Search results for "HIF"
showing 10 items of 1515 documents
Growth and population structure of perch in relation to diet in a small humic lake, Valkea-Kotinen
2011
Lake Valkea-Kotinen is a long-term ecological monitoring site in the Evo region of southern Finland .The aim of this study was to investigate the growth and population structure of perch (Perca fluviatilis L.) in relation to diet in Valkea-Kotinen in order to provide reference data for a study investigating effects of increased loading of dissolved organic matter to nearby Lake Alinen Mustajärvi. Valkea-Kotinen was predominantly inhabited by small benthivorous perch. The growth relationship between opercular bone and total length of perch in the lake is similar to those earlier analysed for nearby lakes. Compared to wider growth rates, the growth of perch was slow and similar to those in si…
An Integrated Theory for the Accumulation of Mentally Ill Offenders and the Effect of Realignment in California
2018
High mental illness prevalence in California state prisons has drawn much attention of scholars and policymakers in the past three decades. Various studies suggest that the mental illness prevalence in prison has increased from 0.14 to 0.3 from 1987 to 2014. The problem with a high concentration of mentally ill prisoners culminated when the California Department of Corrections and Rehabilitation (CDCR) was sued for the violation of inmates’ rights under the Eighth Amendment in the early 1990s. Consequently, CDCR’s health care was placed under Federal receivership to reform prison health care. Receivership is an uncommon remedy adopts by a federal court when other court orders have failed to…
Polysubstituted ferrocenes as tunable redox mediators
2018
A series of four ferrocenyl ester compounds, 1-methoxycarbonyl- (1), 1,1’-bis(methoxycarbonyl)- (2), 1,1’,3-tris(methoxycarbonyl)- (3) and 1,1’,3,3’-tetrakis(methoxycarbonyl)ferrocene (4), has been studied with respect to their potential use as redox mediators. The impact of the number and position of ester groups present in 1–4 on the electrochemical potential E1/2 is correlated with the sum of Hammett constants. The 1/1+–4/4+ redox couples are chemically stable under the conditions of electrolysis as demonstrated by IR and UV–vis spectroelectrochemical methods. The energies of the C=O stretching vibrations of the ester moieties and the energies of the UV–vis absorptions of 1–4 and 1+–4+ c…
Understanding Structure and Stability of Monoclinic Zirconia Surfaces from First-Principles Calculations
2017
Under the water-rich pre-treatment and/or reaction conditions, structure and chemistry of the monoclinic zirconia surfaces are strongly influenced by oxygen vacancies and incorporated water. Here, we report a combined first-principles and atomistic thermodynamics study on the structure and stability of selected surfaces of the monoclinic zirconia. Our results indicate that among the studied surfaces, the most stable (111) surface is the least vulnerable towards oxygen vacancies in contrast to the less stable (011) and (101) surfaces, where formation of oxygen vacancies is energetically more favorable. Furthermore, we present a vigorous, systematic screening of water incorporation onto the s…
Formation, Structural Characterization, and Calculated NMR Chemical Shifts of Selenium-Nitrogen Compounds from SeCl4 and ArNHLi (Ar = supermesityl, m…
2004
Supermesityl selenium diimide [Se{N(C6H2tBu3-2, 4, 6)}2; Se{N(mes*)}2] can be prepared in a good yield from the reaction of SeCl4 and (mes*)NHLi. The molecule adopts an unprecedented anti, anti-conformation, as deduced by DFT calculations at PBE0/TZVP level of theory and supported by 77Se NMR spectroscopy and a crystal structure determination. An analogous reaction involving (C6H2Me3-2, 4, 6)NHLi [(mes)NHLi] unexpectedly lead to the reduction of selenium and afforded the selenium diamide Se{NH(mes)}2 that was characterized by X-ray crystallography and 77Se NMR spectroscopy. The Se-N bonds of 1.847(3) and 1.852(3) A show normal single bond lengths. The <NSeN bond angle of 109.9(1)° also indi…
The Time-Varying Effect of Participatory Shift Scheduling on Working Hour Characteristics and Sickness Absence: Evidence from a Quasi-Experiment in H…
2022
Participatory shift scheduling for irregular working hours can influence shift schedules and sickness absence. We investigated the effects of using participatory shift scheduling and shift schedule evaluation tools on working hour characteristics and sickness absence. We utilized a panel data for 2015−2019 with 16,557 hospital employees (6143 in the intervention and 10,345 in the control group). Difference-in-differences regression with ward-level clustered standard errors was used to estimate the average treatment effect on the treated coefficients relative to timing of the intervention with 95% confidence intervals (CI). Using participatory scheduling tool increased long working hou…
EFFECTS OF SHIFT WORK ON CARDIOVASCULAR ACTIVITY, SERUM CORTISOL AND WHITE BLOOD CELLS COUNT IN A GROUP OF ITALIAN FISHERMEN
2012
We analyzed the effects of working activity and working shifts on the circadian rhythmicity and circadian phase relations of serum cortisol level, white blood cells count, resting heart rate and systolic/diastolic blood pressure in a group of italian fishermen. We observed a shift-induced displacement of cortisol secretion and a modification in leukocyte count. Moreover, systolic/diastolic blood pressure and resting heart rate were markedly influenced by the night shift, whereas no appreciable changes were observed after the morning and afternoon shifts, compared to pre-working values. These data suggest that the human circadian system is greatly influenced by shift work, and serum cortisol…
The role of regional competitiveness in shaping the heterogeneous impact of the Great Recession
2020
This paper assesses the employment resilience of 202 European regions to the Great Recession by investigating the role of regional competitiveness. By using the regional shift component derived from a multiple bases shift–share analysis of employment change as a measure of regional endogenous employment growth, we show that pre‐crisis regional competitiveness determinants are associated with positive performances during the crisis period. However, the variables considered explain well the different vulnerability of the economies, but less convincingly the ability to recover. Taking into account the spatial interactions among regions, results are confirmed and allow us to identify spillover …
Specialization and competitiveness of Polish voivodships in crop production in Poland
2015
Przestrzenna metoda przesunięć udziałów stanowi alternatywę klasycznej analizy shift-share, w której nie jest uwzględnione geograficzne położenie rozważanych regionów. Wiele zachodzących zjawisk, ich rozwój czy też kierunki zmian są bowiem uzależnione od przestrzennych interakcji zachodzących pomiędzy sąsiadującymi regionami. Model przestrzennej analizy shift-share został wprowadzony do badań przez Nazarę i Hewingsa. Model ten przedstawia przestrzennie zmodyfikowane stopy wzrostu (tempa zmian) poszczególnych wariantów zjawiska przez uwzględnienie temp wzrostu zjawiska w obszarach sąsiadujących. Celem artykułu jest analiza zmian struktury produkcji rolnej w województwach Polski w latach 2004…
Electronic Structures and Molecular Properties of Chalcogen Nitrides Se2N2 and SeSN2
2006
The electronic structures and molecular properties of S2N2 as well as the currently unknown chalcogen nitrides Se2N2 and SeSN2 have been studied using various ab initio and density functional methods. All molecules share a qualitatively similar electronic structure and can be primarily described as 2π-electron aromatics having minor singlet diradical character of 6−8% that can be attributed solely to the nitrogen atoms. This diradical character is manifested in the prediction of their molecular properties, in which coupled cluster and multiconfigurational approaches, as well as density functional methods, show the best performance. The conventional ab initio methods RHF and MP2 completely f…