Search results for "Homogeneous"
showing 10 items of 718 documents
Fotogrammetria e tecnologia IR per un rilievo digitale low-cost della scultura “Torso”, di Eduardo Chillida
2014
The paper focuses on the analysis of ‘innovative’ technologies for low-cost survey: downstream test metrology and precise coding methodology, which could be of great support in the documen- tation, virtualization and dissemination of the sculptural heritage. The transposition of the museum works in 3D allows the return of models that can be used by remote –for studies, measurements, restorations, etc.–, no needing a physical contact with the piece, so in a non-invasive way. The virtual museum also offers the pos- sibility to organize exhibitions accessible to a wider audience.
Typology and Representation of Alterations in Territorial Units: A Proposal
2018
Abstract This article proposes a typology of boundary changes in territorial units at two points in time. The different types of changes are organized in a hierarchy and represented homogeneously, independently of the number of territorial units involved and of the changes to them. Each alteration is described precisely and unambiguously, and it is codified to allow the information to be treated automatically. In addition to providing efficient storage of the information about these changes, a canonical representation facilitates the automatic detection of inconsistencies in the database. At the same time, the typology allows us to define backward and forward equivalence rules, which helps …
The classification of submerged vegetation using hyperspectral MIVIS data
2009
The aim of this research is to use hyperspectral MIVIS data to map the Posidonia oceanica prairies in a coastal lagoon (Stagnone di Marsala). It is approximately 12 km long and 2 km wide and is linked to the open sea by two shallow openings. This environment is characterised by prairies of phanerogams, the most common of which is Posidonia oceanica, an ideal habitat for numerous species of fish, molluscs and crustaceans. A knowledge of the distribution of submerged vegetation is useful to monitor the health of the lagoon. In order to classify the MIVIS imagery, the attenuation effects of the water column have been removed from the signal using Lyzenga’s technique. A comparison between class…
Hexagonal nanosheets from the exfoliation of Ni2+-Fe3+ LDHs: a route towards layered multifunctional materials
2010
Here we report the synthesis of a crystalline micrometric-sized hexagonal-shaped Ni2+-Fe3+ LDH by following a modified homogeneous precipitation method. The exfoliation of the material in formamide leads to stable suspensions of hexagonal nanometric sheets, which have been extensively characterized. Our data confirm that the intrinsic properties of the bulk material are retained by these segregated nanosheets, thus opening the door for their use in the development of layered multifunctional materials.
“Release and catch” catalytic systems
2013
In this perspective article the “release and catch” catalytic system concept is discussed. A “release and catch” catalytic system is prepared by non-covalent immobilization of the catalytic moiety on a suitable support, but differently from the usual non-covalently supported catalyst, the catalytic moiety is released in solution over the course of the reaction and it is recaptured at the end of the reaction. Such a “catalyst- sponge like” or “boomerang” system allows one to combine the benefits of homogeneous and heterogeneous catalysis and can be applied to organometallic-based catalysts, organocatalysts and metal-based catalysts.
Catalytic activity of solvated and unsolvated lanthanide halides in Friedel–Crafts acylations
2000
Abstract Anhydrous lanthanide halides — chlorides and bromides — can act as homogeneous catalysts of Friedel–Crafts acylations. The catalytic activity is related to the solubility of these anhydrous salts. More soluble THF or dioxane (Diox.) neodymium and samarium adducts are more active catalysts.
Tailoring polymers through interplay of ligands within precatalysts: 8-(Nitro/benzhydryl-arylimino)-7,7-dimethyl-5,6-dihydroquinolylnickel halides in…
2017
A series of 8-(nitro/benzhydryl-substituted arylimino)-7,7-dimethyl-5,6-dihydroquinolines and the corresponding nickel halide complexes were synthesized and characterized. Molecular structures of representative nickel complexes were determined by single crystal X-ray diffraction, showing the dinuclear dimers with distorted square-pyramidal geometry around the nickel center. The binding energies determined by X-ray photoelectron spectroscopy (XPS) indicate the effective coordination between the sp2-nitrogen and nickel atoms as well as the influence of both the halogen ligands and the substituents within dihydroquinolines on the strength of the NiN bond. Ethylene polymerization with the nicke…
Oxidation of aminodiols mediated by homogeneous and heterogeneous TEMPO
2004
The conversion of amino diols to aminohy- droxy acids by oxidation of the primary hydroxy group mediated by homogeneous and heterogeneous TEMPO (2,2,6,6-tetramethylpiperidine 1-oxyl radi- cal) is reported. The synthesis uses NaOCl as primary oxidant and TEMPO, either dissolved in the homoge- neous phase or entrapped in a sol-gel matrix, as cata- lytic mediator. Homogeneous TEMPO is suitable for the oxidation of aliphatic methylamino diols, while the hybrid organic-inorganic silica sol-gel catalysts are more selective mediators for the oxidation of ben- zylic amino diols like the potent antibiotic chloram- phenicol which, under homogeneous conditions, are unselectively oxidized to benzoic ac…
UraniumIV and uranyle salts, efficient and reusable catalysts for acylation of aromatic compounds
2000
Abstract Uranium tetrachloride, uranyle chloride, fluoride and also nitrate or acetate are very efficient homogeneous catalysts for the Friedel–Crafts acylation of aromatic compounds. With uranyle salts, the reaction, carried under dry air, is highly specific and the mono- or bisacylation products are obtained in high yield. Uranyle catalyst can be quantitatively recovered and reused and the organic products are obtained free of uranium.
Water compatible gold(III)-catalysed synthesis of unsymmetrical ethers from alcohols.
2008
An efficient and broad-scoped method for the preparation of unsymmetrical ethers from alcohols catalysed by the simplest and least expensive gold catalyst, NaAuCl 4 , is described for the first time. The procedure enables the etherification of benzylic and tertiary alcohols with moderate to good yields under mild conditions with low catalyst loading. Symmetrical ethers, the usual side products in the etherification of alcohols, were not detected in this case. The formation of the racemic ether from a chiral benzyl alcohol suggests the intermediacy of a carbocation, which has not previously been postulated for gold-catalysed reactions involving alcohols.