Search results for "I.2"

showing 10 items of 662 documents

MODELING OF A TiO2-COATED QUARTZ -WOOL PACKED-BED PHOTOCATALYTIC REACTOR

2010

A fixed-bed, photocatalytic laboratory reactor aimed to degrade pollutants from water streams was designed and built. Quartz wool coated with a thin film of TiO2 was employed as the reactor filling. The photocatalyst was placed in the reactor forming a loose packing to guarantee the intimate contact among reactants, photons, and the photocatalytic surface. This reactor was employed to study the photocatalytic decomposition of a model pollutant (formic acid). A reactor–radiation–reaction model was developed, which was comprised of the reactor mass balance, radiation model, and kinetic model for the degradation of formic acid. The local superficial rate of photon absorption, which was necessa…

Packed bedSettore ING-IND/26 - Teoria Dello Sviluppo Dei Processi ChimiciChemistryIngeniería de Procesos QuímicosProcess Chemistry and TechnologyQuartz woolSettore ING-IND/25 - Impianti Chimicipacked-bed reactor quartz wool photocatalysis TiO2 kinetics formic acid.Kinetic schemeMineralogyINGENIERÍAS Y TECNOLOGÍASKinetic energyCatalysisIngeniería QuímicaChemical engineeringMass transferPacked-bed reactorPhotocatalysisTiO2FiberPhysics::Chemical PhysicsPhotocatalysisPlug flow reactor modelAbsorption (electromagnetic radiation)General Environmental Science
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Gadd45α modulates aversive learning through post‐transcriptional regulation of memory‐related mRNA s

2018

Abstract Learning is essential for survival and is controlled by complex molecular mechanisms including regulation of newly synthesized mRNAs that are required to modify synaptic functions. Despite the well‐known role of RNA‐binding proteins (RBPs) in mRNA functionality, their detailed regulation during memory consolidation is poorly understood. This study focuses on the brain function of the RBP Gadd45α (growth arrest and DNA damage‐inducible protein 45 alpha, encoded by the Gadd45a gene). Here, we find that hippocampal memory and long‐term potentiation are strongly impaired in Gadd45a‐deficient mice, a phenotype accompanied by reduced levels of memory‐related mRNAs. The majority of the Ga…

Pain ThresholdUntranslated regionRegulatorGene ExpressionCell Cycle ProteinsHippocampusBiochemistryArticlememoryMice03 medical and health sciences0302 clinical medicineGeneticsAnimalsLearningRNA MessengerMolecular BiologyPost-transcriptional regulationGrin2a030304 developmental biologyMice Knockout0303 health sciencesMessenger RNANeuronal PlasticityBehavior AnimalbiologyLong-term potentiationArticlesRNA stabilityAmygdalaRNA BiologyCell biologyGene Expression Regulationbiology.proteinGRIN2ARNA InterferenceMemory consolidationGADD45A030217 neurology & neurosurgeryGadd45aNeuroscienceEMBO reports
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Partecipanti - XXVI Premio Compasso d'Oro ADI

2020

Mostra METTERE RADICI e relativo volume XXVI Compasso d'Oro ADI 2020. La ricerca è Finalista nella categoria "ricerca teorica, storica, critica [...]" al Compasso d'Oro ADI del 2020. L'Osservatorio Permanente dell'ADI ha selezionato la ricerca di Santo Giunta, edita da Marsilio, seconda edizione 2020, dal titolo: Carlo Scarpa, Una [curiosa ] lama di luce, un Gonfalone d'oro, le mani e un viso di donna. Riflessioni sul percorso progettuale per l'allestimento di Palazzo Abatellis. 1953-1954, Prefazione di Richard Murphy, Postfazione di Giampiero Bosoni. Exhibition METTERE RADICI its volume XXVI Compasso d'Oro ADI 2020. The research is also a Finalist in the category "theoretical, historical, …

Palazzo Abatellis Carlo Scarpatheoretical research Compasso d'Oro ADI 2020.Palazzo Abatellis Carlo Scarpa ricerca teorica Compasso d'Oro ADI 2020.Settore ICAR/14 - Composizione Architettonica E Urbana
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Santo Giunta, Carlo Scarpa. Una [curiosa] lama di luce, un gonfalone d'oro, le mani e un viso di donna, Marsilio Editori

2018

La riflessione sul processo progettuale per l'allestimento di Palazzo Abatellis (1953-54) di Carlo Scarpa, edita da Marsilio nel 2016, è stata selezionata nella categoria Ricerca teorico, storico, critica e progetti editoriali, all'INDEX 2018, ed è finalista al Compasso d'Oro ADI 2020. The reflection on the design process for the installation of Palazzo Abatellis (1953-54) by Carlo Scarpa, published by Marsilio 2016, was selected in the category of theoretical, historycal, critical research and publishing projects, at the INDEX 2018, and is a finalist at the Compasso d'Oro ADI 2020.

Palazzo Abatellis Carlo Scarpatheoretical research Compasso d'Oro ADI 2020.Settore ICAR/14 - Composizione Architettonica E Urbana
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Paper-TiO2 composite: An effective photocatalyst for 2-propanol degradation in gas phase

2018

Two simple routes for the synthesis of a paper-TiO2 composite were tuned up and the efficiency of the resulting paper-TiO2 photocatalyst was investigated in the 2-propanol oxidation in gas phase. The first route involved the in-situ generation over the sheet of paper of a TiO2 layer starting from a solution of Ti (OBu)4 in tert-butanoliacetic acid, followed by hydrothermal treatment at 120 degrees C for 3 h. The sample was labelled as paper-TiO2 (H). The second approach was based on the adsorption on the paper of a ready-made suspension of titania nanoparticles (TiO2 sol), generated in autoclave at 140 degrees C and stable in acid medium at pH <3. The sample was labelled as paper-TiO2 (S). …

PaperGeneral Chemical EngineeringComposite numberGeneral Physics and Astronomy02 engineering and technology010402 general chemistry01 natural sciencesAutoclavePropanolAcetic acidchemistry.chemical_compoundAdsorption2-propanolTiO2Organic chemistryChemical Engineering (all)Sol methodSunlight photocatalysisChemistryButanolChemistry (all)Hydrothermal methodSettore CHIM/06 - Chimica OrganicaGeneral Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesSunlight photocatalysiChemical engineeringPhotocatalysisDegradation (geology)Settore CHIM/07 - Fondamenti Chimici Delle Tecnologie0210 nano-technologyJournal of Photochemistry and Photobiology A: Chemistry
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TiO2/Ag2O immobilized on cellulose paper: A new floating system for enhanced photocatalytic and antibacterial activities

2021

Paper-TiO2-Ag2O floating photocatalysts were produced under mild condition and their photocatalytic activity for the degradation of aromatic amine under sunlight stimulant was investigated. Characterizations by Raman, XRD, XPS, DRS and PL confirmed the presence of TiO2 and Ag2O, and the morphology of the appended TiO2/Ag2O layer was probed by FE-SEM. The photocatalytic activity of the prepared samples was investigated by the degradation of aniline (AN) in water under simulated sun-light illumination and constrained conditions, i.e. non-stirring and non-oxygenation. The presence of Ag2O combined with TiO2 was shown to improve the resistance of paper to bacteria attack, thus increasing the du…

PaperMaterials science010501 environmental sciences01 natural sciencesBiochemistry03 medical and health sciencessymbols.namesakechemistry.chemical_compound0302 clinical medicineAnilineX-ray photoelectron spectroscopyTiO2–Ag2O heterojunctionPaper TiO2-Ag2O heterojunction Self-cleaning Surface functionalization Floating photocatalyst030212 general & internal medicineCellulose0105 earth and related environmental sciencesGeneral Environmental Sciencechemistry.chemical_classificationAromatic amineSettore CHIM/06 - Chimica OrganicaChemical engineeringchemistrySurface functionalizationsymbolsPhotocatalysisDegradation (geology)Surface modificationRaman spectroscopySelf-cleaningFloating photocatalyst
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Photocatalytic Degradation of Paraquat and Genotoxicity of its Intermediate Products

2007

Abstract The photocatalytic degradation of paraquat (1,1-dimethyl-4,4′-bipyridylium dichloride) aqueous solutions in the presence of polycrystalline TiO2 Degussa P25 irradiated by near-UV light was investigated. The substrate and total organic carbon concentrations were monitored by UV spectroscopy and TOC measurements, respectively: the complete photocatalytic mineralization of paraquat (20 ppm) was achieved after ca. 3 h of irradiation by using 0.4 g l−1 of catalyst amount at natural pH (ca 5.8). On the contrary no significant photodegradation of paraquat was observed in the absence of TiO2 under similar experimental conditions. To evaluate the genotoxicity of paraquat and its intermediat…

ParaquatSettore ING-IND/24 - Principi Di Ingegneria ChimicaGeneral Chemical EngineeringGeneral Physics and AstronomySubstrate (chemistry)General ChemistryPhotocatalyticGene mutationPhotochemistrymedicine.disease_causeAmes testchemistry.chemical_compoundParaquatchemistryMicronucleus testmedicinePhotocatalysisTiO2GenotoxicityPhotodegradationGenotoxicity
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On the photoreaction of some 1,2,4-oxadiazoles in the presence of2,3-dimethyl-2-butene. Synthesis of N-imidoyl-aziridines

2007

Fhe photochemistry of some 3,5-disubstituted 1,2,4-oxadiazoles in the presence of 2,3-dimethyl-2-butene has been investigated. The irradiation in acetonitrile yielded differently substituted N-imidoyl-aziridines through an aziridination reaction involving an acyliminonitrene intermediate. Pyrolysis of N-imidoyl-aziridines produced the corresponding N-allylamidines through a ring opening process.

PharmacologyphotochemistryOrganic Chemistry124-oxadiazoleGeneral MedicineRing (chemistry)Photochemistrypyrolysi2-ButeneAnalytical Chemistrychemistry.chemical_compoundN-allylamidinechemistryScientific methodOrganic chemistryIrradiationAcetonitrilePyrolysisN-imidoylaziridine
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Pbca-Type In2O3: The High-Pressure Post-Corundum phase at Room Temperature.

2014

High-pressure powder X-ray diffraction and Raman scattering measurements in cubic bixbyite-type indium oxide (c-In2O3) have been performed at room temperature. On increasing pressure c-In2O3 undergoes a transition to the Rh2O3-II structure but on decreasing pressure Rh2O3-II-type In2O3 undergoes a transition to a previously unknown phase with Pbca space group which is isostructural to Rh2O3-III. On further decrease of pressure, we observed a phase transition to the metastable corundum-type In2O3 near room conditions. Recompression of the metastable corundum-type In2O3 at room temperature leads to a transition to the Rh2O3-III phase, thus showing that the Rh2O3-III phase is the post-corundum…

Phase transitionAnalytical chemistryInitio molecular-dynamicschemistry.chemical_elementCrystal structureAmbient-pressureSynchrotronAb initio quantum chemistry methodsMetastabilityPhase (matter)Total-Energy calculationsPhysical and Theoretical ChemistryPhase diagramOxideSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsRhombohedral IN2O3CrystallographyGeneral EnergyCrystal-structurechemistryFISICA APLICADATransitionDiffractionIndiumWave basis-setAmbient pressureThe Journal of Physical Chemistry C
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A quantitative method of photoadsorption determination for irradiated catalyst in liquid–solid system

2009

WOS: 000266963000002

Photoadsorption determination TiO2 suspension Aromatic alcohol oxidationinorganic chemicalsSettore ING-IND/24 - Principi Di Ingegneria ChimicaPhotoadsorption DeterminationAqueous solutionAromatic Alcohol Oxidationorganic chemicalsInorganic chemistryTio2 SuspensionBinary compoundAlcoholGeneral ChemistryHeterogeneous catalysisCatalysisCatalysischemistry.chemical_compoundAdsorptionchemistryBenzyl alcoholPhotocatalysisOrganic chemistryheterocyclic compoundsSettore CHIM/07 - Fondamenti Chimici Delle TecnologieCatalysis Today
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