Search results for "Hydroxyindoles"

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Organocatalytic enantioselective functionalization of indoles in the carbocyclic ring with cyclic imines

2019

[EN] An organocatalytic enantioselective functionalization in the carbocyclic ring of indoles with benzoxathiazine 2,2-dioxides is described using a quinine-derived bifunctional organocatalyst. This aza-Friedel-Crafts reaction provides 4-indolyl, 5-indolyl and 7-indolyl sulfamidate derivatives in good yields (up to 99%) and with moderate to high enantioselectivities (up to 86% ee).

Alkylation02 engineering and technologyAlkylation010402 general chemistryRing (chemistry)01 natural sciencesHydroxyindolesCatalysisKetiminesReaccions químiqueschemistry.chemical_compoundMaterials ChemistryFriedel-Crafts reactionBifunctionalFriedel–Crafts reactionConstructionAsymmetric-SynthesisChemistryInhibitorsEnantioselective synthesisGeneral Chemistry021001 nanoscience & nanotechnologyCombinatorial chemistry0104 chemical sciencesFISICA APLICADASurface modification0210 nano-technologyQuímica orgànicaDerivatives

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