Search results for "Hard"

Polymerization and Damage of C60 Single Crystals under Low Fluency Laser Irradiation

2001

Photo-induced hardening, substructure formation and damage of C 60 single crystals under the 632.8 nm He-Ne laser irradiation in air at a power density of 1.47 mW/mm 2 was investigated by microhardness and AFM methods. Photo-induced formation of the dislocation substructure and crystallographically oriented crack patterns on the (111) face due to lattice contraction on polymerization were observed. Two phototransformed states: soft (400-450 MPa) and hard (650-1000 MPa) are found to appear under laser-irradiation. Hard fullerite is created in the subsurface layer < 1 μm at the saturation stage of phototransformation. It softens to 400-450 MPa at 340 K and reverts to non-polymerized state at …

Soft mode in PMN–PSN ceramics

2008

Various ordered and disordered (1–x)Pb(Mg1/3Nb2/3)O3 –x Pb(Sc1/2Nb1/2)O3 (PMN–PSN) ceramics were studied by THz transmission spectroscopy in the temperature range of 10–300 K. It is found that the dielectric relaxation dominates in the spectra in higher temperatures, T > 170 K. In contrast, below 150 K, the strength of relaxation becomes so weak that the phonon contribution can be separated. The phonon contributribution in the investigated frequency range (200 GHz–2 THz) is presumably caused by the E component of the Last mode. The component exhibits hardening on cooling in all investigated ceramics and its critical temperature in ferroelectric PMN–PSN ceramics (x = 1, 0.95) is lower than t…

Observation of Oriented Close-Packed Lattice Planes in Polycrystalline Hard-Sphere Solids.

1998

We report time-resolved Bragg scattering experiments on solidifying colloidal suspensions of hard spheres. The polar angle-averaged, integrated intensity of the (111) and (311) reflections show a transient, two-step behavior below melting, which depends in a complex way on the volume fraction and is not present for (200) or (220). Detailed analysis of the full two-dimensional scattering pattern reveals intensity maxima of sixfold symmetry close to the position of the (111) and (311) Debye-Scherrer rings. These can be explained assuming oriented crystals with close-packed planes parallel to the container walls. We show that the observed temporal behavior is due to competing homogeneous and h…

Dynamics of crystallization in hard-sphere suspensions.

1996

Density fluctuations are monitored by small-angle light scattering during the crystallization of 0.22-\ensuremath{\mu}m-radius, hard colloidal spheres. Measured structure factors show an intensity maximum at finite-scattering vectors. The shape of the intensity distribution scales at early times during nucleation and growth and again at large times during ripening. At intermediate times there is a crossover region where scaling ceases to be valid. Both the amplitude and the position of the maximum intensity show quasi-power law behavior in time. The values of the observed exponents are within the range expected for classical growth models. The breadth of the intensity distribution increases…

A strategy for the finite element modeling of FRP-confined concrete columns subjected to preload

2018

Abstract Compressive behavior of columns strengthened by means of an outer elastic confinement provided e.g. by fiber-reinforced polymer (FRP) jackets has become a main topic in the field of structural retrofitting. In details, the problem of the response assessment of strengthened columns is still under study. Many analytical formulations have been proposed to describe the compressive behavior of confined concrete under both monotonic and cyclic loads. However, the effect of a stress/strain level in the columns already present prior to apply the confinement has been generally neglected until now, also because of the lack of well defined strategies of modeling. In this frame, here, (1) a FE…

Histotomography of the odontoblast processes at the dentine-enamel junction of permanent healthy human teeth in the confocal laser scanning microscope

1998

The translucency of teeth allows the non-destructive subsurface visualisation of their microstructure by confocal laser scanning microscopy (CLSM) at a level of about 150 μm below the surface. The dentine–enamel junction (DEJ) is accessible only directly adjacent to the cervix of the tooth. Therefore teeth have to be sectioned for studying marginal areas of the dental hard tissue. The potential of the technique for (pseudo) three-dimensional visualisation allows the study of an array of individual confocal images, the interpretation of which is similar to that of macroscopic tomographs (CT-scan, MRI). Additionally, the extended focus mode yields the overlay of individual confocal images in …

Influence of the Mean Load Value in Fatigue Block Loading on Strains

2014

This paper presents the results of the fatigue tests of the specimens made from S3555 steel and aluminum alloy AlCu4MgSi subjected to bending block loading with mean load value. The influence of the changes of the mean load conditions was investigated. During the tests strains were registered and relation between the load and the strains was analyzed. In the case of S355 steel it was observed, that additional hardening occurs when higher value of the mean load is applied at the beginning of the block loading. Other case, when the mean load was increased from zero to maximum, a creep effect of the material was registered. For the specimens made from aluminum alloy similar processes were not …

NMR relaxation study of hardening acid-base dental cements

2001

The Use of Atomic Force Microscopy in Determining the Stiffness and Adhesion Force of Human Dentin After Exposure to Bleaching Agents

2009

Introduction: Oxidant bleaching agents may induce several alterations on mineralized teeth tissues. Our aim is to study,at the ultrastructurallevel,mechanicalmodifications induced on dentin after exposure to different bleaching agents.Methods: Nanoindentation performed with atomic force microscopy was used to measure changes in dentin stiffness as well as the adhesion force between the tip and the tissue both in intertubular and peritubulardentin.Foreachspecimen,dentinlocalization, and bleaching agent, 100 independent nanoindentations were performed. Carbamide peroxide (30%) and hydrogenperoxide(35%) wereusedasbleaching agents. Results: A significant reduction of both stiffness and adhesion…

Effect of polydispersity on the crystallization kinetics of suspensions of colloidal hard spheres when approaching the glass transition

2007

We present a comprehensive study of the solidification scenario in suspensions of colloidal hard spheres for three polydispersities between 4.8% and 5.8%, over a range of volume fractions from near freezing to near the glass transition. From these results, we identify four stages in the crystallization process: (i) an induction stage where large numbers of precursor structures are observed, (ii) a conversion stage as precursors are converted to close packed structures, (iii) a nucleation stage, and (iv) a ripening stage. It is found that the behavior is qualitatively different for volume fractions below or above the melting volume fraction. The main effect of increasing polydispersity is to…