Search results for "Hardwood"
showing 10 items of 20 documents
Automatic measurement of wood fiber orientation and knot detection using an optical system based on heating conduction.
2015
In this paper, a new approach to computing the deviation of wood grain is proposed. To do this, the thermal conduction properties of timber are used (higher conduction in the fiber direction). Exciting the surface of the wood with a laser and capturing the thermal conduction using a thermal camera, an ellipse can be observed. Using a method similar to the tracheid effect, it is possible to extract information from this ellipse, such as the slope of grain and the presence of knots. With this method it is therefore possible to extend the mechanical model (assessing the mechanical properties of timber) to take certain singularities into account. Using this approach, the slope of grain can be e…
Spectroscopic analysis of hot-water- and dilute-acid-extracted hardwood and softwood chips
2017
Hot-water and dilute sulfuric acid pretreatments were performed prior to chemical pulping for silver/white birch (Betula pendula/B. pubescens) and Scots pine (Pinus sylvestris) chips to determine if varying pretreatment conditions on the original wood material were detectable via attenuated total reflectance (ATR) infrared spectroscopy. Pretreatment conditions varied with respect to temperature (130 °C and 150 °C) and treatment time (from 30 min to 120 min). The effects of the pretreatments on the composition of wood chips were determined by ATR infrared spectroscopy. The spectral data were compared to those determined by common wood chemistry analyses to evaluate the suitability of ATR spe…
Role of paramagnetic polyconjugated clusters in lignin antioxidant activity(in vitro)
2012
Using physico-chemical methods (EPR, SEC, Py-GC/MS and UV/VIS spectroscopy) and wet chemical analysis, the characteristics of 6 hardwood lignins in terms of functionality, molecular weight and composition of lignin substructures were determined and considered together with the results of DPPH•, ABTS•+ and O2•− antioxidant assays with the aim to understand the relationships governing antioxidant properties of lignin. The strong positive linear correlation between lignin antioxidant capacity in the three assays used and the extent of conjugation of paramagnetic polyconjugated clusters in lignin macromolecules was found. The biological activity of the most active alkaline lignins was assessed …
Alkali consumption of aliphatic carboxylic acids during alkaline pulping of wood and nonwood feedstocks
2013
Abstract The carbohydrate degradation products have been examined, which are formed during the conventional kraft pulping of a softwood, hardwoods, bamboo, and wheat straw as well as soda and soda-anthraquinone pulping of wheat straw. The focus was on “volatile” acids such as formic and acetic acids and “nonvolatile” hydroxy monocarboxylic and dicarboxylic acids. The different consumption profiles were obtained for the charged alkali required for the neutralization of these aliphatic acids depending on the feedstock and the cooking method. The relative composition of the acid fraction in the black liquors of softwood and hardwood and nonwood feedstocks showed characteristic variations. Howe…
Chlorophenanthrenes, alkylchlorophenanthrenes and alkylchloronaphthalenes in kraft pulp mill products and discharges
1994
Abstract Chlorinated phenanthrenes (PCPHs; P=1–5), alkylphenanthrenes (C4-PCPHs; P=1–3), dimethylnaphthalenes (C2-PCNs; P=1–4) and trimethylnaphthalenes (C3-PCNs; P=1–2) were analyzed by high resolution gas chromatography/high resolution mass spectrometry (HRGC/HRMS) in pulp, effluent and biosludge of two kraft pulp mills (mills 1 and 2). These compounds were indicated to be formed in the manufacture of both bleached hardwood and softwood kraft pulp. Different compound groups dominated in mill 1 samples compared to mill 2 samples. Differences between birch and pine pulp from mill 1 were observed for all substance groups but in mill 2 pulp only for PCPHs. The highest concentrations of PCPHs …
PURIFICATION OF HARDWOOD-DERIVED AUTOHYDROLYSATES
2012
Carbohydrate-containing hydrolysates (1.1 to 14.9% of wood dry matter) obtained from autohydrolysis (at 130 to 150°C for 30 to 120 minutes) of birch (Betula pendula) chips prior to pulping were purified with respect to non-carbohydrate materials, without carbohydrate losses, either by ethyl acetate extraction or XAD-4 resin treatment. In the former case, about 50% of lignin and practically all the furanoic compounds (2-furaldehyde and 5-(hydroxymethyl)furfural) could be removed, whereas in the latter case, the corresponding amounts were about 30% and 50 to 90%, respectively. A partial recovery of various unsaturated impurities is of importance, because they may act as inhibitors when bioche…
Multivariate Correlation between Analytical Data for Various Organics Dissolved during Autohydrolysis of Silver Birch (Betula pendula) Chips and Trea…
2014
Autohydrolysis pre-treatments were performed for the production of hemicellulose-rich autohydrolysates from silver birch (Betula pendula) chips prior to chemical pulping. Pre-treatment conditions were varied with respect to time (from 30 to 120 min) and temperature (130 and 150 °C), covering a P-factor range from 10 to 238. Hydrolysates were analyzed in terms of carbohydrates, lignin, volatile organic acids, and furanoic compounds. The analytical data were subjected to various chemometric techniques to establish the relationships between dissolved organic components, hardwood and softwood used in the experiments, and applied pre-treatment conditions. Using this method, differences between t…
Characterization of Hardwood Soda-AQ Lignins Precipitated from Black Liquor through Selective Acidification
2016
In the development of integrated biorefinery process alternatives to produce value-added by-products, various black liquors from sulfur-free pulping processes offer potential feedstocks for recovering their main chemical constituents, lignin and aliphatic carboxylic acids. In this study, lignin fractions were obtained from silver birch (Betula pendula) soda-anthraquinone black liquor by carbonation (pH to about 8.5) or by acidification (pH to about 2) with H2SO4 after carbonation or directly. These fractions were characterized by Fourier transform infrared (FTIR), ultraviolet (UV), energy dispersive X-ray fluorescence (ED XRF), and 13C nuclear magnetic resonance (13C NMR) spectroscopy. In a…
Solid-liquid nuclear magnetic resonance relaxation and signal amplitude relationships with ranking of seasoned softwoods and hardwoods
2006
In 1H NMR (Nuclear Magnetic Resonance) relaxation measurements for a set of eight hardwood and softwood samples, each Free Induction Decay (FID) is fit by the sum of a “Solid” signal of the form A exp[−c(t/Ts)2] [1−g(t/Ts)2+h(t/Ts)4] plus a “Liquid” signal B exp(−t/T2 FID). Distributions of longitudinal (T1) relaxation times were computed separately for the Solid and Liquid components, giving also the Solid/Liquid 1H ratio α. From measurements on the samples dried, seasoned, and hydrated, the moisture content, (Liquid/Solid weight ratio) was found to be approximately 0.50/α. For each of the “Seasoned” samples (10-13% moisture content) a single T1 peak was found for the Solid and two for the…
Partial Recovery of Aliphatic Carboxylic Acids and Sodium Hydroxide from Hardwood Black Liquor by Electrodialysis
2014
The partial recovery of sodium as NaOH and sodium-free aliphatic carboxylic acids (formic and acetic acids together with various hydroxy carboxylic acids) from alkaline hardwood black liquor (BL, pH about 14) was studied by using electrodialysis (ED). In the first phase, the lignin was partly (about 59% of the initial lignin) precipitated from BL by carbonation (pH to 8.5). Furthermore, the carbonated liquor, mainly containing NaHCO3/Na2CO3 and Na salts of aliphatic carboxylic acids and lignin, was subjected to ED for recovering NaOH and sodium-free aliphatic acids. In the second phase, the carbonated BL was further acidified with H2SO4 (pH to about 2.5) for precipitating more lignin (about…