Search results for "Ilici"
showing 10 items of 238 documents
Performance evaluation and stability of silicide-based thermoelectric modules
2020
Abstract Long-term studies on thermoelectric generators based on N-type magnesium silicide (Mg2.01Si0.49Sn0.5Sb0.01) and P-type higher manganese silicide (Mn0.98Mo0.02Si1.73Ge0.02) materials are presented, in the operating temperature range of 200 °C–400 °C. Emphasis is put on the performance and reliability of the current collector configuration, especially on the hot side of the module, and on the thermomechanical stresses that are created during operation and lifetime testing as a result of large temperature gradients experienced across the thermoelectric legs. With silver (Ag) paste as contact material, the long term-stability of the uni-couples was carried out on non-metalized legs and…
Reactive Sintering of molybdenum disilicide by Spark Plasma Sintering from mechanically activated powder mixtures: Processing parameters and properti…
2008
Abstract Dense molybdenum disilicide with a nano-organized microstructure was synthesized by mechanical activation, by producing nanostructured agglomerates of a 1:2 mixture of Mo and Si, followed by the synthesis/consolidation in one step using SPS technology. In order to synthesize a dense molybdenum disilicide with a perfectly controlled microstructure, an investigation of the influence of Spark Plasma Sintering processing parameters (temperature, heating rate, mechanical pressure and holding time) on the chemical composition and the microstructure characteristics has been performed. The present work shows also that the so-obtained materials present better oxidation resistance in compari…
Determination of impurity distributions in ingots of solar grade silicon by neutron activation analysis
2017
AbstractIn a series of crystallization experiments, the directional solidification of silicon was investigated as a low cost path for the production of silicon wafers for solar cells. Instrumental neutron activation analysis was employed to measure the influence of different crystallization parameters on the distribution of 3d-metal impurities of the produced ingots. A theoretical model describing the involved diffusion and segregation processes during the solidification and cooling of the ingots could be verified by the experimental results. By successive etching of the samples after the irradiation, it could be shown that a layer of at least 60 μm of the samples has to be removed to get r…
The roles of microlites and phenocrysts during degassing of silicic magma
2022
Abstract Silicic magmas span a wide range of eruptive styles between explosive and effusive, and transitions between these styles are commonplace. Yet the triggers of switches in eruptive style remain poorly understood. Eruptions are mostly driven by degassing of magmatic water and their eruption style - effusive or explosive - is likely governed by the efficiency of outgassing as well as magma ascent rate. Microlites and phenocrysts are often purported to promote heterogeneous bubble nucleation and outgassing, both key variables in the degassing dynamics that become crucial in controlling the eruptive style. Here, in order to shed light on the role of nature, size and abundance of crystals…
Incised valleys and tidal seaways: the example of the Miocene Uzès-Castillon basin, SE France.
2012
Abstract The sedimentology and stratigraphy of the Miocene deposits of the Uzès-Castillon basin are revisited. This basin, located in SE France at the junction between the perialpine foreland basin and the W Mediterranean margin, sits in a syncline that formed during the latest Cretaceous Pyrenean tectonic phase. It records the succession of shallow-water mixed siliciclastic to dominantly bioclastic carbonates that alternate with shelf marls. The clastic carbonates were accumulated as a stack of subtidal dunes and bars that were formed by tidal currents channelized in a seaway following the syncline axis. The marls indicate deposition in more protected and locally deeper waters, as interflu…
Shallow vent architecture during hybrid explosive-effusive activity at Cordón Caulle (Chile, 2011-12): Evidence from direct observations and pyroclas…
2013
International audience; In June 2011, an eruption of rhyolite magma began at the Puyehue-Cordón Caulle volcanic complex, southern Chile. By January 2012, explosive activity had declined from sustained pyroclastic (Plinian to sub-Plinian) fountaining to mixed gas and ash jetting punctuated by Vulcanian blasts. This explosive activity was accompanied by synchronous effusion of obsidian lava in a hybrid explosive-effusive eruption. Fortuitous climatic conditions permitted ground-based observation and video recording of transient vent dynamics as well as real-time collection of proximal juvenile ash as it sedimented from the active plume. The main eruptive vent complex and site of lava effusion…
The Permeability Evolution of Tuffisites and Implications for Outgassing Through Dense Rhyolitic Magma
2019
There is growing evidence that outgassing through transient fracture networks exerts an important control on conduit processes and explosive‐effusive activity during silicic eruptions. Indeed, the first modern observations of rhyolitic eruptions have revealed that degassed lava effusion may depend upon outgassing during simultaneous pyroclastic venting. The outgassing is thought to occur as gas and pyroclastic debris are discharged through shallow fracture networks within otherwise low‐permeability, conduit‐plugging lava domes. However, this discharge is only transient, as these fractures become clogged and eventually blocked by the accumulation and sintering of hot, melt‐rich pyroclastic d…
High-resolution 40Ar/39Ar chronostratigraphy of the post-caldera (<20 ka) volcanic activity at Pantelleria, Sicily Strait
2011
Abstract The island of Pantelleria (Sicily Strait), the type locality for pantellerite, has been the locus of major caldera-forming eruptions that culminated, ca. 50 ka ago, in the formation of the Cinque Denti caldera produced by the Green Tuff eruption. The post-caldera silicic activity since that time has been mostly confined inside the caldera and consists of smaller-energy eruptions represented by more than twenty coalescing pantelleritic centers structurally controlled by resurgence and trapdoor faulting of the caldera floor. A high-resolution 40Ar/39Ar study was conducted on key units spanning the recent (post-20 ka) intracaldera activity to better characterize the present-day status…
Experimental Constraints on the Crystallization of Silica Phases in Silicic Magmas
2021
Abstract Low-pressure silica polymorphs, e.g. quartz (Qtz), tridymite (Trd), and cristobalite (Crs), are common in silicic magmas, but the conditions of their formation are still unclear. The stability fields of these polymorphs have been determined in the SiO2, SiO2–H2O, and haplogranite systems, but these simple systems are not directly applicable to silica polymorph crystallization in natural silicic magmas. The present study compiles an experimental database of new and previously-published data documenting the crystallization of silica phases in natural silicic magmas and simple synthetic systems. Silica polymorphs are identified using Raman spectroscopy and their pressure-temperature d…