6533b81ffe1ef96bd1277160

RESEARCH PRODUCT

Long-term evolution of luminescent properties in CdI2 crystals

S. VelgoshYa. ShmygelskyIvan BolestaI. RovetskyiV. LesivtsivAnatoli I. PopovIvan Karbovnyk

subject

010302 applied physicsCadmium hydroxideZone meltingPhotoluminescenceMaterials sciencePhysics and Astronomy (miscellaneous)General Physics and Astronomy02 engineering and technology021001 nanoscience & nanotechnologyPhotochemistry01 natural sciencesSpectral linechemistry.chemical_compoundchemistry0103 physical sciencesCadmium oxideEmission spectrum0210 nano-technologySpectroscopyLuminescence

description

Fresh and aged melt-grown or gas-phase grown CdI2 crystals are studied by means of low-temperature photoluminescence spectroscopy. Noticeable transformations of emission spectra are observed after long-term aging. The formation of nanostructures containing cadmium oxide and cadmium hydroxide as well as the changes in local surrounding of iodine atoms and the possible growth of polytypic modifications of CdI2 are taken into account when considering the diversity of optical spectra.

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