Search results for "ISOC"
showing 10 items of 301 documents
Bright Blue Phosphorescence from Cationic Bis-Cyclometalated Iridium(III) Isocyanide Complexes
2012
We report new bis-cyclometalated cationic indium(III) complexes [((CN)-N-boolean AND)(2)Ir(CN-tert-Bu)(2)](CF3SO3) that have tert-butyl isocyanides as neutral auxiliary ligands and 2-phenylpyridine or 2-(4'-fluoropheny1)-R-pyridines (where R is 4-methoxy, 4-tert-butyl, or 5-trifluoromethyl) as (CN)-N-boolean AND ligands. The complexes are white or pale yellow solids that show irreversible reduction and oxidation processes and have a large electrochemical gap of 3.58-3.83 V. They emit blue or bluegreen phosphorescence in liquid/solid solutions from a cyclometalating-ligand-centered excited state. Their emission spectra show vibronic structure with the highest-energy luminescence peak at 440-…
Sapphire-bearing magmatic rocks trace the boundary between paleo-continents: A case study of Ilmenogorsky alkaline complex, Uralian collision zone of…
2021
Abstract Metamorphic gem corundum (mainly ruby) deposits are robust indicators of continent-continent collision processes. However, a systematic link of primary magmatic blue sapphire occurrences to orogenic belts is less understood. An example is the Ilmenogorsky alkaline complex, within the Ilmen Mountains region and part of the Uralian orogenic belt. The mobile belt is a product of the collision among Kazakhstania, Laurussia, and Siberia continents prior to the closure of the Paleo-Uralian ocean and formation of the Laurasia supercontinent (330–250 Ma). It is believed that the alkaline complex became inсluded into the separate Sysertsk-Ilmenogorsk microcontinent with unconstrained border…
Young ages from old garnet in the polyphase metamorphic terrane of the Limpopo Belt, South Africa
2020
Abstract The P–T–t path of high-grade metamorphic rocks is significant for understanding vertical motions and heating of the crust. In general, garnet is used to constrain P–T paths and metamorphic zircon is used to obtain t for different metamorphic stages. However, this approach may be complicated by polyphase tectonothermal events. The Central Zone of the Limpopo Belt in South Africa is a complex Precambrian metamorphic terrane that has experienced three distinct high-grade metamorphic events at 3.22 Ga (M1), 2.62 Ga (M2), and 2.02 Ga (M3), based on zircon dating. A previous investigation of a metapelite enclave in the Bulai pluton in the Central Zone showed that metamorphic zircon in th…
Evolution of Pan-African island arc assemblages in the southern Red Sea Hills, Sudan, and in southwestern Arabia as exemplified by geochemistry and g…
1991
Kr6ner, A., Linnebacher, P., Stern, R.J., Reischmann, T., Manton, W. and Hussein, I.M., 1991. Evolution of Pan-African island arc assemblages in the southern Red Sea Hills, Sudan, and in southwestern Arabia as exemplified by geochemistry and geochronology. In: R.J. Stern and W.R. van Schmus (Editors), Proterozoic Crustal Evolution in the Late Proterozoic. Precambrian Res., 53:99-117. We report Rb-Sr whole-rock and zircon ages for metavolcanic and plutonic associations in the southeastern part of the Red Sea Hills, Sudan, and show that these rocks constitute one of the earliest Pan-African arc assemblages within the Arabian-Nubian shield. The remarkable similarity in geochemistry and age bet…
Time-scale of deformation and intertectonic phases revealed by P-T-D-t relationships in the orogenic middle crust of the Orlica-Śnieżnik Dome, Polish…
2014
A section of the orogenic middle crust (Orlica-nienik Dome, Polish/Czech Central Sudetes) was examined to constrain the duration and significance of deformation (D) and intertectonic (I) phases. In the studied metasedimentary synform, three deformation events produced an initial subhorizontal foliation S1 (D-1), a subsequent subvertical foliation S2 (D-2) and a late subhorizontal axial planar cleavage S3 (D-3). The synform was intruded by pre-, syn- and post-D-2 granitoid sheets. Crystallization-deformation relationships in mica schist samples document I1-2 garnet-staurolite growth, syn-D-2 staurolite breakdown to garnet-biotite-sillimanite/andalusite, I2-3 cordierite blastesis and late-D-3…
Multi-chronometric ages and origin of Archaean tonalitic gneisses in Finnish Lapland: A case for long crustal residence time
1984
The Tojottamanselka gneisses of the Koitelainen region, northern Finland, have been dated by the Sm-Nd and the common Pb methods. The Sm-Nd data of seven samples from a small area (100 m × 100 m) define an isochron ofT=3.06±0.12 (2σ) Ga, with correspondingINd=0.50848±9 (2σ), oreNd(T)=−3.7±1.8. This age is in good agreement with the zircon U-Pb discordia age (3.1 Ga) reported by Kroner et al. (1981) and is interpreted as the time of magmatic emplacement. The distinctly negativeeNd(T) value is found for the first time for Archean tonalitic gneisses and implies derivation of these magmas by remelting of continental material with a long (200–500 Ma) crustal residence time. A few samples, on the…
Numerical dating of the Eckfeld maar fossil site, Eifel, Germany: a calibration mark for the Eocene time scale.
2000
Sediments of the Eckfeld maar (Eifel, Germany) bear a well-preserved Eocene fauna and flora. Biostratigraphically, Eckfeld corresponds to the Middle Eocene mammal reference level MP (Mammals Paleogene) 13 of the ELMA (European Land Mammal Age) Geiseltalian. In the maar crater, basalt fragments were drilled, representing explosion crater eruption products. By 40Ar/39Ar dating of the basalt, for the first time a direct numerical calibration mark for an Eocene European mammal locality has been established. The Eckfeld basalt inverse isochron date of 44.3 +/- 0.4 Ma suggests an age for the Geiseltalian/Robiacian boundary at 44 Ma and, together with the 1995 time scale of Berggren et al., a time…
Eclogites and Garnet Pyroxenites: Problems Resolving Provenance Using Lu-Hf, Sm-Nd and Rb-Sr Isotope Systems
2010
Cratonic eclogites and garnet pyroxenites from the Kaapvaal craton have heterogeneous Hf^Nd^Sr^(O) isotope ratios that define a positive Hf^Nd isotope array and a negative Nd^Sr isotope array. Isotopic variability encompasses depleted (mid-ocean ridge basalt and ocean-island basalt) to enriched mantle compositions (Group I and II kimberlites) and overlaps with that of the Kaapvaal craton garnet peridotite xenoliths. Isotopic heterogeneity at Roberts Victor is less extreme than previously reported and ranges from eclogites with a highly depleted MORB-like signature to enriched eclogites similar to Group II and transitional kimberlites and Group II megacrysts (eHf1⁄4 ^32·8). Much of this simi…
A late Precambrian (∼ 710 Ma) high volcanicity rift in the southern Eastern Desert of Egypt
1991
The late Precambrian Shadli Metavolcanics of SE Egypt constitute a slightly metamorphosed bimodal sequence that has been previously interpreted as manifesting volcanic activity at an island arc. We report the first Rb-Sr geochronologic, trace element (including REE), and Nd isotopic data for these rocks. Two types of basalt are recognized, the stratigraphically lower suite having compositions like N-MORB ferrobasalt while the overlying basalt is similar to slightly fractionated E-MORB. The two basalt types were derived from melting of a strongly depleted source, most likely within the upper 60–75 km of the upper mantle. The origin of the felsic melts is problematic, and these could either h…
Diffusion versus recrystallization processes in Rb–Sr geochronology: Isotopic relics in eclogite facies rocks, Western Gneiss Region, Norway
2008
Abstract Rb–Sr and U–Pb isotopic data for granulite facies rocks, forming textural relics with respect to eclogite facies metamorphism in the Western Gneiss Region (WGR) of Norway, highlight the importance of textures and mineral reaction kinetics for the interpretation of geochronological data. Studied rocks from Bardsholmen, southern WGR, were subjected to granulite facies metamorphism at 955 ± 3 Ma (U–Pb, zircon). Later on, they experienced a subduction-related, kinetically stranded eclogitization ( T > 650 °C at ∼20 kbar) at 404 ± 2 Ma (Rb–Sr multimineral internal isochron data), followed by exhumation through amphibolite facies conditions. Full conversion of granulite to eclogite was …