moieties.
A Search for Ultra-high-energy Neutrinos from TXS 0506+056 Using the Pierre Auger Observatory
2020
Results of a search for ultra-high-energy neutrinos with the Pierre Auger Observatory from the direction of the blazar TXS 0506+056 are presented. They were obtained as part of the follow-up that stemmed from the detection of high-energy neutrinos and gamma rays with IceCube, Fermi-LAT, MAGIC, and other detectors of electromagnetic radiation in several bands. The Pierre Auger Observatory is sensitive to neutrinos in the energy range from 100 PeV to 100 EeV and in the zenith-angle range from θ = 60° to θ = 95°, where the zenith angle is measured from the vertical direction. No neutrinos from the direction of TXS 0506+056 have been found. The results were analyzed in three periods: One of 6 m…
New Insights into the Provenance of the Obsidian Fragments of the Island of Ustica (Palermo, Sicily)
2016
In this study we applied a multidisciplinary approach, coupling geophysical and geochemical measurements, to unveil the provenance of 170 obsidian flakes, collected on the volcanic island of Ustica (Sicily). On this island there are some prehistoric settlements dated from the Neolithic to the Middle Bronze Age. Despite not having geological outcrops of obsidian rocks, the countryside of Ustica is rich in fragments of this volcanic glass, imported from other source areas. The study of obsidian findings was carried out first through visual observations and density measurements. At least two different obsidian families have been distinguished, probably imported from Lipari and Pantelleria isla…
The first archaeometric characterization of obsidian artifacts from the archaeological site of Samshvilde (South Georgia, Caucasus)
2019
This paper presents the first results about the provenance of obsidian fragments recovered in the archaeological site of Samshvilde (South Georgia, Caucasus) with the aim to obtain knowledge related to the network distribution and procurement of obsidian in Georgia. The geochemical characterization of thirty archaeological finds was obtained by the LA-ICP-MS method, an almost non-destructive technique capable of chemically characterizing the volcanic glass. A comparison of geochemical results obtained on both archaeological artefacts and geological samples collected from Chikiani outcrop in Georgia, together with literature data of southern Caucasus and eastern Turkey, allowed us to define …
Suppressiveness of 18 composts against 7 pathosystems : variability in pathogen response
2006
International audience; Compost is often reported as a substrate that is able to suppress soilborne plant pathogens, but suppression varies according to the type of compost and pathosystem. Reports often deal with a single pathogen while in reality crops are attacked by multiple plant pathogens. The goal of the present study was to evaluate the disease suppression ability of a wide range of composts for a range of plant pathogens. This study was conducted by a consortium of researchers from several European countries. Composts originated from different countries and source materials including green and yard waste, straw, bark, biowaste and municipal sewage. Suppressiveness of compost-amende…
Cryptic taxa should have names: Reflections in the glasswort genusSalicornia(Amaranthaceae)
2012
Incongruence between morphology and molecules, i.e., genetic differentiation of lineages that are morphologically identical, or morphological variation among accessions sharing identical genotypes, has been increasingly reported and is most problematic in taxa with reduced morphologies. We here review and discuss these issues for plant taxonomy, taking Salicornia, one of the taxonomically most challenging genera of angiosperms, as a model. We argue in favour of a taxonomic system that remains as much 'workable' as possible for traditional morphology-based taxonomy, but avoids merging genetically widely divergent lineages despite their morphological similarity. Our revised classification of …
Anhydrobiosis: Inside yeast cells
2018
International audience; Under natural conditions yeast cells as well as other microorganisms are regularly subjected to the influence of severe drought, which leads to their serious dehydration. The dry seasons are then changed by rains and there is a restoration of normal water potential inside the cells. To survive such seasonal changes a lot of vegetative microbial cells, which belong to various genera and species, may be able to enter into a state of anhydrobiosis, in which their metabolism is temporarily and reversibly suspended or delayed. This evolutionarily developed adaptation to extreme conditions of the environment is widely used for practical goals - for conservation of microorg…
Liquid Crystal Phases in Suspensions of Charged Plate-Like Particles
2012
International audience; Anisotropic interactions in colloidal suspensions have recently emerged as a route for the design of new soft materials. Nonisotropic particles can form nematic, smectic, hexatic, and columnar liquid crystals. Although the formation of these phases is well rationalized when excluded volume is solely at play, the role of electrostatic interactions still remains unclear and even less so when particles present a charge heterogeneity, for example, clays. Here, we use Monte Carlo simulations of concentrated suspensions of charged disk-like particles to reveal the role of Coulomb interactions and charge anisotropy underlying liquid crystal formation and structures. We obse…
Failure maps to assess bearing performances of glass composite laminates
2018
Aim of this article is the assessment of the bearing mechanical performances of pin-loaded glass laminates as function of their geometrical configuration. To this concern, 32 specimens having different hole diameter (D), laminate width (W), and hole center to laminate free edge distance (E) have been tested under bearing conditions. The maximum bearing stress and the stress-displacement curves were analyzed as function both of hole to laminate free edge distance E and hole diameter D. Moreover, an experimental 2D failure map was created by placing the experimental results (i.e., the kind of failure mechanism occurred for each geometrical configuration) in the plane E/D versus W/D ratios. In…