Search results for "INTERACTION"

showing 10 items of 5710 documents

Ferromagnetic coupled μ-phenoxo-μ-carboxylato heterodinuclear complexes based on the Cr(salen) moiety: Structural and magnetic characterization

2009

The synthesis, crystal structure, and magneto-chemical characterization of two new unprecedented μ-phenoxo-μ-carboxylato heterodinuclear complexes based on the Cr(salen) moiety (salen = N,N′-bis(salicylidene)ethylenediamine), [MII(O2C(CH3)3)(OH2)2(μ-O2C(CH3)3)(μ-salen)CrIII(O2C(CH3)3)], M = Ni (2), Co(3) are reported. The dinuclear complexes were obtained starting from the mononuclear trans-[Cr(salen)(CN)2]PPh4 (1), whose crystal structure is also reported. They show a trans arrangement of the Cr(salen) unit, bridging through the phenolate O atoms to a second metal center. An additional μ2-O2-carboxylato bridge and a further monodentating carboxylate ligand complete the roughly octahedral C…

ANISOTROPYCoordination sphereChemistryOtras Ciencias QuímicasExchange interactionCiencias QuímicasEthylenediamineCrystal structureSINGLE-MOLECULE MAGNETSInorganic ChemistryMagnetizationCrystallographychemistry.chemical_compoundCOBALT(II) COMPLEXESOctahedronFerromagnetismCarboxylatePIVALATE COMPLEXESCIENCIAS NATURALES Y EXACTAS
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Texture - flavour cross-modal interactions in dairy desserts: physico-chemical or cognitive mecanisms?

2006

International audience

AROMASENSORYTASTE[SPI.GPROC] Engineering Sciences [physics]/Chemical and Process Engineering[SDV.IDA]Life Sciences [q-bio]/Food engineering[SPI.GPROC]Engineering Sciences [physics]/Chemical and Process EngineeringTEXTUREFLAVOUR[SDV.IDA] Life Sciences [q-bio]/Food engineeringPHYSICO-CHEMICALINTERACTIONDESSERTComputingMilieux_MISCELLANEOUS
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Nuclear anapole moment interaction in BaF from relativistic coupled-cluster theory

2018

We present high accuracy relativistic coupled cluster calculations of the P-odd interaction coefficient $W_A$ describing the nuclear anapole moment effect on the molecular electronic structure. The molecule under study, BaF, is considered a promising candidate for the measurement of the nuclear anapole moment, and the preparation for the experiment is now underway [Altunas et al., Phys. Rev. Lett. 120, 142501 (2018)]. Influence of various computational parameters (size of the basis set, treatment of relativistic effects, and treatment of electron correlation) on the calculated $W_A$ coefficient is investigated and a recommended value of 147.7 Hz with an estimated uncertainty of 1.5% is prop…

ATOMIC PARITY NONCONSERVATIONDIATOMIC-MOLECULESP-ODDVIOLATIONAtomic Physics (physics.atom-ph)Nuclear TheoryDENSITY FUNCTIONALSFOS: Physical sciences01 natural sciences010305 fluids & plasmasPhysics - Atomic PhysicsENHANCEMENTMolecular electronic structure0103 physical sciencesIMPLEMENTATIONNuclear Experiment010306 general physicsBasis setPhysicsElectronic correlationELECTRIC-FIELD GRADIENTSDiatomic moleculeWEAK-INTERACTIONSCoupled clusterMoment (physics)Atomic physicsRelativistic quantum chemistryAPPROXIMATIONPhysical Review A
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Binding mode analysis of ABCA7 for the prediction of novel Alzheimer's disease therapeutics

2021

Graphical abstract

ATP Adenosine-triphosphateNBD nucleotide binding domainGSH reduced glutathionePolypharmacologyAlzheimer’s disease (AD)ATP-binding cassette transporterHTS high-throughput screeningBiochemistryABCA7Structural BiologyPLIF protein ligand interactionMSD membrane spanning domainPDB protein data bankTM transmembrane helixABC ATP-binding cassetteMultitarget modulation (PANABC)RMSD root mean square distanceABC transporter (ABCA1 ABCA4 ABCA7)Computer Science ApplicationsMOE Molecular Operating EnvironmentPharmacophoreSNP single-nucleotide polymorphismBiotechnologyResearch ArticleBBB blood-brain barrierBiophysicsDrug designComputational biologyBiologyAD Alzheimer’s diseasePET positron emission tomographyIC intracellular helixAPP amyloid precursor proteincryo-EM cryogenic-electron microscopyGeneticsHomology modelingBinding siteRational drug design and developmentComputingMethodologies_COMPUTERGRAPHICSNBD-cholesterol 7-nitro-2-13-benzoxadiazol-4-yl-cholesterolTransporterPSO particle swarm optimizationPET tracer (PETABC)ECD extracellular domainR-domain/region regulatory domain/regionABCA1biology.proteinEH extracellular helixTP248.13-248.65BODIPY-cholesterol 44-difluoro-4-bora-3a4a-diaza-s-indacene-cholesterolComputational and Structural Biotechnology Journal
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Machine learning of microbial interactions using abductive ILP and hypothesis frequency/compression estimation

2021

Interaction between species in microbial communities plays an important role in the functioning of all ecosystems, from cropland soils to human gut microbiota. Many statistical approaches have been proposed to infer these interactions from microbial abundance information. However, these statistical approaches have no general mechanisms for incorporating existing ecological knowledge in the inference process. We propose an Abductive/Inductive Logic Programming (A/ILP) framework to infer microbial interactions from microbial abundance data, by including logical descriptions of different types of interaction as background knowledge in the learning. This framework also includes a new mechanism …

Abductive/Inductive Logic Programming (A/ILP)[SDV] Life Sciences [q-bio]inferencehypothesis frequencymachine learning of ecological networksinteraction networkcomputer scienceestimation (HFE)
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Apprentissage automatique de réseaux d'interaction à partir de données de séquences de nouvelle génération

2022

Climate change and other human-induced processes are modifying ecosystems, globally, at an ever increasing rate. Microbial communities play an important role in the functioning ecosystems, maintaining their diversity and services. These communities are shaped by the different abiotic environmental effects to which they are subjected and the biotic interactions between all community members. The ANR Next-Generation Biomonitoring (NGB) project proposed to reconstruct interaction networks from abundance measures obtained sequencing environmental DNA (eDNA) and to use these networks to monitor ecosystem change. In this thesis, conducted as part of the NGB project, I evaluate the potential of tw…

Abductive/Inductive Logic Programming (A/ILP)apprentissage automatique explicableInteraction networksbiological controlséquençage de nouvelle générationmicrobial ecologygrapevine[SDE.BE] Environmental Sciences/Biodiversity and Ecology[SDV] Life Sciences [q-bio]Plasmopara viticolamicrobiomesréseaux d'InteractionNext-Generation sequencingbiomonitoringexplainable machine learning
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Fundamentals of 3D imaging and displays: a tutorial on integral imaging, light-field, and plenoptic systems

2018

There has been great interest in researching and implementing effective technologies for the capture, processing, and display of 3D images. This broad interest is evidenced by widespread international research and activities on 3D technologies. There is a large number of journal and conference papers on 3D systems, as well as research and development efforts in government, industry, and academia on this topic for broad applications including entertainment, manufacturing, security and defense, and biomedical applications. Among these technologies, integral imaging is a promising approach for its ability to work with polychromatic scenes and under incoherent or ambient light for scenarios fro…

Ability to workImatges tridimensionals en medicinaIntegral imagingGeometrical opticsComputer science02 engineering and technologyÒptica021001 nanoscience & nanotechnologyPhysical optics01 natural sciencesAtomic and Molecular Physics and Optics010309 opticsOptical imagingHuman–computer interaction0103 physical sciencesMedical imagingHolographic display0210 nano-technologyLight fieldImatges Processament Tècniques digitals
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Factors controlling planktonic size spectral responses to autumnal circulation in a Mediterranean lake

2006

14 pages, and figures, and tables statistics.

Abiotic componentEcologyMixed layerfungiFood websCascading effectsAquatic SciencePlanktonMixing depthFood webOceanographyPhytoplanktonPhysical forcingEnvironmental scienceFactor interactionTrophic cascadeHydrobiologyTrophic levelFreshwater Biology
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Vertical spectrum of ethene: uncontracted versus contracted correlation methods and the role of the adapted molecular orbitals

1998

Abstract Ethylene vertical excitation energies (VEE) below 9.5 eV have been calculated with the complete active-space singles and doubles configuration interaction self-consistent size-consistent dressing (SC) 2 CAS–SDCI. The mean of the absolute deviation from experiment for the calculated VEE are 0.14, 0.05 and 0.03 eV for three different molecular orbital (MO) sets tried. The results show that an uncontracted method and a realistic MO set avoid the difficulties present in the calculation of the strongly mixed Rydberg-valence 1B 1u states.

Absolute deviationChemistrySpectrum (functional analysis)General Physics and AstronomyMolecular orbitalCorrelation methodPhysical and Theoretical ChemistryConfiguration interactionAtomic physicsExcitationChemical Physics Letters
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Synthesis and Physical Stability of Novel Au-Ag@SiO<SUB>2</SUB> Alloy Nanoparticles

2012

The present study describes the synthesis of nanoparticles of silver-gold alloys and with their electrokinetic and spectroscopic characterisation. The synthesis was made in two steps. In the first step silver nanoparticles coated with silica (Ag@SiO2) were synthesised using a novel method assisted by laser ablation. The second step consisted on the introduction of KAuCl4 in the colloidal solution of Ag@ SiO2 nanoparticles in order to obtain silica-coated silver-gold alloy nanoparticles. The changes of colour and mean diameter of Ag@SiO2 nanoparticles caused by the introduction of the gold salt were found dependent on its concentration. Upon increasing (KAuCl4) the diameter of nanoparticles …

AbsorbanceColloidMaterials scienceAlloyAnalytical chemistryengineeringNanoparticleDLVO theoryInteraction energyengineering.materialSurface plasmon resonanceSilver nanoparticleNanoscience and Nanotechnology
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