Search results for "Impedance"
showing 10 items of 432 documents
A kinetic interpretation of a negative time constant in impedance equivalent circuits for the dissolution/passive transition
2007
Abstract A theoretical impedance function is proposed for the active/passive transition of nickel in an acid sulphate medium. It is considered that passivating species progressively covers the electrode surface. This approximated model predicts the appearance of negative time constants in the impedance spectra when coverage coefficient θ values for passive species are greater than 0.5.
Alternating current electrogravimetry of copper electrodissolution in a sulfuric acid solution
2017
Abstract Copper electrodissolution processes have been studied by means of electrochemical impedance spectroscopy and ac-electrogravimetry (mass impedance). During ac-electrogravimetry acquisition, mass decreases or increases due to the electrodissolution or the electrodeposition of copper, respectively. As a result, this continuous mass drift makes impossible obtaining a true ac-electrogravimetry response unless a numerical correction was applied. It has been compared the electrochemical behavior of copper layers previously treated and other freshly deposited on the gold electrode of the quartz crystal microbalance. The simultaneous analysis of both impedance functions has allowed separati…
Bipolar membranes under forward and reverse bias conditions. Theory vs. experiment
1994
Abstract Bipolar membranes are layered structures composed of one cation-and one anion-exchange membrane joined together in series. The current—voltage curves of two recently developed bipolar membranes have been analysed theoretically and experimentally under both forward and reverse bias conditions. The experimental trends observed are high conductivity under forward bias conditions and high impedance first, and then electric field enhanced (EFE) water dissociation for high enough applied voltages, under reverse bias conditions. The forward bias measurements can contribute to a better knowledge of some of the transport parameters entering also in the reverse biased membrane. Comparison of…
Vascular resistance arm of the baroreflex: methodology and comparison with the cardiac chronotropic arm.
2020
Baroreflex response consists of cardiac chronotropic (effect on heart rate), cardiac inotropic (on contractility), venous (on venous return) and vascular (on vascular resistance) arms. Because of its measurement simplicity, cardiac chronotropic arm is most often analysed. The aim was to introduce a method to assess vascular baroreflex arm, and to characterize its changes during stress. We evaluated the effect of orthostasis and mental arithmetics (MA) in 39 (22 female, median age: 18.7 yrs.) and 36 (21 female, 19.2 yrs.) healthy volunteers, respectively. We recorded systolic and mean blood pressure (SBP and MBP) by volume-clamp method and R-R interval (RR) by ECG. Cardiac output (CO) was re…
The Behaviour of Mistuned Piezoelectric Shunt Systems and Its Estimation
2016
This paper addresses monoharmonic vibration attenuation using piezoelectric transducers shunted with electric impedances consisting of a resistance and an inductance in series. This type of vibration attenuation has several advantages but suffers from problems related to possible mistuning. In fact, when either the mechanical system to be controlled or the shunt electric impedance undergoes a change in their dynamical features, the attenuation performance decreases significantly. This paper describes the influence of biases in the electric impedance parameters on the attenuation provided by the shunt and proposes an approximated model for a rapid prediction of the vibration damping performa…
A direct impedance tomography algorithm for locating small inhomogeneities
2003
Impedance tomography seeks to recover the electrical conductivity distribution inside a body from measurements of current flows and voltages on its surface. In its most general form impedance tomography is quite ill-posed, but when additional a-priori information is admitted the situation changes dramatically. In this paper we consider the case where the goal is to find a number of small objects (inhomogeneities) inside an otherwise known conductor. Taking advantage of the smallness of the inhomogeneities, we can use asymptotic analysis to design a direct (i.e., non-iterative) reconstruction algorithm for the determination of their locations. The viability of this direct approach is documen…
Explicit Characterization of Inclusions in Electrical Impedance Tomography
2001
In electrical impedance tomography one seeks to recover the spatial conductivity distribution inside a body from knowledge of the Neumann--Dirichlet map. In many practically relevant situations the conductivity is smooth apart from some inhomogeneities where the conductivity jumps to a higher or lower value. An explicit characterization of these inclusions is developed in this paper. To this end a class of dipole-like indicator functions is introduced, for which one has to check whether their boundary values are contained in the range of an operator determined by the measured Neumann--Dirichlet map. It is shown that this holds true if and only if the dipole singularity lies inside the inhom…
Approximate 3-Dimensional Electrical Impedance Imaging
2001
We discuss a new approach to three-dimensional electrical impedance imaging based on a reduction of the information to be demanded from a reconstruction algorithm. Images are obtained from a single measurement by suitably simplifying the geometry of the measuring chamber and by restricting the nature of the object to be imaged and the information required from the image. In particular we seek to establish the existence or non-existence of a single object (or a small number of objects) in a homogeneous background and the location of the former in the (x,y)-plane defined by the measuring electrodes. Given in addition the conductivity of the object rough estimates of its position along the z-a…
Toward morphological thoracic EIT: major signal sources correspond to respective organ locations in CT.
2012
Lung and cardiovascular monitoring applications of electrical impedance tomography (EIT) require localization of relevant functional structures or organs of interest within the reconstructed images. We describe an algorithm for automatic detection of heart and lung regions in a time series of EIT images. Using EIT reconstruction based on anatomical models, candidate regions are identified in the frequency domain and image-based classification techniques applied. The algorithm was validated on a set of simultaneously recorded EIT and CT data in pigs. In all cases, identified regions in EIT images corresponded to those manually segmented in the matched CT image. Results demonstrate the abilit…
Evaluation of an Optical Energy Harvester for SHM Application
2019
Abstract In this paper a preliminary study on an array configuration of rectified optical nanoantennas for energy harvesting application is proposed. Currently, the major impediments for the use of the rectified optical nanoantenna known as rectenna are the relatively low conversion efficiency and low power transfer to the load, both of them caused mainly by the mismatch between the impedance of the rectifier (several kilo ohms) and that of the antenna (hundreds of ohm). For this reason, the design of the array represents a crucial point to obtain the maximum energy transfer from the rectenna to the load, represented as a typical DC/DC boost power converter, and modeled by an equivalent inp…