Search results for "HOT"

showing 10 items of 14851 documents

Thermal photon v3 at LHC from fluctuating initial conditions

2014

Abstract We calculate the triangular flow parameter v 3 of thermal photons for 0–40% central collisions of Pb nuclei at LHC using an event-by-event hydrodynamic model with fluctuating initial conditions. Thermal photon v 3 with respect to the participant plane angle is found to be positive and significant compared to the elliptic flow parameter v 2 of thermal photons. In addition, photon v 3 as a function of p T shows similar qualitative nature to photon v 2 in the region 1 p T 6 GeV / c . We argue that while v 3 originates from ϵ 3 deformations of the initial state density distribution, fast buildup of radial flow due to fluctuations is the main driving mechanism for the observed large val…

PhysicsNuclear and High Energy PhysicsParticle physicsLarge Hadron ColliderPhotonDistribution (mathematics)Flow (mathematics)Plane (geometry)ThermalElliptic flowFunction (mathematics)Atomic physicsNuclear Physics A
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Lateral magnification matrix from the dioptric power matrix formalism in the paraxial case.

2012

Background Previous studies have highlighted that power matrices fully characterize the concept of dioptric power of any astigmatic surface. Thus, the basic equations in physiological optics can be generalized using the matrix formalism of the dioptric power. Among others, lateral magnification has also been interpreted as a matrix but mainly concerning magnification modification induced by spectacle correction of refractive error. Purpose To provide a fresh look into a novel paraxial formulation for the assessment of the lateral magnification using power matrices and in presence of astigmatism for thin and thick imaging systems in general. Methods Linear optics provides the frame to genera…

Optics and Photonicsbusiness.industrymedia_common.quotation_subjectParaxial approximationPhysics::OpticsMagnificationAstigmatismAsymmetrySensory SystemsOphthalmologyMatrix (mathematics)Formalism (philosophy of mathematics)OpticsThin lensHumansbusinessRefractive indexPower matrixOptometrymedia_commonMathematicsLensesOphthalmicphysiological optics : the journal of the British College of Ophthalmic Opticians (Optometrists)
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Differential diurnal variations of anandamide and 2-arachidonoyl-glycerol levels in rat brain.

2004

The endogenous ligands of cannabinoid receptors, also known as endocannabinoids, have been implicated in many physiological and pathological processes of the central nervous system. Here we show that the levels of the two major endocannabinoids, anandamide and 2-arachidonoyl-glycerol (2-AG), in four areas of the rat brain, change dramatically between the light and dark phases of the day. While anandamide levels in the nucleus accumbens, pre-frontal cortex, striatum and hippocampus were significantly higher in the dark phase, the opposite was observed with 2-AG, whose levels were significantly higher during the light phase in all four regions. We found that the activity of the fatty acid ami…

Malemedicine.medical_specialtyDiacylglycerol lipaseCannabinoid receptorPolyunsaturated Alkamidesmedicine.medical_treatmentPhotoperiod2-ArachidonoylglycerolArachidonic AcidsAmidohydrolasesGlyceridesRats Sprague-DawleyCellular and Molecular Neurosciencechemistry.chemical_compoundFatty acid amide hydrolaseInternal medicineCannabinoid Receptor ModulatorsmedicineanandamideAnimals2-arachidonoylglycerol; anandamide; cannabinoid; circadian; faahMolecular BiologyPharmacologybiologyBrainCell BiologyAnandamidefaahcannabinoidEndocannabinoid system2-arachidonoylglycerolCircadian RhythmRatsMonoacylglycerol lipaseEndocrinologycircadianchemistryBiochemistrybiology.proteinMolecular MedicineCannabinoidEndocannabinoidsCellular and molecular life sciences : CMLS
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40-GHz photonic waveform generator by linear shaping of four spectral sidebands

2015

International audience; We show that the amplitude and phase shaping of only four sidebands of the optical spectrum is sufficient to synthesize parabolic, triangular, or flat-top pulse trains at high repetition rates. Selection of the symmetric carrier-suppressed waveform is easily achieved by changing the phase difference between the inner and outer spectral lines. Experiments carried out at a repetition rate of 40 GHz confirm the high quality of the intensity profiles that are obtained.

Physics[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics][ PHYS.PHYS.PHYS-OPTICS ] Physics [physics]/Physics [physics]/Optics [physics.optics]Signal generatorbusiness.industryPhase (waves)02 engineering and technology01 natural sciencesPulse shapingAtomic and Molecular Physics and OpticsSpectral line010309 optics020210 optoelectronics & photonicsOpticsAmplitudeQuality (physics)0103 physical sciences0202 electrical engineering electronic engineering information engineeringWaveformsense organsPhotonicsbusiness
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σ-Hammett parameter: a strategy to enhance both photo- and electro-luminescence features of heteroleptic copper(i) complexes

2017

This work studies the effect of the σ-Hammett parameter (σp) – i.e., the σ-donation effect caused by substitution at the para position of a bipyridine ligand (4,4′-R2bipy, where R is MeO, Me, H, NO2) – on both the photo- and electro-luminescence features of a series of heteroleptic copper(I) complexes – i.e., [Cu(N^N)(P^P)]+ where N^N and P^P ligands are R2bipy and Xantphos, respectively. By virtue of a comprehensive photophysical, theoretical, and thin-film lighting device – i.e., light-emitting electrochemical cells (LECs) – investigation, we note a clear relationship between the σp and the photo- and electro-luminescence parameters, such as photoluminescence quantum yields, excited-state…

PhotoluminescenceXantphosLigandchemistry.chemical_element02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnologyPhotochemistry01 natural sciencesCopper0104 chemical sciencesElectrochemical cellInorganic ChemistryPara positionchemistry.chemical_compoundBipyridinechemistryElectro luminescencePhysical chemistry0210 nano-technologyDalton Transactions
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Environmentally Friendly Photocatalytic Oxidation of Aromatic Alcohol to Aldehyde in Aqueous Suspension of Brookite TiO(2)

2008

WOS: 000260509000008

chemistry.chemical_classificationGreen chemistryBrookite Tio2Settore ING-IND/24 - Principi Di Ingegneria ChimicaSelective photocatalysis Alcohol oxidation BrookiteAlcohol OxidationBrookiteAlcoholGeneral ChemistryAldehydeCatalysisCatalysischemistry.chemical_compoundchemistryvisual_artAlcohol oxidationSelective Photocatalysisvisual_art.visual_art_mediumPhotocatalysisOrganic chemistrySettore CHIM/07 - Fondamenti Chimici Delle TecnologieSelectivity
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Cytosporones, coumarins, and an alkaloid from the endophytic fungus Pestalotiopsis sp. isolated from the Chinese mangrove plant Rhizophora mucronata

2009

Chemical examination of the endophytic fungus Pestalotiopsis sp., isolated from the leaves of the Chinese mangrove Rhizophora mucronata, yielded 11 new compounds including cytosporones J-N (1-3, 5-6), five new coumarins pestalasins A-E (8-12), and a new alkaloid named pestalotiopsoid A (14), along with the known compounds cytosporone C (4), dothiorelone B (7), and 3-hydroxymethyl-6,8-dimethoxycoumarin (13). The structures of the new compounds were unambiguously elucidated on the basis of extensive spectroscopic data analysis.

Spectrometry Mass Electrospray IonizationMagnetic Resonance SpectroscopyClinical BiochemistryPharmaceutical ScienceBiochemistryEndophyteCell Linechemistry.chemical_compoundAlkaloidsAscomycotaCoumarinsDrug DiscoveryBotanyAnimalsHumansPestalotiopsisMolecular BiologyRhizophora mucronatabiologyAlkaloidOrganic ChemistryRhizophoraceaePhenolic acidFungi imperfectibiology.organism_classificationchemistryRhizophoraceaeMolecular MedicineSpectrophotometry UltravioletMangroveBioorganic & Medicinal Chemistry
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The effect of longitudinal chromatic aberration on the lag of accommodation and depth of field.

2016

Purpose Longitudinal chromatic aberration is present in all states of accommodation and may play a role in the accommodation response and the emmetropisation process. We study the change of the depth of field (DOFi) with the state of accommodation, taking into account the longitudinal chromatic aberration. Methods Subjective DOFi was defined as the range of defocus beyond which the blur of the target (one line of optotypes of 0.1 logMAR shown on a black-and-white microdisplay, seen through different colour filters) was perceived as objectionable. The subject's eye was paralysed and different, previously-measured accommodative states (corresponding to the accommodative demands of 0D, 2D and …

AdultMaleAccommodative responseLag01 natural sciencesDeformable mirror010309 optics03 medical and health sciencesYoung Adult0302 clinical medicineOpticsPhysiological optics0103 physical sciencesChromatic aberrationHumansDepth of fieldMathematicsDepth Perceptionbusiness.industryAccommodation OcularEmmetropiaSensory SystemsOphthalmology030221 ophthalmology & optometryOptometryFemaleMonochromatic colorbusinessAccommodationColor PerceptionPhotic StimulationOptometryOphthalmicphysiological optics : the journal of the British College of Ophthalmic Opticians (Optometrists)
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Selective Stepwise Suzuki Cross-Coupling Reaction for the Modelling of Photosynthetic Donor−Acceptor Systems

2009

A Suzuki reaction performed as a selective stepwise substitution of two boryl groups on a diarylporphyrin precursor is reported for straightforward construction of a porphyrin trimer, modeling photosynthetic donor-acceptor systems.

[CHIM.ORGA]Chemical Sciences/Organic chemistry010405 organic chemistryOrganic ChemistryTrimer010402 general chemistryPhotosynthesisPhotochemistry01 natural sciencesBiochemistryPorphyrinCoupling reaction0104 chemical scienceschemistry.chemical_compounddonor-acceptor systemchemistrySuzuki reaction[ CHIM.ORGA ] Chemical Sciences/Organic chemistryface to faceSuzuki couplingPhysical and Theoretical ChemistryDonor acceptorporphyrinComputingMilieux_MISCELLANEOUSOrganic Letters
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Dicyclopentaannelated Hexa-peri-hexabenzocoronenes with a Singlet Biradical Ground State

2021

Abstract Synthesis of two dicyclopentaannelated hexa‐peri‐hexabenzocoronene (PHBC) regioisomers was carried out, using nonplanar oligoaryl precursors with fluorenyl groups: mPHBC 8 with two pentagons in the “meta”‐configuration was obtained as a stable molecule, while its structural isomer with the “para”‐configuration, pPHBC 16, could be generated and characterized only in situ due to its high chemical reactivity. Both PHBCs exhibit low energy gaps, as reflected by UV‐vis‐NIR absorption and electrochemical measurements. They also show open‐shell singlet ground states according to electron paramagnetic resonance (EPR) measurements and density functional theory (DFT) calculations. The use of…

low energy gapnot-fully benzenoid PAH010402 general chemistryPhotochemistry01 natural sciencesCatalysislaw.inventiondicyclopentaannelationopen-shell biradicallawStructural isomerMoleculeSinglet stateElectron paramagnetic resonance010405 organic chemistryChemistryCommunicationAromaticityGeneral ChemistryCommunications0104 chemical sciencesDensity functional theoryPolycyclic Aromatic Hydrocarbons | Hot Paperhexa-peri-hexabenzocoroneneGround stateAntiaromaticityAngewandte Chemie International Edition
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