Search results for "ISOC"

showing 10 items of 301 documents

Effect of sodium dodecyl sulphate and Brij-35 on the analysis of sulphonamides in physiological samples using direct injection and acetonitrile gradi…

2016

Micellar liquid chromatography (MLC) is a reversed-phase (RP) mode, which often does not require gradient elution, since the peaks of mixtures of compounds within a large range of polarities appear more evenly distributed in the chromatograms of isocratic elution, giving rise to a “gradient effect”. However, the use of a gradient of organic solvent may still be convenient to shorten the total analysis time. This work compares the separation of 15 sulphonamides using conventional hydro-organic RPLC and MLC with the surfactants sodium dodecyl sulphate (SDS) and Brij-35, and both isocratic and gradient elution with acetonitrile. The observed behaviour is rationalized attending to the interacti…

Isocratic elutionChromatographyChemistryElutionGeneral Chemical EngineeringSodium010401 analytical chemistryGeneral EngineeringAnalytical chemistrychemistry.chemical_element010402 general chemistry01 natural sciences0104 chemical sciencesAnalytical Chemistrychemistry.chemical_compoundStationary phaseMicellar liquid chromatographyPhase (matter)AlkylbenzenesAcetonitrileAnalytical Methods
researchProduct

Modeling of Retention in Reversed Phase Liquid Chromatography

2015

Isocratic elutionChromatographyElutionChemistryHydrophilic interaction chromatographyGradient elutionReversed-phase chromatography
researchProduct

Topical Application of Glycolipids from Isochrysis galbana Prevents Epidermal Hyperplasia in Mice

2017

Chronic inflammatory skin diseases such as psoriasis have a significant impact on society. Currently, the major topical treatments have many side effects, making their continued use in patients difficult. Microalgae have emerged as a source of bio-active molecules such as glycolipids with potent anti-inflammatory properties. We aimed to investigate the effects of a glycolipid (MGMG-A) and a glycolipid fraction (MGDG) obtained from the microalga Isochrysis galbana on a TPA-induced epidermal hyperplasia murine model. In a first set of experiments, we examined the preventive effects of MGMG-A and MGDG dissolved in acetone on TPA-induced hyperplasia model in mice. In a second step, we performed…

Keratinocytes0301 basic medicineglycolipidsAdministration Topicalmedicine.medical_treatmentPharmaceutical SciencePharmacologyIsochrysis galbanaOintmentsMGDGMiceDrug DiscoveryMicroalgaelcsh:QH301-705.5Pharmacology Toxicology and Pharmaceutics (miscellaneous)Skinintegumentary systembiologyChemistrymicroalgaeHaptophytaHyperplasiaepidermal hyperplasiaCytokineIsochrysis galbanaCytokinesTetradecanoylphorbol AcetateFemalemedicine.drugskinglycolipids; <b>MGDG</b>; skin; inflammation; epidermal hyperplasia; microalgae; <i>Isochrysis galbana</i>Cell SurvivalDrug CompoundingSkin AbsorptionSkin DiseasesArticle03 medical and health sciencesGlycolipidIn vivoPsoriasismedicineAnimalsHumansDexamethasoneInflammationHyperplasiamedicine.diseasebiology.organism_classificationEpidermal hyperplasia030104 developmental biologylcsh:Biology (General)inflammationGlycolipidsEx vivoMarine Drugs
researchProduct

Metodes izstrāde oligonukleotīdu saistības termodinamisku parametru noteikšanai

2020

Maģistra darbā ir oligonukleotīdu dizainēšana, lai varētu detektēt fluorescentus kušanas līknes. Literatūras apskatā aprakstītas metodes, kas pielietotas oligonukleotīdu termodinamisko parametru noteikšanai. Tika izpētīti optimālie parametri fluorescentu kušanas grafiku uzņemšanai. Iegūtie rezultāti paver iespēju jaunai metodei, lai izpētītu termodinamiskos parametrus oligonukleotīdiem.

KinētikaFluorescences spektroskopijaDisociācijas konstanteTermodinamikaĶīmija
researchProduct

Personības iezīmju saistība ar vērtējumu par antisociālu uzvedību

2022

Kad runa ir par cilvēku uzvedības un antisociālas uzvedības prognozēšanu, izmantojot personības iezīmes, izrādās, uzdevums ir diezgan sarežģīts. Dažos pētījumos ir atrasti ietekmīgi pierādījumi korelācijai, bet citos tie netiek atrasti. Ikviens var kļūt par antisociālas uzvedības upuri, tā pat kā jebkurš to var veikt. Katrs cilvēks ir indivīds, kura domas, uzskati un vērtības var atšķirties no pārējiem. Tādējādi šīs atšķirības ietekmē arī indivīda skatījumu un toleranci pret antisociālu uzvedību un cilvēkiem, kuri uzvedas antisociāli. Vai pastāv saikne starp indivīda personības iezīmēm un veidu, kā viņi uztver antisociālu uzvedību? Šajā pētījumā mēs meklējam korelācijas starp Lielā piecinie…

Korelatīvs pētijumsPsiholoģijaPersonības iezīmesLielais piecinieksAntisociāla uzvedība
researchProduct

Preparation and reactions of palladium(II) complexes with C2-bonded heteroaromatic ligands trans[PdCl(RN)(PPh3)2] (RN = 2-pyridyl, 2-pirazyl, 2-pyrim…

1986

Abstract The complexes trans -[PdCl(R N )(PPh 3 ) 2 ] (I) [R N = 2-pyridyl (2-Py), 2-pyrazyl (2-pyz), 2-pyrimidyl (2-pym) group] have been prepared in high yield by deprotonation with NEt 3 of the corresponding cationic compounds trans [PdCl(R N H) (PPh 3 ) 2 ] + (R N H = N -protonated C 2 -heteroaromatic ligand) in the presence of an excess of PPh 3 . In chlorinated solvents, complexes I undergo a slow reversible dimerization into the binuclear derivatives [PdCl(μ-R N )(PPh 3 )] 2 (II) (μ-R N = C 2 , N 1 -bridging ligand). From the 31 P NMR spectra in 1,2-dichloroethane the following dissociation constants were obtained: 1.9 mol 1 −1 (R N = 2-py), 5.1 × 10 −2 (2-pym), 6.6 × 10 −3 (2-pyz). …

LigandStereochemistryIsocyanideDimerOrganic ChemistryMigratory insertionBridging ligandNuclear magnetic resonance spectroscopyBiochemistryInorganic Chemistrychemistry.chemical_compoundDeprotonationchemistryMaterials ChemistryPhysical and Theoretical ChemistryTriphenylphosphineJournal of Organometallic Chemistry
researchProduct

Genetic Influences on Alcohol Use Behaviors Have Diverging Developmental Trajectories: A Prospective Study Among Male and Female Twins

2014

Background Both alcohol-specific genetic factors and genetic factors related to externalizing behavior influence problematic alcohol use. Little is known, however, about the etiologic role of these 2 components of genetic risk on alcohol-related behaviors across development. Prior studies conducted in a male cohort of twins suggest that externalizing genetic factors are important for predicting heavy alcohol use in adolescence, whereas alcohol-specific genetic factors increase in importance during the transition to adulthood. In this report, we studied twin brothers and sisters and brother–sister twin pairs to examine such developmental trajectories and investigate whether sex and cotwin se…

MaleAdolescentAlcohol DrinkingPopulationTwinsMedicine (miscellaneous)ToxicologyArticleDevelopmental psychologyCohort StudiesYoung Adult5. Gender equalitymedicineHumansLongitudinal StudiesProspective StudiesYoung adultChild10. No inequalityeducationProspective cohort studyFinlandeducation.field_of_studyAntisocial personality disorderAlcohol dependenceta3142medicine.diseasePsychiatry and Mental healthConduct disorderPopulation SurveillanceCohortFemalePsychologyCohort studyClinical psychologyAlcoholism: Clinical and Experimental Research
researchProduct

Contribution of Motivational Climates and Social Competence in Physical Education on Overall Physical Activity: A Self-Determination Theory Approach …

2020

Using a cross-sectional study design, we tested a structural equation model of hypothesized relationships among a group of variables: motivational climate in physical education (PE), students&rsquo

MaleAdolescentHealth Toxicology and Mutagenesismedia_common.quotation_subjectSelf-conceptlcsh:MedicineEmpathylapset (ikäryhmät)prososiaalisuusArticlePhysical educationDevelopmental psychologyalakouluprimary schoolSocial Skills03 medical and health sciences0302 clinical medicineSocial skillskoululiikuntaprosocial behaviormotivaatioilmastoHumans030212 general & internal medicineChildliikuntaharrastusExerciseSelf-determination theorymedia_commonMotivationPhysical Education and TrainingAmotivationlcsh:Rsosiaaliset taidotstructural equation modelPublic Health Environmental and Occupational Health030229 sport sciencesrakenneyhtälömallitSelf ConceptCross-Sectional StudiesProsocial behaviorantisocial behaviorSocial competenceFemalepoikkeava käyttäytyminenfyysinen aktiivisuusInternational Journal of Environmental Research and Public Health
researchProduct

Action Representation in Patients with Bilateral Vestibular Impairments

2011

During mental actions subjects feel themselves performing a movement without any corresponding motor output. Although broad information is available regarding the influence of central lesions on action representation, little is known about how peripheral damages affect mental events. In the current study, we investigated whether lack of vestibular information influences action representation. Twelve healthy adults and twelve patients with bilateral vestibular damage actually performed and mentally simulated walking and drawing. The locomotor paths implied one (first walking task) and four (second walking task) changes in the walking direction. In the drawing task, participants drew on a she…

MaleAnatomy and PhysiologyPsychologie appliquéelcsh:MedicineIMAGERYTask (project management)Behavioral NeuroscienceBODYlcsh:ScienceVestibular systemMovement DisordersMultidisciplinaryLOCOMOTIONParietal lobeMiddle AgedSciences bio-médicales et agricolesTEMPORAL FEATURESNeurologyVestibular Diseases[ SCCO.NEUR ] Cognitive science/NeuroscienceMedicineFemaleSIMULATED MOTOR ACTIONSBiologieResearch ArticleAdultREHABILITATIONmedicine.medical_specialtyIsochronyCognitive NeuroscienceNeurophysiologyBiologyEXECUTIONAffect (psychology)Neurological SystemPhysical medicine and rehabilitationMotor systemmedicineHumansBiologyARM MOVEMENTSMotor Systemslcsh:RPERFORMANCEMENTAL PRACTICEAction (philosophy)Case-Control StudiesGait analysislcsh:QNeuroscience
researchProduct

Predictability of oppositional defiant disorder and symptom dimensions in children and adolescents with ADHD combined type.

2010

BackgroundOppositional defiant disorder (ODD) is frequently co-occurring with attention deficit hyperactivity disorder (ADHD) in children and adolescents. Because ODD is a precursor of later conduct disorder (CD) and affective disorders, early diagnostic identification is warranted. Furthermore, the predictability of three recently confirmed ODD dimensions (ODD-irritable, ODD-headstrong and ODD-hurtful) may assist clinical decision making.MethodReceiver-operating characteristic (ROC) analysis was used in order to test the diagnostic accuracy of the Conners' Parent Rating Scale revised (CPRS-R) and the parent version of the Strength and Difficulties Questionnaire (PSDQ) in the prediction of …

MaleBOYSPsychometricsSocial Sciences3202 Applied PsychologyDevelopmental psychology2738 Psychiatry and Mental Health0302 clinical medicineDEFICIT-HYPERACTIVITY DISORDEROPERATING CHARACTERISTIC ANALYSISPerception and Action [DCN 1]ChildDIFFICULTIES QUESTIONNAIRE SDQApplied PsychologyMental Health [NCEBP 9]Parenting05 social sciencesANTISOCIAL-BEHAVIORLONGITUDINAL COURSE10058 Department of Child and Adolescent PsychiatryPrognosisConfirmatory factor analysisPsychiatry and Mental healthConduct disorderAttention Deficit and Disruptive Behavior DisordersChild PreschoolRegression AnalysisFemalemedicine.symptomPsychology050104 developmental & child psychologyAdolescenteducation610 Medicine & healthIrritabilityEXECUTIVE DYSFUNCTION03 medical and health sciencesRating scalePredictive Value of Testsmental disordersmedicineAttention deficit hyperactivity disorderHumans0501 psychology and cognitive sciencesBEHAVIOR CHECKLISTPsychiatric Status Rating ScalesParent Rating Scalesmedicine.disease030227 psychiatryROC CurveRATING-SCALESAttention Deficit Disorder with HyperactivityCONDUCT DISORDERExecutive dysfunction
researchProduct