Search results for "Inclusion"
showing 10 items of 891 documents
On the formation of inclusion complexes at the solid/liquid interface of anchored temperature-responsive PNIPAAM diblock copolymers with γ-cyclodextr…
2017
The thermal responsive behavior of adsorbed layers of diblock copolymers of poly(N-isopropylacrylamide) (PNIPAAM) and poly((3-acrylamidopropyl)trimethylammonium chloride) (PAMPTMA(+)) with γ-cyclodextrin (γ-CD) at the solid/liquid interface has been investigated using three in situ techniques: null ellipsometry, quartz–crystal microbalance with dissipation monitoring, and neutron reflectometry. The measurements provided information about the adsorbed amounts, the layer thickness, hydration and viscoelastic properties, and the interfacial structure and composition. The copolymers adsorb to silica with the cationic PAMPTMA(+) blocks sitting as anchors in a flat conformation and the PNIPAAM ch…
Ammonium ion mediated resorcarene capsules: ESI-FTICRMS study on gas-phase structure and ammonium ion affinity of tetraethyl resorcarene and its per-…
2003
AbstractThe ammonium ion binding affinities of tetraethyl resorcarene (1) and its per-methylated derivative (2) were studied by electrospray ionization Fourier transform ion cyclotron resonance (ESI-FTICR) mass spectrometry. Ten different ammonium ions were tested as guests for the resorcarenes. A strong tendency for complex formation was observed with all ammonium ions of size and charge distribution suitable for noncovalent interactions with the cavities of the resorcarene hosts 1 and 2. Although differences in ammonium ion affinities were observed between 1 and 2 due to the dissimilar conformations, the overall tendency was that increase in the degree of substitution and the length of ca…
[2]Catenanes and inclusion complexes derived from self-assembled rectangular PdII and PtII metallocycles
2012
New inclusion complexes and [2]catenanes were self-assembled from a fluorescent diazapyrenium based ligand, a PdII or PtII complex, and cyclic or acyclic electron rich aromatic guests in aqueous and organic media. The molecular rectangles display a π-deficient cavity suitable to incorporate π-donor aromatic systems. The inclusion complexes between the metallocycles and phenylenic (2a,b) and naphthalenic (3a,b–5a,b) derivatives were studied by NMR, UV-vis and fluorescence spectroscopy. The crystal structure of (3b) ⊂ 1a·6PF(6) confirmed the insertion of the guest into the cavity of the metallocycle. Following the same self-assembly strategy, the use of polyethers 6,7 as π-donors resulted in …
Complexation and Extraction of PAHs to the Aqueous Phase with a Dinuclear Pt II Diazapyrenium‐Based Metallacycle
2010
New palladium and platinum metallacycles have been synthesized by reaction between a 2,7-diazapyrenium-based ligand and Pd(II) and Pt(II) complexes. The inclusion complexes between the metallacycles and polycyclic aromatic hydrocarbons (PAHs) in CD(3)NO(2) and D(2)O were studied by NMR spectroscopy. The structures of the inclusion complexes of the Pt metallacycle as host with pyrene, phenanthrene, and triphenylene were confirmed by single crystal X-ray crystallography. The association constants between the Pt metallacycle and the selected PAHs were determined in CH(3)CN following the characteristic charge-transfer band displayed in their UV/Vis absorption spectrum. Although in aqueous solut…
Isothermal decompression history in the “Western Granulite” terrain, central Tanzania: Evidence from reaction textures and trapped fluids in metapeli…
2008
Abstract The Mozambique Belt (MB) of the East Africa Orogen contains large areas of granulite-facies migmatitic gneisses with Archaean and Palaeoproterozoic protolith ages and that were recycled during the Neoproterozoic Pan-African orogeny. The study area is situated along the Great Ruaha River and within the Mikumi National Park in central Tanzania where migmatitic gneisses and mafic to intermediate granulites are interlayered with Neoproterozoic granulite-facies migmatitic metapelites. Mineral textures suggest isothermal decompression, with the peak mineral assemblage comprising Grt–Bt–Ky–Kfs–Pl–Qtz ± Phn ± Ti-Oxide ± melt and amphibolite-facies retrograde assemblage Grt–Bt–Sil–Ms–Kfs–Pl…
Foreign language teaching within special needs education: learning from Europe-wide experience
2005
In this article, Anne Stevens and David Marsh focus on the main aspects of the argument and discussion raised in the recently published European Commission (2005) report on the teaching and learning of languages in the context of special educational needs. They explore the avenues of possible action that should follow if the issues raised in the report are to be effectively addressed.
Pullneyocoris dentatus gen. et sp. nov. (Hemiptera: Pentatomoidea: Cydnidae), the third representative of the subfamily Amnestinae from mid-Cretaceou…
2020
Abstract A new genus and species of burrower bug, Pullneyocoris dentatus gen. et sp. nov. (Hemiptera: Cydnidae: Amnestinae), is described from amber of northern Myanmar. It is the third representative of this family known from Burmese amber, and besides its autapomorphies, it presents a mixture of characters relevant to the extant Parachilocoris Horvath, 1919 and Pullneya Horvath, 1919. A comparison of this new genus to the two genera already described from the burmite, i.e. Chilamnestocoris Lis J.A., Lis. B. & Heiss, 2018, and Punctacorona Wang, Du, Yao & Ren, 2019 is also provided.
Variation of H2O/CO2and CO2/SO2ratios of volcanic gases discharged by continuous degassing of Mount Etna volcano, Italy
2008
[1] We applied the Multi-GAS technique to measure compositions of the volcanic plumes continuously discharged from summit craters of Voragine, Northeast and Bocca Nuova at Mount Etna, in an attempt to estimate compositions of the source volcanic gases. The estimated CO2/SO2 and H2O/CO2 ratios of the volcanic gases show a large variation ranging from 0.6 to 30 and from 1 to 18, respectively. This variability overlaps with the compositional range of dissolved volatiles in melt inclusions and their coexisting bubbles in a magma chamber and can be caused by the low-pressure degassing of a magma with variable bubble content ranging from 0.3 to 15 wt.%. The variable bubble content in the magma is…
Actitudes hacia el alumnado con discapacidad en educación física: validación de la EAADEF-EP a la etapa de educación primaria
2020
La investigación que aborda la inclusión del alumnado con discapacidad en educación física (EF) se presenta como un reto educativo en la actualidad. El objetivo de este estudio fue validar la Escala de Actitud hacia el Alumnado con Discapacidad en Educación Física (EAADEF) de Íñiguez-Santiago et al. (2017) a la etapa de educación primaria (EAADEF-EP). Participaron 465 estudiantes (rango 9-13 años) que cursaban 4º, 5º y 6º curso de la etapa de educación primaria obligatoria (EPO). Se confirmaron unos índices de ajuste adecuados para la adaptación de la EAADEF a EPO, mostrándose la estructura factorial invariante respecto al curso, género, el contacto previo con familiares o amigos con discap…
Representation of ASD in mass media: analysis of a generalist newspaper
2020
Los medios de comunicación influyen notablemente en sus consumidores, por lo que no son meros informadores, sino que también son creadores de opinión. Este hecho es relevante para el ámbito de la inclusión, en tanto que las necesidades específicas de apoyo educativo son también un tema tratado por los medios de comunicación. En el presente estudio se analizan los artículos que abordan la temática relacionada con el Trastorno del Espectro Autista (TEA) en el diario El País durante el año 2017. Los resultados del análisis de contenido de los artículos indican que el TEA fue un tema de interés en el año 2017. Los contenidos más recurrentes fueron las causas del TEA, frecuentemente desmintiendo…