Search results for "Ground state"

Photostability and Photoreactivity in Biomolecules: Quantum Chemistry of Nucleic Acid Base Monomers and Dimers

2008

The great potentials of high-level ab initio methods, in particular, the CASPT2//CASSCF protocol, are fully illustrated through: (i) the study of ultrafast energy relaxation in DNA/RNA base monomers, (ii) the intrinsic population mechanism of the lowest triplet state, and (iii) how bioexcimers can be considered as precursors of charge transfer and photoinduced reactivity. In order to describe these processes properly, the presence of conical intersections (CIs) and the topology of the involved pathways have to be determined correctly. Thus, in theoretical calculations the dynamic electronic correlation has to be considered. The accessibility of the CIs (or the seam of CIs) becomes crucial t…

Extracting work from random collisions: A model of a quantum heat engine

2022

We study the statistical distribution of the ergotropy and of the efficiency of a single-qubit battery ad of a single-qubit Otto engine, respectively fuelled by random collisions. The single qubit, our working fluid, is assumed to exchange energy with two reservoirs, a non-equilibrium "hot" reservoir and a zero temperature cold reservoir. The interactions between the qubit and the reservoirs is described in terms of a collision model of open system dynamics. The qubit interacts with the non-equilibrium reservoir (a large ensemble of qudits all prepared in the same pure state) via random unitary collisions and with the cold reservoir (a large ensemble of qubits in their ground state) via a p…

Quantum Chemical Calculations Predict the Diphenyl Diuranium Compound [PhUUPh] To Have a Stable1Ag Ground State

2006

Constituent-quark model description of triply heavy-baryon nonperturbative lattice QCD data

2015

This paper provides results for the spectra of triply charmed and bottom baryons based on a constituent quark model approach. We take advantage of the assumption that potential models are expected to describe triply heavy baryons to a similar degree of accuracy as the successful results obtained in the charmonium and bottomonium sectors. The high precision calculation of the ground state and positive and negative parity excited states recently reported by nonperturbative lattice QCD provides us with a unique opportunity to confront model predictions with data. This comparison may also help to build a bridge between two difficult to reconcile lattice QCD results, namely, the lattice SU(3) QC…

Doubly heavy baryon spectra guided by lattice QCD

2016

This paper provides results for the ground state and excited spectra of three-flavored doubly heavy baryons, $bcn$ and $bcs$. We take advantage of the spin-independent interaction recently obtained to reconcile the lattice SU(3) QCD static potential and the results of nonperturbative lattice QCD for the triply heavy baryon spectra. We show that the spin-dependent potential might be constrained on the basis of nonperturbative lattice QCD results for the spin splittings of three-flavored doubly heavy baryons. Our results may also represent a challenge for future lattice QCD work, because a smaller lattice error could help in distinguishing between different prescriptions for the spin-dependen…

Resonance interaction energy between two entangled atoms in a photonic bandgap environment

2018

We consider the resonance interaction energy between two identical entangled atoms, where one is in the excited state and the other in the ground state. They interact with the quantum electromagnetic field in the vacuum state and are placed in a photonic-bandgap environment with a dispersion relation quadratic near the gap edge and linear for low frequencies, while the atomic transition frequency is assumed to be inside the photonic gap and near its lower edge. This problem is strictly related to the coherent resonant energy transfer between atoms in external environments. The analysis involves both an isotropic three-dimensional model and the one-dimensional case. The resonance interaction…

Exact Solution of Quantum Optical Models by Algebraic Bethe Ansatz Methods

1996

From long standing interests in solitons and integrable systems, e.g. SIT (1968– 74)1,2, “optical solitons” CQ04 (1977)3, we solve exactly, by algebraic Bettie ansatz (= quantum inverse) methods4, models of importance to quantum optics including the quantum Maxwell-Bloch envelope equations for plane-wave quantum self-induced transparency (SIT) in one space variable (x) and one time (t)2; and in the one tinte (t)5 a family of models surrounding and extending the Tavis-Cummings model6 of N 2-level atoms coupled to one cavity mode for ideal cavity (Q = ∞) QED. Additional Kerr type nonlinearities or Stark shifted levels can he incorporated into the Hamiltonian H of one of the most general model…

Phase transitions and quantum effects in adsorbed monolayers

1996

Phase transitions in absorbed (two-dimensional) fluids and in absorbed layers of linear molecules are studied with a combination of path integral Monte Carlo (PIMC), Gibbs ensemble Monte Carlo (GEMC), and finite size scaling techniques. For a classical (nonadditive) hard-disk fluid the “critical” nonadditivities, where the entropy-driven phase separations set in, are presented. For a fluid with internal quantum states the gas-liquid coexistence region, tricritical, and triple points can be determined, and a comparison with density functional (DFT) results shows good agreement for the freezing densities. LinearN 2 molecules adsorbed on graphite (in the √3 × √3 structure) show a transition fr…

All spin-1 topological phases in a single spin-2 chain

2014

Here we study the emergence of different Symmetry-Protected Topological (SPT) phases in a spin-2 quantum chain. We consider a Heisenberg-like model with bilinear, biquadratic, bicubic, and biquartic nearest-neighbor interactions, as well as uniaxial anisotropy. We show that this model contains four different effective spin-1 SPT phases, corresponding to different representations of the $(\mathbb{Z}_2 \times \mathbb{Z}_2) + T$ symmetry group, where $\mathbb{Z}_2$ is some $\pi$-rotation in the spin internal space and $T$ is time-reversal. One of these phases is equivalent to the usual spin-1 Haldane phase, while the other three are different but also typical of spin-1 systems. The model also …

Ultrafast critical ground state preparation via bang-bang protocols

2020

The fast and faithful preparation of the ground state of quantum systems is a challenging task but crucial for several applications in the realm of quantum-based technologies. Decoherence poses a limit to the maximum time-window allowed to an experiment to faithfully achieve such desired states. This is of particular significance in critical systems, where the vanishing energy gap challenges an adiabatic ground state preparation. We show that a bang-bang protocol, consisting of a time evolution under two different values of an externally tunable parameter, allows for a high-fidelity ground state preparation in evolution times no longer than those required by the application of standard opti…