Search results for "Grain Size"
showing 10 items of 131 documents
The formation of silica high temperature polymorphs from quartz: Influence of grain size and mineralising agents
2015
Abstract The formation of high-temperature silica polymorphs in presence of Na and K has been studied at various temperatures and soaking times, starting from quartzes of different grain size, ex situ as well as in situ. The results show that cristobalite and tridymite formation is strongly influenced by the nature and the amount of mineraliser added. In particular, K seems to discriminate more between the two structures, as it produces the largest observed amount of cristobalite. The disappearance of quartz can be controlled by the proper combination of mineraliser/temperature/time, which in turn control the amount and the type of polymorph formed, together with the amount of amorphous mat…
Quantification of pedogenic particles masked by geogenic magnetic fraction
2021
AbstractPedogenic magnetic fraction in soils is attributed to fine-grained particles, i.e. superparamagnetic grains. In the case of a strongly magnetic geogenic fraction, pedogenic magnetic contribution is hard to detect. To the best of our knowledge, detailed research into the masking of pedogenic superparamagnetic grains and quantification of this effect has not yet been carried out. The principal aim of our research is to quantify the influence of coarse-grained ferrimagnetic fraction on the detection of the superparamagnetic grains. In order to describe the masking phenomenon, volume and frequency-dependent magnetic susceptibility were determined on a set of laboratory prepared samples …
Elucidating the Effect of Bimodal Grain Size Distribution on Plasticity and Fracture Behavior of Polycrystalline Materials
2020
The refinement of grains in a polycrystalline material leads to an increase in strength but as a counterpart to a decrease in elongation to fracture. Different routes are proposed in the literature to try to overpass this strength-ductility dilemma, based on the combination of grains with highly contrasted sizes. In the simplest concept, coarse grains are used to provide relaxation locations for the highly stressed fine grains. In this work, a model bimodal polycrystalline system with a single coarse grain embedded in a matrix of fine grains is considered. Numerical full-field micro-mechanical analyses are performed to characterize the impact of this coarse grain on the stress-strain const…
Grain size effect and local disorder in polycrystalline relaxors via scanning probe microscopy
2007
Local piezoresponse of individual grains in polycrystalline Pb0.9125La0.0975(Zr0.65Ti0.35)0.976O3 (PLZT 9.75/65/35) relaxor ceramics is studied using the scanning probe microscopy (SPM) technique. The observed piezoelectric contrast consisting of irregular (labyrinth-type) polarization patterns is attributed to the compositional disorder and consequent charge imbalance caused by high La concentration. A measure of this disorder, the polarization correlation length ξ, is directly determined using an autocorrelation analysis function implemented in the SPM software. The analysis of the obtained images shows that ξ taken at the scale ~200 nm varies as a function of the position inside the grai…
Processing and properties of nanocrystalline Pb(Sc0.5Ta0.5)O3, Pb(Sc0.5Nb0.5)O3, Pb(Mg1/3Nb2/3)O3and Pb0.76Ca0.24TiO3films and ferroelectric/ relaxor…
2001
Abstract Thin films of relaxor materials, namely Pb(Sc0.5Ta0.5)O3 (PST), Pb(Sc0.5Nb0.5)O3 (PSN) and Pb(Mg1/3Nb2/3)O3 (PMN), and of Pb0.76Ca0.24TiO3 (PTC), which is a classical ferroelectric as bulk material, have been produced to examine whether nanocrystalline relaxor materials show influences in their properties if their grain size is reduced to dimensions known from their nanodomains and to investigate effects in a superlattice of nanocrystalline ferroelectric and relaxor films. At first amorphous films of the different materials were deposited onto a Ti/Pt coated Silicon (100) wafer by reactive rf-sputtering. Different grain sizes could be prepared by a controlled annealing process. The…
Processing and properties of nanocrystalline Pb(Sc0.5Ta0.5)O3, Pb(Sc0.5nb0.5)O3 and Pb(Mg1/3Nb2/3)O3 films produced by RF-sputtering from ceramic tar…
2000
Abstract Nanocrystalline thin films of different relaxor materials, namely Pb(Sc0.5Ta0.5)O3 (PST), Pb(Sc0.5Nb0.5)O3(PSN), Pb(Mg1/3Nb2/3)O3(PMN) have been produced by RF-sputtering to investigate whether it will affect their dielectric properties if their grain size is reduced to the dimensions known from their nanodomains. The XRD shows that the amorphous film crystallizes in pyrochlore structure at lower temperatures and short times. Annealing at higher temperatures and far longer time intervals leads to an increasing amount of perovskite phase with a grain size in the nanometer range. These results including dielectric measurements will be presented and discussed.
Using a neural network for predicting the average grain size in friction stir welding processes
2009
In the paper the microstructural phenomena in terms of average grain size occurring in friction stir welding (FSW) processes are focused. A neural network was linked to a finite element model (FEM) of the process to predict the average grain size values. The utilized net was trained starting from experimental data and numerical results of butt joints and then tested on further butt, lap and T-joints. The obtained results show the capability of the AI technique in conjunction with the FE tool to predict the final microstructure in the FSW joints.
The Effect of Grain Size of the Stock on Electrical Characteristics of the Li0.03Na0.97Ta0.05Nb0.95O3Perovskite Ceramics
2012
The microstructure and electrical properties of two samples of the ferroelectric Li0.03Na0.97Ta0.05Nb0.95O3 ceramic solid solution prepared from initial charge stocks of different dispersity by conventional ceramics technology are compared. The average size of grains and concentration of pores in the samples are found to be of little difference while the electrical properties of the ceramics are strongly affected by the grain size of the initial mixture. The difference in properties is due to conditions at the diffusion stage of the solid-phase synthesis caused by differences in composition of larger grains rather than the grain size itself.
Influence of Ag, Cu dopants on the second and third harmonic response of ZnO films
2009
International audience; Silver- and copper-doped ZnO films were prepared by radio-frequency (RF)-magnetron sputtering on glass and quartz substrates. The influence of dopants content on the microstructural evolution and optical as well as nonlinear optical (NLO) properties were investigated. It has been found that the grain sizes were enlarged with increasing of Ag, Cu dopants amount in ZnO films. The Ag or Cu doping leads to the optical band gap narrowing. Besides, the second-order NLO response of Ag- and Cu-doped ZnO films is lower than that of undoped ZnO film. The second harmonic generation (SHG) efficiency of the ZnO:Ag film was found to be higher than that of the ZnO:Cu film at the si…
Grain size dependent bandgap shift of SnO2 nanofibers
2013
SnO2 nanofibers with various grain sizes ranging from 18.5 to 31.6 nm in diameter were fabricated by electrospinning a polymeric solution and subsequent controlled calcination of the as-spun fibers. The calcined fibers were polycrystalline and composed of densely packed nano-sized SnO2 grains. The effect of the nanograin size on the optical bandgap of SnO2 nanofibers was examined by ultraviolet-visible spectroscopy. The bandgap showed a strong dependence on the nanograin size. The bandgap decreased with increasing nanograin size. Some calculations were performed to understand the relationship between the experimentally obtained bandgaps of the SnO2 nanofibers and the theoretical ones. Quant…