Search results for "HYPERFINE"

showing 10 items of 428 documents

Hyperfine shifts for cesium in Argon at high density

1974

An optical pumping experiment was performed to obtain precise hfs shifts for Cs in Argon. The shifts measured include a term quadratic in the densityρ and a large temperature coefficient. The coefficients of the expansionδv/v0=a ρ+bρ2 area(80 °C)=−29.8(6)x10−9(Torr−1(0°C))b(80 °C)=+11(2)x10−14(Torr−2(0 °C)).

Optical pumpingNuclear and High Energy PhysicsArgonMaterials sciencechemistryCaesiumchemistry.chemical_elementHigh densityNuclear fusionAtomic physicsHyperfine structureTemperature coefficientZeitschrift für Physik
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Precision spectroscopy at heavy ion ring accelerator SIS300

2007

Unique spectroscopic possibilities open up if a laser beam interacts with relativistic lithium-like ions stored in the heavy ion ring accelerator SIS300 at the future Facility for Antiproton and Ion Research FAIR in Darmstadt, Germany. At a relativistic factor gamma = 36 the 2P 1/2 level can be excited from the 2S 1/2 ground state for any element with frequency doubled dye-lasers in collinear geometry. Precise transition energy measurements can be performed if the fluorescence photons, boosted in forward direction into the X-ray region, are energetically analyzed with a single crystal monochromator. The hyperfine structure can be investigated at the 2P 1/2 - 2S 1/2 transition for all elemen…

Optical pumpingPhysicsPhotonLaser coolingExcited stateFacility for Antiproton and Ion ResearchAtomic physicsGround stateHyperfine structureIon
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Mössbauer Spectral Study of Two Layered Honeycomb Molecular Magnets: PPh4FeIIFeIII(ox)3 and NBu4FeIIFeIII(ox)3

2002

The Mossbauer spectra of the layer ferrimagnets PPh4FeIIFeIII(ox)3 and NBu4FeIIFeIII(ox)3 have been measured between 1.9 and 315 K. The paramagnetic spectra exhibit both high-spin iron(II) and iron(III) doublets. The iron(II) quadrupole splittings are negative and decrease substantially upon cooling as a result of a low-symmetry crystal field splitting. In contrast, the iron(III) splittings are small, positive, and virtually independent of temperature. The respective magnetic ordering temperatures of 30 and 42.5 K agree well with the phase observed by bulk magnetometry and the magnetic sextets yield hyperfine fields of ca. 60 kOe for iron(II) and 540 kOe for iron(III). The unusually low iro…

ParamagnetismDipoleMaterials scienceCrystal field theoryMössbauer spectroscopyQuadrupoleAnalytical chemistryQuadrupole splittingHyperfine structureSpectral line
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Importance of Spin-Orbit Interaction for the Electron Spin Relaxation in Organic Semiconductors

2013

Despite the great interest organic spintronics has recently attracted, there is only a partial understanding of the fundamental physics behind electron spin relaxation in organic semiconductors. Mechanisms based on hyperfine interaction have been demonstrated, but the role of the spin-orbit interaction remains elusive. Here, we report muon spin spectroscopy and time-resolved photoluminescence measurements on two series of molecular semiconductors in which the strength of the spin-orbit interaction has been systematically modified with a targeted chemical substitution of different atoms at a particular molecular site. We find that the spin-orbit interaction is a significant source of electro…

PhotoluminescenceMaterials scienceGeneral Physics and Astronomy02 engineering and technology010402 general chemistry01 natural sciencesSpin-Orbit InteractionHyperfine structureComputingMilieux_MISCELLANEOUSCondensed matter physicsSpintronicsbusiness.industryOrganic SemiconductorRelaxation (NMR)Settore FIS/01 - Fisica SperimentaleSpin–orbit interactionMuon spin spectroscopy021001 nanoscience & nanotechnology0104 chemical sciencesOrganic semiconductorSemiconductorElectron Spin RelaxationCondensed Matter::Strongly Correlated Electrons[PHYS.COND.CM-SCE]Physics [physics]/Condensed Matter [cond-mat]/Strongly Correlated Electrons [cond-mat.str-el]0210 nano-technologybusiness
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57Fe,61Ni, and121Sb M�ssbauer study of oxidic spinel ferrites CoxNi5/3?xFeSb1/3O4

1987

Antimony substituted nickel ferrites Co x Ni5/3−xFeSb1/3O4 withx=0,1/3,1,4/3, and 5/3 were prepared by the common ceramic technique, and the single-phase structure was confirmed by x-ray powder diffraction.57Fe Mossbauer spectra were recorded at 4.2 K with and without an applied magnetic fieldHlong=60 kOe in order to determine the cation distribution and the spin structure. Utilizing the cation distributions and the Yafet-Kittel spin structures for B-site Fe3+ ions, derived from Mossbauer experiments the calculated magnetic moments are in excellent agreement with the experimental values at 4.2 K. The existence of Ni2+ ions in crystallographic A-sites was confirmed by61Ni Mossbauer spectrosc…

Physics and Astronomy (miscellaneous)Magnetic momentMössbauer effectChemistryGeneral EngineeringIonic bondingGeneral ChemistryIonMagnetizationNuclear magnetic resonanceMössbauer spectroscopyPhysical chemistryGeneral Materials ScienceSpin (physics)Hyperfine structureApplied Physics A Solids and Surfaces
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New Nuclear Magnetic Moment of Bi209 : Resolving the Bismuth Hyperfine Puzzle

2018

A recent measurement of the hyperfine splitting in the ground state of Li-like ${^{208}\mathrm{Bi}}^{80+}$ has established a ``hyperfine puzzle''---the experimental result exhibits a $7\ensuremath{\sigma}$ deviation from the theoretical prediction [J. Ullmann et al., Nat. Commun. 8, 15484 (2017); J. P. Karr, Nat. Phys. 13, 533 (2017)]. We provide evidence that the discrepancy is caused by an inaccurate value of the tabulated nuclear magnetic moment (${\ensuremath{\mu}}_{I}$) of $^{209}\mathrm{Bi}$. We perform relativistic density functional theory and relativistic coupled cluster calculations of the shielding constant that should be used to extract the value of ${\ensuremath{\mu}}_{I}(^{209…

Physics010304 chemical physicsMagnetic momentGeneral Physics and Astronomychemistry.chemical_element01 natural sciencesIonBismuthCoupled clusterchemistry0103 physical sciencesNuclear magnetic momentDensity functional theoryAtomic physics010306 general physicsGround stateHyperfine structurePhysical Review Letters
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Limits on gravitational Einstein Equivalence Principle violation from monitoring atomic clock frequencies during a year

2016

Sun's gravitation potential at earth varies during a year due to varying Earth-Sun distance. Comparing the results of very accurate measurements of atomic clock transitions performed at different time in the year allows us to study the dependence of the atomic frequencies on the gravitational potential. We examine the measurement data for the ratio of the frequencies in Hg$^+$ and Al$^+$ clock transitions and absolute frequency measurements (with respect to caesium frequency standard) for Dy, Sr, H, hyperfine transitions in Rb and H, and obtain significantly improved limits on the values of the gravity related parameter of the Einstein Equivalence Principle violating term in the Standard Mo…

Physics010308 nuclear & particles physicsAtomic Physics (physics.atom-ph)FOS: Physical sciencesFine-structure constantElectron01 natural sciencesAtomic clockPhysics - Atomic PhysicsGravitationsymbols.namesakeGravitational potentialStandard-Model ExtensionQuantum mechanics0103 physical sciencessymbols010306 general physicsHamiltonian (quantum mechanics)Hyperfine structure
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Observation of the Bottomonium Ground State in the Decay Υ(3S)→γηb

2008

The authors report the results of a search for the bottomonium ground state {eta}{sub b}(1S) in the photon energy spectrum with a sample of (109 {+-} 1) million of {Upsilon}(3S) recorded at the {Upsilon}(3S) recorded at the {Upsilon}(3S) energy with the BABAR detector at the PEP-II B factory at SLAC. They observe a peak in the photon energy spectrum at E{sub {gamma}} = 921.2{sub -2.8}{sup +2.1}(stat) {+-} 2.4(syst) MeV with a significance of 10 standard deviations. They interpret the observed peak as being due to monochromatic photons from the radiative transition {Upsilon}(3S) {yields} {gamma} {eta}{sub b}(1S). This photon energy corresponds to an {eta}{sub b}(1S) mass of 9388.9{sub -2.3}{…

Physics010308 nuclear & particles physicsBranching fractionElectron–positron annihilationParticle physicsGeneral Physics and AstronomyBABAR detectorPhoton energy01 natural sciencesB-factoryParticle decay0103 physical sciencesHigh Energy Physics::ExperimentAtomic physicsNuclear Experiment010306 general physicsGround stateFísica de partículesExperimentsHyperfine structureEnergy (signal processing)
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Measurement of the quadrupole moment of Re185 and Re187 from the hyperfine structure of muonic X rays

2020

The hyperfine splitting of the 5g→4f transitions in muonic Re185,187 has been measured using high resolution high purity germanium detectors and compared to state-of-the-art atomic theoretical predictions. The spectroscopic quadrupole moment has been extracted using modern fitting procedures and compared to the values available in literature obtained from muonic x rays of natural rhenium. The extracted values of the nuclear spectroscopic quadrupole moment are 2.07(5) b and 1.94(5) b, respectively for Re185 and Re187.

Physics010308 nuclear & particles physicschemistry.chemical_elementHigh resolutionGermaniumRhenium01 natural sciences7. Clean energychemistry0103 physical sciencesQuadrupolePhysics::Atomic PhysicsVacuum polarizationAtomic physics010306 general physicsHyperfine structurePhysical Review C
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Quadrupole moments of radium isotopes from the 7p 2 P 3/2 hyperfine structure in Ra II

1988

The hyperfine structure and isotope shift of221–226Ra and212,214Ra have been measured in the ionic (Ra II) transition 7s 2 S 1/2–7p 2 P 3/2 (λ=381.4 nm). The method of on-line collinear fast-beam laser spectroscopy has been applied using frequency-doubling of cw dye laser radiation in an external ring cavity. The magnetic hyperfine fields are compared with semi-empirical and ab initio calculations. The analysis of the quadrupole splitting by the same method yields the following, improved values of spectroscopic quadrupole moments:Q s (221Ra)=1.978(7)b,Q s (223Ra)=1.254(3)b and the reanalyzed valuesQ s (209Ra)=0.40(2)b,Q s (211Ra)=0.48(2)b,Q s (227Ra)=1.58(3)b,Q s (229Ra)=3.09(4)b with an ad…

PhysicsAb initio quantum chemistry methodsExcited stateQuadrupoleNuclear Physics - ExperimentQuadrupole splittingAtomic physicsGround stateSpectroscopyHyperfine structureAtomic and Molecular Physics and OpticsMolecular electronic transitionZeitschrift f�r Physik D Atoms, Molecules and Clusters
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