Search results for "INVESTIGATION"

showing 10 items of 366 documents

La diagnostica chimico-fisica a supporto della conservazione e del restauro delle opere cartacee

2017

Questo contributo è stato prodotto a seguito dell’intervento del Prof. Caponetti e della sessione laboratoriale guidata dalla Dott.ssa Saladino in collaborazione con il Dott. Renda e la Dott.ssa Chirco in cui è stata realizzata una dimostrazione pratica di come si possano eseguire le indagini di materiale cartaceo con strumentazione portatile. Nel presente contributo sono presentate e illustrate alcune delle tecniche di indagine idonee per l’analisi di opere cartacee, ed in particolare alcune di quelle che possono essere applicate mediante strumentazione portatile. Queste tecniche forniscono informazioni complementari e consentono la conoscenza dell’opera stessa (tipologia di carta, tecnica…

Conservation of ancient paper non-invasive investigationsConservazione carta antica indagini non invasiveSettore CHIM/02 - Chimica Fisica
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Thermally Induced Structural Modification of Silica Nanoparticles Investigated by Raman and Infrared Absorption Spectroscopies

2010

We report an experimental investigation by Raman and infrared (IR) absorption spectroscopies on the structural modifications induced by isochronal thermal treatments on amorphous SiO2 nanoparticles (fumed silica). In particular, three different commercial types of this material, characterized by particle mean diameters of 7, 14, and 40 nm, were subjected to thermal treatments from 100 up to 1000 °C. We found that some properties of fumed silica, such as the SiOSi mean bond angle, ring size distribution, and surface adsorbed water content, are drastically different from those of common bulk silica materials and intimately related to the particles' dimension. The SiOSi mean bond angle, probed…

Core shellSintering effectAnalytical chemistryDehydroxylationSilica nanoparticleSurface shellThermal treatmentTypical valueNanoparticleSinteringFumed silicaThermal treatmentThree-membered ringeducation.field_of_studyWater contentAdsorbed waterRaman lineAtomic networkSilicaThermally inducedSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsSurfaceGeneral EnergysymbolsNetwork structureAbsorption (chemistry)IR measurementMaterials scienceAbsorption spectroscopyStrained structurePopulationInfrared imagingInfrared spectroscopyAbsorptionsymbols.namesakeAdsorptionAbsorption spectroscopyHighly strainedShells (structures)Physical and Theoretical ChemistryeducationFumed silicaNano silica Raman proprieta' strutturaliExperimental investigationParticle mean diameterBond angleStructural modificationSilica materialRaman spectroscopy
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Binding properties of mono-6-amino-beta-cyclodextrin towards p-nitroaniline derivatives: a polarimetric study

Cyclodextrins host-guest interactions stability constants polarimetric investigationSettore CHIM/06 - Chimica Organica
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A cluster of cuticle protein genes of Drosophila melanogaster at 65A: sequence, structure and evolution

1997

0016-6731 (Print) Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S.; A 36-kb genomic DNA segment of the Drosophila melanogaster genome containing 12 clustered cuticle genes has been mapped and partially sequenced. The cluster maps at 65A 5-6 on the left arm of the third chromosome, in agreement with the previously determined location of a putative cluster encompassing the genes for the third instar larval cuticle proteins LCP5, LCP6 and LCP8. This cluster is the largest cuticle gene cluster discovered to date and shows a number of surprising features that explain in part the genetic complexity of the LCP5, LCP6 and LCP8 loci. The genes encoding LCP5 a…

DNA ComplementaryEvolutionMolecular Sequence DataGene DosageSequence HomologyArthropod cuticleInvestigationsGenomeEvolution MolecularSequence Homology Nucleic AcidComplementaryGene clusterGeneticsAnimalsDrosophila melanogaster/*geneticsGene conversionGeneCuticle (hair)GeneticsGenomebiologyNucleic AcidBase SequenceIntronMolecularDNAbiology.organism_classificationInsect Proteins/*geneticsDrosophila melanogasterMultigene FamilyInsect ProteinsDrosophila melanogaster
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Degradation study of XVIII century graffiti on the walls of Chiaramonte Palace (Palermo, Italy)

2010

A systematic investigation of the original materials and the degradation phenomena induced by soluble salts on the wall matrix and on the graffiti of the Inquisition jails of Chiaramonte Palace in Palermo (Italy) was carried out. Built in the XIV century, Chiaramonte Palace was used as Inquisition court during the XV–XVI centuries. The ancient graffiti, recently discovered, represent a unique historical witness of the prisoners that lived during that terrible period. In order to study the nature, the amount and the distribution of the salts in the masonry, stone materials sampled at different depth from the wall matrix and saline efflorescences were analysed. Different physical techniques w…

Degradation studyXRDmedia_common.quotation_subjectXRFMineralogyStone materialsX ray fluorescenceXPSGeneral Materials ScienceWall paintingHistorical heritageIonic chromatographyConservation treatmentmedia_commonConservation treatmentIonic chromatographyCharacterisationSystematic investigationGeneral ChemistryArtCrystallisationSulphateGraffitiArchaeologySoluble saltWall matrixPhysical characterisationRelative humiditie
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Finite Element Method and Von Mises Investigation on Bone Response to Dynamic Stress with a Novel Conical Dental Implant Connection

2020

The bioengineering and medical and biomedical fields are ever closer, and they manage to obtain surprising results for the development of new devices. The field of simulations and studies in silica has undergone considerable development in recent years, favoring the advancement of medicine. In this manuscript, a study was carried out to evaluate the force distribution on the implant components (In-Kone® Universal) and on the peri-implant tissues subjected to loading. With the finite element analysis and the Von Mises method, it was possible to evaluate this distribution of forces both at 0 degrees (occlusal force) and at 30 degrees; the applied force was 800 N. The obtained results on this …

Dental Stress AnalysisField (physics)Article SubjectComputer sciencemedicine.medical_treatmentFinite Element AnalysisBiomedical EngineeringGeneral Biochemistry Genetics and Molecular BiologyBone and BonesBite ForceStress (mechanics)03 medical and health sciences0302 clinical medicinemedicinevon Mises yield criterionHumansDental implantDental ImplantsGeneral Immunology and Microbiologybusiness.industryR030206 dentistryGeneral MedicineConical surfaceStructural engineeringFinite element methodConnection (mathematics)MedicineDevelopment (differential geometry)Stress Mechanicalbusiness030217 neurology & neurosurgeryFinite Element Method Von Mises Investigation Bone Response Conical Dental Implant ConnectionResearch Article
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Klimt artwork: red-pigment material investigation by backscattering Fe-57 Mössbauer spectroscopy, SEM and p-XRF

2017

Material tests were performed on a rediscovered Klimt-artwork "Trompetender Putto". We performed studies on the red colored spots, mainly taken from non-restored parts. MIMOS II Fe-57 Mossbauer spectroscopy (novelty in art-pigment analysis) mainly reveals haematite and crystallized goethite in red colors. Electron microscopy can identify various layers of the original and overpainting of an artwork. The number of layers fluctuates between three and four chemically painted areas. The portable X-ray fluorescence analysis enables to reduce the pigment list to containing mercury (cinnabar), lead, zinc, iron and titanium. Infrared-light-irradiation visualizes the different age of the pigments.

Dewey Decimal Classification::500 | Naturwissenschaften::540 | ChemieArcheologyGoethiteMaterials scienceScanning electron microscopepigmentsAnalytical chemistryinfra-red-light investigationchemistry.chemical_elementZinc01 natural sciencesKlimt: “Trompetender Putto”PigmentMaterialcharakterisierung0103 physical sciencesMössbauer spectroscopy0601 history and archaeologyddc:750lcsh:CC1-960010306 general physics060102 archaeologyTrompetender PuttoMössbauer spectroscopy06 humanities and the artsDewey Decimal Classification::700 | Künste Bildende Kunst allgemein::750 | MalereiOverpaintingKlimt GustavDewey Decimal Classification::700 | Künste Bildende Kunst allgemeinCinnabarchemistryPigmentvisual_artddc:540visual_art.visual_art_mediumddc:660lcsh:ArchaeologyX-ray fluorescence analysisddc:700660 Technische Chemiescanning electron microscopyTitanium
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Methods to investigate coronary microvascular function in clinical practice.

2012

A growing amount of data is increasingly showing the relevance of coronary microvascular dysfunction (CMVD) in several clinical contexts. This article reviews techniques and clinical investigations of the main noninvasive and invasive methods proposed to study coronary microcirculation and to identify CMVD in the presence of normal coronary arteries, also trying to provide indications for their application in clinical practice.

Diagnostic Imagingmedicine.medical_specialtymyocardial contrast echocardiographyCoronary microcirculationCoronary Artery DiseaseCoronary microvascular functionDiagnostic toolsintracoronary Doppler ultrasoundMicrocirculationcoronary microcirculationtransthoracic Doppler echocardiographyCoronary artery diseaseCoronary circulationcardiovascular magnetic resonanceInternal medicineCoronary CirculationmedicineDIAGNOSTIC TOOLSHumansNormal coronary arteriesbusiness.industryMicrocirculationGeneral Medicinemedicine.diseaseSettore MED/11 - Malattie Dell'Apparato Cardiovascolarediagnostic investigationClinical PracticeMyocardial contrast echocardiographymedicine.anatomical_structurePETcardiovascular magnetic resonance; coronary microcirculation; diagnostic investigation; intracoronary Doppler ultrasound; myocardial contrast echocardiography; PET; transthoracic Doppler echocardiography; Coronary Artery Disease; Coronary Circulation; Diagnostic Imaging; Humans; Microcirculation; Cardiology and Cardiovascular MedicineSettore MED/11 - MALATTIE DELL'APPARATO CARDIOVASCOLARECardiologymicrovascular functionHEARTCORONARYbusinessCardiology and Cardiovascular Medicine
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Self-reported nonceliac wheat sensitivity in an outpatient digestive endoscopy center: high frequency but insufficient medical approach.

2021

Objective: 'Self-reported wheat sensitivity' (SRWS) is a self-reported condition caused by wheat ingestion in the absence of celiac disease or wheat allergy. The aim of the study was to investigate the frequency and characteristics of SRWS in outpatients referred for digestive endoscopy. Methods: The study, performed at the University of Palermo, enrolled 496 outpatients. Results: Seven individuals (1.4%) had an already established diagnosis of celiac disease. The questionnaire was administered to the other 489 individuals: 98 subjects (20%) were SRWS, the remaining 391 served as controls (i.e. not-SRWS). SRWS patients were younger (P < 0.001), with a higher percentage of females (P = 0.…

DiarrheaMalemedicine.medical_specialtyAllergySettore MED/09 - Medicina InternaGlutensnon-celiac wheat sensitivityColonoscopydyspepsiaWheat HypersensitivityAsymptomaticEndoscopy GastrointestinalDiet Gluten-FreeIntolerancesInternal medicineOutpatientsmedicineHypersensitivityHumansendoscopygastro-esophageal refluxDepression (differential diagnoses)gluten-related diseaseirritable bowel syndromeHepatologymedicine.diagnostic_testinvestigationbusiness.industryGastroenterologymedicine.diseaseDiarrheaCeliac DiseaseGERDFemaleSelf Reportmedicine.symptombusinessWheat allergyEuropean journal of gastroenterologyhepatology
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On-line photoreaction and fluorimetric determination of diazepam.

1993

DiazepamChemistryUltraviolet RaysClinical BiochemistryAnalytical chemistryPharmaceutical ScienceFluorescence spectroscopyAnalytical ChemistryInvestigation methodsSpectrometry FluorescenceDrug DiscoveryCalibrationFlow Injection AnalysisLine (text file)Quantitative analysis (chemistry)SpectroscopyJournal of pharmaceutical and biomedical analysis
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