Search results for "Ih"

showing 10 items of 9382 documents

4-(4-Fluorophenyl)-2-methyl-3-(1-oxy-4-pyridyl)isoxazol-5(2H)-one

2008

The crystal structure of the title compound, C15H11FN2O3, was determined as part of a study on the biological activity of isoxazolone derivatives as p38 mitogen-activated protein kinase (MAPK) inhibitors. The dihedral angles between rings are isoxazole/benzene = 55.0 (3)°, isoxazole/pyridine = 33.8 (2)° and benzene/pyridine = 58.1 (2)°.

Biological activityGeneral ChemistryCrystal structureDihedral angleCondensed Matter PhysicsBioinformaticsOrganic PapersMedicinal chemistrylcsh:Chemistrychemistry.chemical_compoundlcsh:QD1-999chemistryPyridineGeneral Materials ScienceIsoxazoleBenzeneProtein kinase AActa Crystallographica Section E Structure Reports Online
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Skolēnu pašnovērtējums bioloģijas mācību procesā

2005

Bioloģija - mācīšana un mācīšanāsSelf-assessmentEducational psychologyEducational assessmentSkolas pedagoģijaIzglītības psiholoģijaPašnovērtējums:SOCIAL SCIENCES::Social sciences::Education [Research Subject Categories]Biology - study and teaching
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Design and validation of a wireless Body Sensor Network for integrated EEG and HD-sEMG acquisitions

2022

Sensorimotor integration is the process through which the human brain plans the motor program execution according to external sources. Within this context, corticomuscular and corticokinematic coherence analyses are common methods to investigate the mechanism underlying the central control of muscle activation. This requires the synchronous acquisition of several physiological signals, including EEG and sEMG. Nevertheless, physical constraints of the current, mostly wired, technologies limit their application in dynamic and naturalistic contexts. In fact, although many efforts were made in the development of biomedical instrumentation for EEG and High Density-surface EMG (HD-sEMG) signal ac…

Biomedical Engineeringevoked potentialsWireless communicationSynchronizationReceiversBody sensor networkswireless body sensor networkmittauslaitteetInternal MedicineHumansEEGsensorimotor integrationBiopotential acquisition systemsHD-sEMGElectromyographyGeneral NeuroscienceRehabilitationsensoriverkotBrainSignal Processing Computer-AssistedElectroencephalographyelektromyografiahermo-lihastoimintaBiopotential acquisition systems; Body sensor networks; EEG; Electroencephalography; Electromyography; evoked potentials; HD-sEMG; Instruments; Receivers; sensorimotor integration; Synchronization; wireless body sensor network; Wireless communicationInstrumentsWireless Technologylangattomat verkot
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Triphen­yl[(4-phenyl­benzo­yl)meth­yl]phospho­nium trifluoro­methane­sulfonate

2010

In the cation of the title compound, C32H26OP+·CF3O3S−, the dihedral angle between the benzene rings of the biphenyl group is 42.37 (8)°. In the crystal, the cations and anions interact through intermolecular C—H...O hydrogen bonds, forming chains parallel to the b axis. These chains are further linked by C—H...π stacking interactions into layers parallel to the bc plane.

BiphenylCrystallographyHydrogen bondStackingMethane sulfonateGeneral ChemistryMeth-Dihedral angleCondensed Matter PhysicsBioinformaticsMedicinal chemistryOrganic PapersCrystalchemistry.chemical_compoundchemistryQD901-999General Materials ScienceBenzeneActa Crystallographica Section E: Structure Reports Online
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Magnetoelectrochemistry of 4,4′-bis(dimethylamino)biphenyl and 4,4′-dinitrobiphenyl azacrown macrocyclic lactams

2005

Abstract The voltammetric behaviour at carbon fibre microelectrodes under the application of static magnetic fields of two series of macrolactams containing in their structure 4,4′-bis(dimethylamino)biphenyl or 4,4′-dinitrobiphenyl groups in MeCN solution is described. The response of 4,4′-dinitrobiphenyl receptors is dominated by two successive one-electron reduction processes at −0.9 and −1.6 V versus AgCl/Ag. 4,4′-bis(dimethylamino)biphenyl-containing receptors display two one-electron oxidations above +0.8 and +1.0 V. In both cases, a dihedral/planar interconversion precedes the second electron transfer step. Upon application of moderate (0.05–0.2 T) static magnetic fields to the electr…

BiphenylStereochemistryGeneral Chemical EngineeringReaction intermediateDihedral angleElectrochemistrychemistry.chemical_compoundElectron transferCrystallographychemistryElectrochemistryCyclic voltammetryAcetonitrileConformational isomerismElectrochimica Acta
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Polyazapodands Derived from Biphenyl. Study of their Behaviour as Conformationally Regulated Fluorescent Sensors

2004

Eight new polyazapodands containing a 4,4′-substituted biphenyl moiety have been synthesised. Four (7, 8, 9 and 11) are functionalised on positions 4 and 4′ with a nitro group and four (1, 2, 3 and 10) with a dimethylamino substituent. Comparison of the emission behaviour of 1, 2, 3 with that of the reference compounds 10 and tetramthylbenzidine, clearly suggests that a modification in the dihedral angle between the biphenyl rings is an important factor in determining the fluorescent response of the molecule. The fluorescence is pH dependent, due to the formation of intramolecular hydrogen bonds between protonated aliphatic nitrogens and a carbonyl oxygen, which influences the aforementione…

Biphenylchemistry.chemical_compoundCrystallographyChemistryStereochemistryHydrogen bondIntramolecular forceSubstituentMoietyMoleculeProtonationGeneral ChemistryDihedral angleSupramolecular Chemistry
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2,5-Dimethyl-4′-nitrobiphenyl

2006

The title compound, C14H13NO2, is a non-planar biphenyl derivative, in which the dihedral angle between the benzene rings is 62.65 (5) °.

Biphenylchemistry.chemical_compoundchemistryPolymer chemistryGeneral Materials ScienceGeneral ChemistryPhysics::Chemical PhysicsDihedral angleCondensed Matter PhysicsBenzene4-NitrobiphenylDerivative (chemistry)Acta Crystallographica Section E Structure Reports Online
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Biphenyl-4-yl 4-methylbenzenesulfonate

2017

Molecules of the title compound, C19H16O3S, are composed of a biphenyl moiety substituted with a toluene-4-sulfonate group. The dihedral angle between the two coplanar biphenyl rings and the toluene ring is 52.72 (6)°.

Biphenylcrystal structure010405 organic chemistryStereochemistryCrystal structureDihedral angletosyl­ates010402 general chemistryRing (chemistry)01 natural sciencesTolueneMedicinal chemistryCoupling reaction0104 chemical scienceschemistry.chemical_compoundSulfonatechemistrycross-coupling reactionsMoietyIUCrData / International Union of Crystallography
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Comparison of the crystal structures of 4,4′-bis[3-(4-methylpiperidin-1-yl)prop-1-yn-1-yl]-1,1′-biphenyl and 4,4′-bis[3-(2,2,6,6-tetramethylpiperidin…

2015

The crystal structures of the two title compounds display chair conformations of the piperidine rings in their mol­ecules. In compound (I), the biphenyl system has a twisted conformation with a dihedral angle of 26.57 (6)° while in compound (II) the two phenyl rings are exactly coplanar.

Biphenylcrystal structureCrystallographybiologyStereochemistryCyclohexane conformationGeneral ChemistryCrystal structureDihedral angleCondensed Matter PhysicsRing (chemistry)biology.organism_classificationResearch Communicationschemistry.chemical_compoundbiphenyl ringchemistryQD901-999TetraMoietyGeneral Materials SciencePiperidinepiperidine ringbis-tertiary ammonium analogActa Crystallographica Section E: Crystallographic Communications
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Study of the Curing Process of DGEBA Epoxy Resin Through Structural Investigation

2015

In this work, a multi-scale approach with different analytical methods is applied to study the curing process and the structural properties of a diglycidyl ether of bisphenol A (DGEBA) epoxy resin. This monomer, thermally cured using 4,4′-diaminodiphenilsulfone (DDS) as hardener, is analyzed after 10, 45, 90, and 120 min of reaction time at 180 °C to obtain information on samples with different cross-linking densities. Samples are also characterized after extraction in acetone in order to obtain structural information on the insoluble parts. For this purpose, differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMTA), solid-state nuclear magnetic resonance (ss-NMR),…

Bisphenol AMaterials scienceDiglycidyl etherEpoxy resins solid-state nuclear magnetic resonance (ss-NMR) positron annihilation lifetime spectroscopy (PALS)Polymers and PlasticsOrganic ChemistryEpoxyDynamic mechanical analysisCondensed Matter Physicschemistry.chemical_compoundMonomerDifferential scanning calorimetrychemistrySolid-state nuclear magnetic resonancevisual_artPolymer chemistryMaterials Chemistryvisual_art.visual_art_mediumSettore CHIM/07 - Fondamenti Chimici Delle TecnologiePhysical and Theoretical ChemistryThermal analysis
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