Search results for "INOCA"

showing 10 items of 76 documents

CCDC 136298: Experimental Crystal Structure Determination

2002

Related Article: A.J.Ayling, S.Broderick, J.P.Clare, A.P.Davis, M.N.Perez-Payan, M.Lahtinen, M.J.Nissinen, K.Rissanen|2002|Chem.-Eur.J.|8|2197|doi:10.1002/1521-3765(20020503)8:9<2197::AID-CHEM2197>3.0.CO;2-J

Space GroupCrystallographyCrystal SystemMethyl 3alpha-(p-nitrobenzenesulfonylamido)-7alpha12alpha-bis(p-nitrophenylaminocarbonyloxy)-5beta-cholan-24-oate acetone chloroform solvateCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 101414: Experimental Crystal Structure Determination

1998

Related Article: A.Shivanyuk, C.Schmidt, V.Bohmer, E.F.Paulus, O.Lukin, W.Vogt|1998|J.Am.Chem.Soc.|120|4319|doi:10.1021/ja9729286

Space GroupCrystallographyCrystal SystemNN'-Di-t-butyl- 24820-tetramethyl-1022-dihydroxy-461618-tetrakis(tosyloxy)-bis(56-k:5'6'-w)(13)oxazinocalix(4)arene hydrateCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 2077804: Experimental Crystal Structure Determination

2021

Related Article: Petr Vosáhlo, Léa Radal, Marine Labonde, Ivana Císařová, Julien Roger, Nadine Pirio, Jean-Cyrille Hierso, Petr Štěpnička|2021|Organometallics|40|1934|doi:10.1021/acs.organomet.1c00244

Space GroupCrystallographyCrystal Systemallyl-(1-(diphenylphosphino)-1'-(sulfonatomethylaminocarbonyl)ferrocene)-palladium chloroform solvateCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 117737: Experimental Crystal Structure Determination

1998

Related Article: A.Shivanyuk, C.Schmidt, V.Bohmer, E.F.Paulus, O.Lukin, W.Vogt|1998|J.Am.Chem.Soc.|120|4319|doi:10.1021/ja9729286

Space GroupCrystallographyNN'-Diadamantyl-24820-tetramethyl-1022-dihydroxy-461618-tetrakis(tosyloxy)-bis(56-k:5'6'-w)(13)oxazinocalix(4)arene chloroform dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

Application of palladium complexes bearing acyclic amino(hydrazido)carbene ligands as catalysts for copper-free Sonogashira cross-coupling

2015

Abstract Metal-mediated coupling of one isocyanide in cis-[PdCl2(CNR1)2] (R1 = C6H11 (Cy) 1, tBu 2, 2,6-Me2C6H3 (Xyl) 3, 2-Cl-6-MeC6H3 4) and various carbohydrazides R2CONHNH2 [R2 = Ph 5, 4-ClC6H4 6, 3-NO2C6H4 7, 4-NO2C6H4 8, 4-CH3C6H4 9, 3,4-(MeO)2C6H3 10, naphth-1-yl 11, fur-2-yl 12, 4-NO2C6H4CH2 13, Cy 14, 1-(4-fluorophenyl)-5-oxopyrrolidine-3-yl 15, (pyrrolidin-1-yl)C(O) 16, 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propane-1-yl 17, EtNHC(O) 18] or sulfohydrazides R3SO2NHNH2 [R3 = Ph 19, 4-MeC6H4 20] led to a series of (hydrazido)(amino)carbene complexes cis-[PdCl2{ C (NHNHX) N(H)R1}(CNR1)]; X = COR2, SO2R3 (21–48, isolated yields 60–96%). All prepared species were characterized by elemental…

StereochemistryIsocyanideArylchemistry.chemical_elementSonogashira couplingCopper-free Sonogashira couplingAcyclic diaminocarbenesNuclear magnetic resonance spectroscopyPalladium-(acyclic diminocarbene) catalystsMedicinal chemistryCatalysisCatalysischemistry.chemical_compoundchemistryCatalytic cycleMechanism of catalytic action of Pd-ADCsPhysical and Theoretical Chemistryta116CarbenePalladiumJournal of Catalysis

researchProduct

Pyrrhalta luteola e Tinicallis takachihoensis sugli olmi in Sicilia occidentale

1998

Ulmus sp. Pyrrhalta luteola Tinocallis takachihoensis.

researchProduct

Safety of micafungin in prospective and retrospective clinical trials

2012

Summary Managing fungal diseases remains a major challenge for clinicians despite the improved armamentarium of antifungal agents. This review identified 19 publications reporting safety data on micafungin. Two of these publications were spin off publications, the remaining 17 (15 prospective, two retrospective) were included in the main assessment. Major adverse events reported which occurred in more than 2% in the study populations were infusion-related, gastro-intestinal and hepatic (LFT parameters elevations). Micafungin demonstrated significantly less renal events compared with liposomal amphotericin B and less hepatic events compared with voriconazole. Compared with fluconazole no sig…

VoriconazolebiologyEchinocandinbusiness.industryMicafunginDermatologyGeneral Medicinebacterial infections and mycosesbiology.organism_classificationInfectious DiseasesImmunologymedicineChillsmedicine.symptombusinessAdverse effectCandida albicansEchinocandinsFluconazolemedicine.drugMycoses

researchProduct

CCDC 2077805: Experimental Crystal Structure Determination

2021

allyl-(11'-di-t-butyl-3-(diphenylphosphino)-3'-(sulfonatomethylaminocarbonyl)ferrocene)-palladium dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

Palladium(II)-Mediated Addition of Benzenediamines to Isocyanides: Generation of Three Types of Diaminocarbene Ligands Depending on the Isomeric Stru…

2016

Coupling of the palladium-bis(isocyanide) complexes cis-[PdCl2(CNR)2] (R = 2,6-Me2C6H3 1, 2-Cl-6-MeC6H3 2) with benzene-1,3-diamine (BDA1) leads to the diaminocarbene species cis-[PdCl2(CNR){C(NHR)═NH(1,3-C6H4NH2)}] (5 and 6, respectively). In this reaction, BDA1 behaves as a monofunctional nucleophile that adds to one of the RNC ligands by one amino group. By contrast, the reaction of 1 and 2 with benzene-1,4-diamine (BDA2) involves both amino functionalities of the diamine and leads to the binuclear species [cis-PdCl2(CNR){μ-C(NHR)═NH(1,4-C6H4)NH═C(NHR)}-(cis)-PdCl2(CNR)] (6 and 7) featuring two 1,4-bifunctional diaminocarbene ligands. The reaction of cis-[PdCl2(CNR)2] (R = cyclohexyl 3) …

benzenediamines010405 organic chemistryStereochemistryIsocyanideOrganic Chemistrychemistry.chemical_elementdiaminocarbenespalladium complexes010402 general chemistry01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistryNucleophileDiamineisomersPhysical and Theoretical ChemistryCarbeneta116PalladiumOrganometallics

researchProduct

Reacción aza-Michael intramolecular organocatalítica sobre enonas y derivados de ácido: nuevas estrategias

2016

Una de les metodologies més importants, junt amb la reacció de Mannich, per la formació d’enllaços carboni-nitrogen i per accedir a compostos b-amino carbonílics, és la reacció aza-Michael, que consisteix en l’addició conjugada d’una font de nitrogen nucleòfila a un sistema a,b-insaturat. Aquesta reacció adquireix una especial rellevància a la seua versió intramolecular ja que condueix a la formació d’heterocicles nitrogenats de forma senzilla. A més, quan l’olefina activada conté centres proquirals, al procés d’addició es generen un o més centres estereogènics, pel que la versió asimètrica d’esta reacció permetria obtenir compostos nitrogenats funcionalitats de forma estereoselectiva. Ment…

heterociclos nitrogenadosorganocatálisiscatálisis asimétricacompuestos beta-aminocarbonílicosUNESCO::QUÍMICAquímica orgánica:QUÍMICA [UNESCO]

researchProduct