Search results for "Heat capacity"
showing 10 items of 90 documents
Heat Capacity and Entanglement Measure in a simple two-qubit model
2011
A simple two-qubit model showing Quantum Phase Transitions as a consequence of ground state level crossings is studied in detail. Using the Concurrence of the system as an entanglement measure and heat capacity as a marker of thermodynamical properties, an analytical expression giving the latter in terms of the former is obtained. A protocol allowing an experimental measure of entanglement is then presented and compared with a related proposal recently reported by Wie\'sniak, Vedral and Brukner
Heavy fermion spin liquid in herbertsmithite
2015
We analyze recent heat capacity measurements in herbertsmithite $\rm ZnCu_3(OH)_6Cl_2$ single crystal samples subjected to strong magnetic fields. We show that the temperature dependence of specific heat $C_{mag}$ formed by quantum spin liquid at different magnetic fields $B$ resembles the electronic heat capacity $C_{el}$ of the HF metal $\rm YbRh_2Si_2$. We demonstrate that the spinon effective mass $M^*_{mag}\propto C_{mag}/T$ exhibits a scaling behavior like that of $C_{el}/T$. We also show that the recent measurements of $C_{mag}$ are compatible with those obtained on powder samples. These observations allow us to conclude that $\rm ZnCu_3(OH)_6Cl_2$ holds a stable strongly correlated …
Spectral broadening by quasiparticle pile-up in X-ray microcalorimeters with superconducting absorbers
2004
Long-living quasiparticles can pile-up in a superconducting absorber of an X-ray microcalorimeter when photons are detected at high count rate. These quasiparticles can give a non-negligible contribution to the total heat capacity of the detector thus affecting the pulse height spectrum of detected photons. We investigated this effect with numerical simulations and evaluated the resulting spectral broadening as a function of the photon absorption rate, and the heat capacity of the detector for a NTD germanium microcalorimeter with pure Sn absorber.
Entanglement and heat capacity in a two-atom Bose–Hubbard model
2012
Abstract We show that a two-atom Bose–Hubbard model exhibits three different phases in the behavior of thermal entanglement in its parameter space. These phases are demonstrated to be traceable back to the existence of level crossings in the ground state of the same system. Significant similarities between the behaviors of thermal entanglement and heat capacity in the parameter space are brought to light thus allowing to interpret the occurrence and the meaning of all these three phases.
Prediction of ionic liquid's heat capacity by means of their in silico principal properties
2016
The in silico principal properties (PPs) of ionic liquids (ILs), derived by means of the VolSurf+ approach, were used to develop a Partial Least Squares (PLS) model able to find a quantitative correlation among IL descriptors (accounting for both cationic and anionic structural features) and heat capacity values, providing affordable predictions validated by experimental Cp measurements for an external set of ILs. In silico predictions allowed the selection of a limited number of structurally different ILs with similar Cp values, providing the possibility to select an optimal IL according to efficiency, as well as to environmental and economic sustainability. The present general procedure, …
Heat Capacity and Dielectric Properties of the PNN-PT Ferroelectric Ceramics
2012
A study of dielectric permittivity and heat capacity of the (1-х)PbNi1/3Nb2/3O3 – хPbTiO3 solid solution system (x = 0.3, 0.4, 0.5) within the 290–700 K range is reported. Temperatures of phase transitions Tm determined from maximums of dielectric permittivity ϵ depends on the content of PbTiO3. A broad phase transition is shown to proceed in the 0.7PbNi1/3Nb2/3O3–0.3PbTiO3 composition around 312 K. Specific to phase transitions anomalous heat capacity is observed at Т ≈ 520 K in all compositions studied.
Thermal properties of ferroelectric 0.7PbNi1/3Nb2/3O3–0.3PbTiO3ceramics
2013
A study of heat capacity as function of temperature of the 0.7PbNi1/3Nb2/3O3–0.3PbTiO3 solid solution within the 120–800 K range is reported. Broad anomalies on the curve of heat capacity are revealed in the 250–450 K and 450–650 K intervals peaking at 520 K and a λ-anomaly at T ≈ 225 K. Results are discussed with account for dielectric and structural data.
Long-range magnetic order in the porous metal–organic framework Ni(pyrazine)[Pt(CN)4]
2017
A combined study involving DFT calculations, neutron scattering, heat capacity and magnetic measurements at very low temperatures demonstrates the long-range magnetic ordering of Ni(pyrazine)[Pt(CN)4] below 1.9 K, describing its antiferromagnetic spin arrangement. This compound belongs to the family of porous coordination polymers M(pyrazine)[Pt(CN)4] (M = divalent metal), renowned for showing interesting combinations of porosity and magnetic properties. The possibility of including long-range magnetic ordering, one of the most pursued functional properties, opens new perspectives for the multifunctionality of this class of compounds.
Packing a multidisperse system of hard disks in a circular environment.
2008
We consider the problem of finding the densest closed packing of hard disks with proposed different radii in a circular environment, such that the radius of the circumcircle is minimal. With our approach, we are able to find denser packings for various problem instances than known from the literature. Both for the dynamics of the simulation and for the optimum values of the radii of the circumcircles, we find various scaling laws.
Thermal Parameters Measurements of High-Rise Building Envelope
2016
In buildings, to ensure the thermal comfort of the occupants and to keep the energy consumption as low as possible, a correct design of the thermal system is necessary. To do so, an appropriate determination of the thermo-physical properties of the wall materials is needed, particularly; new light-weight building technologies are widely used in the construction of the building envelope. One of these parameters, particularly important in Mediterranean climatic dynamic conditions is the heat capacity, due to the presence of the sun’s energy contribution in hot and cold seasons. The value of the heat capacity in such like materials is typically quite different from the declared parameter, obta…