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CCDC 813612: Experimental Crystal Structure Determination
2012
Related Article: Xin Xiong Li, Shou-Tian Zheng, Jie Zhang, Wei-Hui Fang, Guo-Yu Yang, J.M.Clemente-Juan|2011|Chem.-Eur.J.|17|13032|doi:10.1002/chem.201101496
CCDC 116033: Experimental Crystal Structure Determination
2000
Related Article: K.Hensen, R.Mayr-Stein, T.Stumpf, P.Pickel, M.Bolte, H.Fleischer|2000|J.Chem.Soc.,Dalton Trans.||473|doi:10.1039/a908134h
CCDC 955313: Experimental Crystal Structure Determination
2013
Related Article: Brian D. Rekken , Thomas M. Brown , James C. Fettinger , Felicitas Lips , Heikki M. Tuononen , Rolfe H. Herber , and Philip P. Power|2013|J.Am.Chem.Soc.|135|10134|doi:10.1021/ja403802a
Potential application of some wide band gap materials for UV dosimetry
2005
Properties of some wide band gap materials–natural and CVD diamonds – have been studied for their potential application in UV dosimetry, using methods of optically stimulated luminescence and thermoluminescence. The observed properties are compared with those of the previously studied AlN ceramics. From the OSL excitation spectra, it follows that spectral sensitivity of the studied materials falls mainly into the UVC range, OSL and TL emission spectra are located within the visible light region, thus suitable for usual photodetectors. OSL stimulation spectra of the studied materials have a continuous character and are located in a broad visible/near infrared spectral region implying that th…
Evaluation of carbamazepine uptake and metabolization by Typha spp., a plant with potential use in phytotreatment
2011
Abstract Phytoremediation technologies such as constructed wetlands have shown higher efficiencies in removal of pharmaceuticals from wastewaters than conventional wastewater treatment processes, and plants seem to have an important role in the removal of some of those compounds. In this context, a study was conducted to assess tolerance, uptake, and metabolism of the epilepsy drug, carbamazepine, by the macrophyte Typha spp. This evaluation was conducted in hydroponic solutions with 0.5–2.0 mg/L of this pharmaceutical for a maximum period of 21 days. The removal of carbamazepine from nutrient solutions by the plants reached values of 82% of the initial contents. Furthermore, a metabolite (…
Metal complexes of the carbonic anhydrase inhibitor methazolamide (Hmacm). Crystal structure of the Zn(macm)2 (NH3)2. Anticonvulsant properties of th…
1995
Complexes of Co(II), Cu(II), and Zn(II) with deprotonated methazolamide and ammonia are synthesized and characterized. The complex Zn(macm)2(NH3)2 crystallizes in the monoclinic C2/c space group with a = 13.468(1), b = 6.759(1), c = 23.014(2) A, beta = 90.27(1), and Z = 4. The structure was refined to R = 0.049 (Rw = 0.053). The Zn(II) ion is coordinated to two deprotonated sulfonamido nitrogen atoms of the macm- ligand and two nitrogen atoms of the ammonia ligands in a distorted tetrahedron. The Zn(macm)2(NH3)2 complex is shown to be a simple model for the methazolamide inhibition of CA. EHMO calculations applied to fractional coordinates of the Zn(macm)2(NH3)2 complex indicate that the at…
Chromatographic Air Analyzer Microsystem for the Selective and Sensitive Detection of Explosive-related Compounds
2014
Abstract The detection of explosives and explosive-related compounds is of major importance for the monitoring of explosive- contaminated sites. Current methods need to become cheaper and portable while maintaining a high sensitivity and selectivity level. In that sense, a silicon micro-analytical platform consisting of a three-dimensional micro-preconcentrator based on a hydrophobic zeolite, coupled to a silicon spiral micro-column was built. A chemical gas sensor acted as a miniaturized gas detector. This system allowed selective detection of orthonitrotoluene (ONT), an explosive-related compound at the sub-ppm level in the presence of toluene and moisture.
Detection of lung cancer bio-markers in human breath using a micro-fabricated air analyzer
2015
International audience; The analysis of volatile organic compounds (VOCs) that are linked to lung cancer is a very promising way in medical diagnostics because it is non-invasive and potentially inexpensive. In that sense, a silicon micro-analytical platform consisting of a three-dimensional micro-preconcentrator coupled to a silicon spiral gas chromatographic micro-column was built. A metal oxide-based gas sensor acted as a miniaturized gas detector. This system allowed selective detection of VOCs at the sub-ppm level. The present study is focused first on the chromatographic air analyzer fabrication and second on the selection of an appropriate adsorbent. Various adsorbents such as activa…
Lexical and sublexical units in speech perception.
2009
Saffran, Newport, and Aslin (1996a) found that human infants are sensitive to statistical regularities corresponding to lexical units when hearing an artificial spoken language. Two sorts of segmentation strategies have been proposed to account for this early word-segmentation ability: bracketing strategies, in which infants are assumed to insert boundaries into continuous speech, and clustering strategies, in which infants are assumed to group certain speech sequences together into units (Swingley, 2005). In the present study, we test the predictions of two computational models instantiating each of these strategies i.e., Serial Recurrent Networks: Elman, 1990; and Parser: Perruchet & Vint…
Spatiotemporal Dynamics of the Processing of Spoken Inflected and Derived Words:A Combined EEG and MEG Study
2011
The spatiotemporal dynamics of the neural processing of spoken morphologically complex words are still an open issue. In the current study, we investigated the time course and neural sources of spoken inflected and derived words using simultaneously recorded electroencephalography (EEG) and magnetoencephalography (MEG) responses. Ten participants (native speakers) listened to inflected, derived, and monomorphemic Finnish words and judged their acceptability. EEG and MEG responses were time-locked to both the stimulus onset and the critical point (suffix onset for complex words, uniqueness point for monomorphemic words). The ERP results showed that inflected words elicited a larger left-late…