Search results for "Ibi"
showing 10 items of 13473 documents
Synthesis, crystal structure and magnetic properties of the cyclic tetranuclear compound [Cu4(pz)4(hppa)2(H2O)4] [pz = pyrazolate; hppa = R,S-2-hydro…
2019
Abstract The synthesis, X-ray structure and magnetic properties of the neutral tetranuclear copper(II) complex of formula [Cu4(pz)4(hppa)2(H2O)4] (1) [Hpz = pyrazole and hppa = R,S-2-hydroxo-2-phenyl-2-(1-pyrazolyl)acetate] are reported. Remarkably, the structure of 1 reveals the presence of the S- and R-forms of the new hppa ligand which is formed in situ in the complex reaction between copper(II), pyrazole and phenylmalonate in water:methanol solvent mixture under ambient conditions. The two crystallographically independent copper(II) ions [Cu(1)/Cu(2)] are five-coordinate in square pyramidal surroundings. Three nitrogen atoms, from two pz groups and one hppa ligand and one oxygen atom of…
Effect of different concentrations of specific inhibitor of matrix metalloproteinases on the shear bond strength of self-adhesive resin cements to de…
2017
Background Considering the probability of chemical and enzymatic reactions between matrix metalloproteinases (MMPs) in the dentin structure and their specific inhibitors, the aim of the present study was to evaluate the effect of different concentrations of specific inhibitor of MMPs (galardin) on the shear bond strength of self-adhesive resin cements to dentin. Material and Methods Forty-eight sound human premolars were mounted in self-cured acrylic resin after removal of the enamel on the buccal and lingual surfaces. The dentin surfaces achieved were polished and prepared with 600-grit silicon carbide paper. The samples were divided into 3 groups (n=16) based on the concentration of galar…
Vibration Tests and Structural Identification of the Bell Tower of Palermo Cathedral
2019
Background: The recent seismic events in Italy have underlined once more the need for seismic prevention for historic constructions of architectural interest and in general, the building heritage. During the above-mentioned earthquakes, different masonry monumental buildings have been lost due to the intrinsic vulnerability and ageing that reduced the structural member strength. This has made the community understand more that prevention is a necessary choice for the protection of monuments. Objective: The paper aims at demonstrating a strategy of investigation providing the possibility of health judgment, identifying a computational model for the assessment of structural capacity under se…
Anticipating the impact of pitfalls in kinetic biodegradation parameter estimation from substrate depletion curves of organic pollutants
2019
[EN] Accurate and reliable estimation of kinetic parameters of pollutant biodegradation processes is essential for environmental and health risk assessment. Common biodegradation models proposed in the literature, such as the nonlinear Monod equation and its simplified versions (e.g. Michaelis-Menten-like and first-order equations), are problematic in terms of accuracy of kinetic parameters due to the parameter correlation. However, a comparison between these models in terms of accuracy and reliability, related to data imprecision, has not been performed in the literature. This task is necessary, mainly because the model selection cannot be straightforward, as shown in this work. To facilit…
Evaluation of deep learning algorithms for national scale landslide susceptibility mapping of Iran
2021
The identification of landslide-prone areas is an essential step in landslide hazard assessment and mitigation of landslide-related losses. In this study, we applied two novel deep learning algorithms, the recurrent neural network (RNN) and convolutional neural network (CNN), for national-scale landslide susceptibility mapping of Iran. We prepared a dataset comprising 4069 historical landslide locations and 11 conditioning factors (altitude, slope degree, profile curvature, distance to river, aspect, plan curvature, distance to road, distance to fault, rainfall, geology and land-sue) to construct a geospatial database and divided the data into the training and the testing dataset. We then d…
The influence of the wind direction and plants on the variability of topsoil magnetic susceptibility in industrial and urban areas of southern Poland
2016
Volume magnetic susceptibility (κ) was measured on the soil surface and in the vertical topsoil profile within a 300 km2 area located in an urban-industrial conurbation. The results were compared to plant species compositions in the forest storeys, elevation above sea level, and terrain geomorphology. The content and mineral composition of the magnetic fraction were determined in the soil horizons. It was found that the extent of the area with enhanced topsoil magnetic susceptibility was similar to the dominant wind direction (south–west). Enhanced κ values were observed for the soil at the forest margin on the leeward side of the emitters as well as at sites located on exposed local elevat…
Assessing and Modeling Soil Detachment Capacity by Overland Flow in Forest and Woodland of Northern Iran
2020
Land use has significant effects on the erosion process, since it influences the soil detachment capacity by causing an overland flow (Dc). The effects of different land uses on the rill detachment capacity have not been explained in depth, and the hydraulic parameters providing accurate estimates of this soil property have not been completely identified. This study quantifies Dc at low flow rates in woodland and forestland, compared to two other land uses (cropland and grassland), in the Saravan watershed (Northern Iran), and develops prediction models of Dc and rill erodibility (Kr). Dc was measured on undisturbed soil samples, collected in the four land uses, and characterized in terms o…
Soil erosion processes in European vineyards: A qualitative comparison of rainfall simulation measurements in Germany, Spain and France
2016
Small portable rainfall simulators are considered a useful tool to analyze soil erosion processes in cultivated lands. European research groups in Spain (Valencia, Málaga, Lleida, Madrid and La Rioja), France (Reims) and Germany (Trier) have used different rainfall simulators (varying in drop size distribution and fall velocities, kinetic energy, plot forms and sizes, and field of application) to study soil loss, surface flow, runoff and infiltration coefficients in different experimental plots (Valencia, Montes de Málaga, Penedès, Campo Real and La Rioja in Spain, Champagne in France and Mosel-Ruwer valley in Germany). The measurements and experiments developed by these research teams give…
Revision of the genus Anasibirites Mojsisovics (Ammonoidea): An iconic and cosmopolitan taxon of the late Smithian (Early Triassic) extinction
2016
34 pages; International audience; The family Prionitidae Hyatt represents a major component of ammonoid faunas during the Smithian (Early Triassic), and the genus Anasibirites Mojsisovics is the most emblematic taxon of this family. Its stratigraphical range is restricted to the beginning of the late Smithian (Wasatchites distractus Zone). The genus is also characterized by an unusual cosmopolitan distribution, thus contrasting with most earlier Smithian ammonoid distributions that were typically restricted by latitude. Because the late Smithian witnessed an extinction of the nekton (e.g. ammonoids, conodonts) whose amplitude is equal to or larger than that of the end-Permian crisis, the nu…
Evidence of tephra reworking in loess based on 2D magnetic susceptibility mapping: A case study from Rocourt, Belgium
2016
Abstract In this article, a new and original approach to characterize tephra layers based on high resolution magnetic susceptibility (MS) mapping is applied to the tephra deposits of Rocourt (Belgium). A series of MS maps of selected sections show the 3D morphology of tephra horizons, including local dip and reworked structures of the Rocourt and Eltville tephras, proven by chemical analyses of phenocrysts. At Rocourt, tephras are observed in loess which is an excellent material for testing the efficiency of the magnetic susceptibility mapping of tephra deposits. We also attempted to locate the volcanic source of the Eltville tephra based on the spatial analysis of the thickness of deposits…