Search results for "Hybrids"

showing 10 items of 46 documents

Vortex motion in Nb/PdNi/Nb trilayers: new aspects in the flux flow state

2011

We study the dynamics of vortex lines in Supercondutor/Ferromagnet/Superconductor (SFS) heterostructures at microwave frequencies. We have employed swept-frequency, Corbino-disk and resonant, dielectric-resonator techniques to obtain the field and temperature dependence of the vortex-state parameters. We concentrate here on the genuine flux-flow resistivity $\rho_{ff}$, that we access at subcritical currents using a sufficiently high driving frequency. We find that $\rho_{ff}$ does not follow the well-known Bardeen-Stephen model. Instead, it is well described by a full time-dependent Ginzburg-Landau expression at very thin F layer thickness, but changes to a previously unreported field-depe…

SuperconductivityMaterials scienceField (physics)Condensed matter physicsCondensed Matter - SuperconductivityEnergy Engineering and Power TechnologyFOS: Physical sciencesDielectric resonatorVorticityCondensed Matter PhysicsCondensed Matter::Mesoscopic Systems and Quantum Hall EffectElectronic Optical and Magnetic MaterialsVortexSuperconductivity (cond-mat.supr-con)FerromagnetismElectrical resistivity and conductivityCondensed Matter::SuperconductivityElectrical and Electronic Engineeringsuperconductors; nb; mixed state; s/f hybrids; dielectric resonator; resistance; vortex dynamics; surface impedance; corbino disk; vortices; temperatureMicrowave
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Rapid and eco-friendly synthesis of graphene oxide-silica nanohybrids

2014

The increasing interest in Graphene oxide (GO) is due to many issues: the presence of both sp2-conjugated atoms and oxygen-containing functional groups provides a strong hydrophilicity and the possibility to further functionalize it with other molecules (i.e. π-π interactions covalent attachment etc.) [1]. Furthermore since the GO is biocompatible and noncytotoxic many studies have been recently focused on the development of GO-based nanodevices for bioimaging DNA detection drug delivery. Due to their low cytotoxicity and large internal surface area silica nanoparticles have been taken into account as promising material for biolabeling and drug loading/delivery. Particular consideration has recently been demonstrated for GO-silica composites because of the potentialities for electrical applications their chemical inertia and stability toward ions exposure. The possibility to combine the extraordinary properties of GO and silica offers several advantages for the realization of nanoprobes for biological applications and of biosensor [12]. The strategy for the fabrication of GO-nanosilica nanohybrids can be schematized as follows: (i) synthesis of GO by oxidizing graphite powder with the method described by Marcano et al. [3] (ii) Preparation of oxygen-loaded silica nanoparticles by thermal treatments in controlled atmosphere in order to induce high NIR emission at 1272 nm from high purity silica nanoparticles. (iii) preparation of GrO-silica nanohybrid films via rapid solvent casting in water. The nanohybrids were tested by XPS FTIR Raman analysis UV photoluminescence analysis TGA Zeta potential measurements electrical tests AFM and SEM. Several nanohybrids were prepared by combining two different typologies of GO and two different samples of silica.
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One step grafting of monomethoxy poly(ethylenglycol) during synthesis of maghemite nanoparticles in aqueous medium

2008

Abstract Grafting of silanated monomethoxy poly(ethylene glycol) (m-PEG) onto maghemite nanoparticles surface in aqueous medium through one step procedure was investigated. The major characteristic of this work is that the grafting of m-PEG was produced during the synthesis of maghemite nanoparticles. The maghemite nanoparticles were characterized by photon correlation spectroscopy (PCS), zeta potential measurement, X-ray diffraction (XRD), Raman spectroscopy, transmission electron microscopy (TEM), Fourier transform infrared spectrometer (FTIR), and X-ray photoelectron spectroscopy (XPS). The spinel structure of maghemite nanoparticles was verified and successful grafting of m-PEG was evid…

Thermogravimetric analysisMaterials scienceAnalytical chemistryInfrared spectroscopyNanoparticleMaghemitemacromolecular substances02 engineering and technologyengineering.material010402 general chemistry01 natural scienceschemistry.chemical_compoundsymbols.namesakeColloid and Surface ChemistryZeta potentialaqueous mediumFourier transform infrared spectroscopyComputingMilieux_MISCELLANEOUShybridstechnology industry and agriculturemonomethoxy poly(ethylene glycol)021001 nanoscience & nanotechnologygrafting0104 chemical sciences[ CHIM.POLY ] Chemical Sciences/Polymersmaghemite[CHIM.POLY]Chemical Sciences/Polymerschemistrysymbolsengineering0210 nano-technologyRaman spectroscopyEthylene glycolNuclear chemistry
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Straightforward preparation of highly loaded MWCNT-polyamine hybrids and their application in catalysis

2020

Multiwalled carbon nanotubes (MWCNTs) were easily and efficiently functionalised with highly cross-linked polyamines. The radical polymerisation of two bis-vinylimidazolium salts in the presence of pristine MWCNTs and azobisisobutyronitrile (AIBN) as a radical initiator led to the formation of materials with a high functionalisation degree. The subsequent treatment with sodium borohydride gave rise to the reduction of imidazolium moieties with the concomitant formation of secondary and tertiary amino groups. The obtained materials were characterised by thermogravimetric analysis (TGA), elemental analysis, solid state 13C-NMR, Fourier-transform infrared spectroscopy (FT-IR), transmission ele…

Thermogravimetric analysisNitroaldol reactionPotentiometric titrationHeterogeneous Catalysis Carbon nanotubes Ionic Liquids Green Chemistry AminesBioengineering02 engineering and technology010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundSodium borohydridePolymer chemistryGeneral Materials ScienceGeneral EngineeringAzobisisobutyronitrileGeneral ChemistrySettore CHIM/06 - Chimica OrganicaMWCNT-polyamine hybrids021001 nanoscience & nanotechnologyAtomic and Molecular Physics and Optics0104 chemical scienceschemistryddc:540Radical initiatorKnoevenagel condensation0210 nano-technologyddc:546
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Aroma production and fermentation performance of S. cerevisiae × S. kudriavzevii natural hybrids under cold oenological conditions

2019

This work aims to describe the wine fermentation characteristics of 23 natural S. cerevisiae × S. kudriavzevii hybrid yeasts related to fermentative environments isolated from different regions and their significance for the aroma spectra of the produced wines. Fermentations were performed at 12 °C in artificial must, and S. cerevisiae and S. kudriavzevii pure species strains were used for comparison purposes. We determined the relevant kinetic parameters of fermentation, the concentration of the main metabolites and the main aroma-related compounds produced after fermentation. The results revealed that some strains that show well-rounded characteristics could be profitable yeast starters f…

Wine yeastNatural hybridsS. cerevisiaeWineSaccharomyces cerevisiaeMicrobiologySaccharomyces03 medical and health sciencesFood microbiologyS. kudriavzeviiFood scienceAromaAroma030304 developmental biologyWinemakingWineFermentation in winemaking0303 health sciencesbiology030306 microbiologyChemistryfood and beveragesGeneral Medicinebiology.organism_classificationYeastCold Temperaturecarbohydrates (lipids)Yeast in winemakingFermentationOdorantsCryotoleranceHybridization GeneticFermentationFood ScienceInternational Journal of Food Microbiology
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Differences in the glucose and fructose consumption profiles in diverse Saccharomyces wine species and their hybrids during grape juice fermentation

2009

7 pages, 4 figures, 5 tables.

WineHybridsSugars in wineFructoseMicrobiologySaccharomycesSaccharomyceschemistry.chemical_compoundSpecies SpecificitySugar consumptionFood scienceWinemakingWine yeastsWinebiologyTemperatureGenetic Variationfood and beveragesFructoseGeneral Medicinebiology.organism_classificationYeastKineticsYeast in winemakingGlucosechemistryBiochemistryFermentationFood MicrobiologyFermentationFood ScienceInternational Journal of Food Microbiology
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Biotechnological applications of the sepiolite interactions with bacteria: Bacterial transformation and DNA extraction

2020

International audience; Among the various clay minerals, sepiolite, which is a natural nanofibrous silicate that exhibit a poor cell toxicity, is a potential promising nanocarrier for the non-viral and stable transfer of plasmid DNA into bacteria, mammalian and human cells. We first show here that sepiolite binds to bacteria, which can be useful in decontamination protocols. In a previous research we have shown that is possible to modulate the efficiency of the absorption of different types of DNA molecules onto sepiolite, and that the DNA previously adsorbed could be recovered preserving the DNA structure and biological activity. Taking advantage of both, the sepiolite/bacteria and sepioli…

[SDV.BIO]Life Sciences [q-bio]/Biotechnology[SDV]Life Sciences [q-bio]Sepiolite020101 civil engineering02 engineering and technology[SDV.BBM.BM] Life Sciences [q-bio]/Biochemistry Molecular Biology/Molecular biology0201 civil engineeringchemistry.chemical_compoundAdsorptionPlasmidPlasmid extractionGeochemistry and Petrology[CHIM]Chemical SciencesComputingMilieux_MISCELLANEOUSBacterial transformation[PHYS]Physics [physics]Bionanohybrids[CHIM.MATE] Chemical Sciences/Material chemistrybiologyChemistrySepioliteGeology[SDV.BBM.BM]Life Sciences [q-bio]/Biochemistry Molecular Biology/Molecular biologyDNA[CHIM.MATE]Chemical Sciences/Material chemistry021001 nanoscience & nanotechnologybiology.organism_classificationNanomaterialCombinatorial chemistryDNA extraction[SDV.BIO] Life Sciences [q-bio]/BiotechnologySepiolite Bionanohybrids Nanomaterial DNA Bacterial transformation Plasmid extractionNanocarriers0210 nano-technologyBacteriaDNATransformation efficiency
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Impact of stresses associated to climate changes on natural and induced grapevine resistance to pathogens

2013

France is a worldwide leader in grape production and has to face global changes including climate evolution and transitions towards sustainable systems of production. One major problem in viticulture is indeed the high susceptibility of most of the grown cultivars to cryptogamic diseases, such as downy mildew (Plasmopara viticola). Maintaining a satisfactory health status of grapevine currently requires numerous fungicide treatments. However, in an objective of sustainable viticulture, there is increasing societal request, winegrower awareness, and political incitation to reduce this use of pesticides. For these reasons, alternative strategies of protection are currently investigated at the…

[SDV] Life Sciences [q-bio]abiotic stressclimate evolutionresistant hybrids[SDV]Life Sciences [q-bio]food and beveragesprotection new stratégiesFranceviticulturedefence elicitorsglobal changebeneficial microorganisms
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RNase H1 and H2 are differentially regulated to eliminate RNA-DNA hybrids

2019

SUMMARYRNA-DNA hybrids are tightly regulated to ensure genome integrity. The RNase H enzymes, RNase H1 and H2, contribute to chromosomal stability through the removal of RNA-DNA hybrids. Loss of RNase H2 function is implicated in human diseases of the nervous system and cancer. To better understand RNA-DNA hybrid dynamics, we have focused on elucidating the regulation of the RNase H enzymes themselves. Using yeast as a model system, we demonstrate that RNase H1 and H2 are controlled in different manners. RNase H2 is regulated in a strict cell cycle dependent manner, both in terms of its R-loop removal, and ribonucleotide excision repair functions. RNase H1, however, can function independent…

chemistry.chemical_classificationEnzymechemistrybiologyRNase PRibonucleotide excision repairbiology.proteinRna dna hybridsCell cycleRNase HYeastFunction (biology)Cell biology
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Pyrene-Capped CdSe@ZnS Nanoparticles as Sensitive Flexible Oxygen Sensors in Non-Aqueous Media**

2014

A flexible, highly sensitive sensor of oxygen in non-aqueous solvents is described. It consists of CdSe/ZnS nanoparticles decorated with a considerable number of pyrene units, thus making the formation of the pyrene excimer possible. The emission of the pyrene excimer and that of the nanoparticle are suitably separated from each other and also from the excitation wavelength. This sensor can be applied as a ratiometric oxygen sensor by using the linear response of the pyrene excimer lifetime combined with the linear response of the nanoparticle excited state lifetime. This nanohybrid has been assayed in seven media with different dielectric constants and viscosities over the whole oxygen con…

chemistry.chemical_elementNanoparticleNanotechnologyGeneral ChemistryDielectricFull PapersratiometricPhotochemistryExcimersensorsOxygennanohybridschemistry.chemical_compoundchemistryExcited statePyreneLimiting oxygen concentrationorganic solventsOxygen sensoroxygenChemistryOpen
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