Search results for "Infrared"

OH-related Infrared Absorption Bands in Oxide Glasses

2005

We report the infrared activity, in the spectral region of the OH stretching modes, of different composite silicate glasses whose chemical composition is established by X-ray fluorescence measurements. The analysis of the absorption line profiles is made in terms of different spectral contributions, Gaussian in shape. The comparison with analogous spectra obtained in vitreous silica samples with impurity concentrations < 100 part per million moles is evidence of the effects of the different oxides on the vibrational properties of the OH groups. In particular, for oxide glasses a red shift of the composite band at about 3670 cm(-1), assigned to the OH stretching modes of free Si-OH groups an…

X-shooter spectroscopy of young stars with disks. The TW Hydrae association as a probe of the final stages of disk accretion

2019

We investigate ongoing accretion activity in young stars in the TW Hydrae association (TWA, ~8-10 Myr), an ideal target to probe the final stages of disk accretion down to brown dwarf masses. Our sample comprises eleven TWA members with infrared excess, amounting to 85% of the total TWA population with disks, with spectral types between M0 and M9, and masses between 0.58 and 0.02 Msol. We employed homogeneous spectroscopic data from 300 to 2500 nm, obtained with X-shooter, to derive individual extinction, stellar parameters, and accretion parameters simultaneously. We then examined Balmer lines and forbidden emission lines to probe the physics of the star-disk interaction environment. We de…

TW Hydrae association with X-shooter

2019

Measurements of the protoplanetary disk frequency in young star clusters of different ages indicate disk lifetimes <10Myr. However, our current knowledge of how mass accretion in young stars evolves over the lifespans of disks is subject to many uncertainties, especially at the lower stellar masses. In this study, we investigate ongoing accretion activity in the TW Hydrae association (TWA), the closest association of pre-main sequence stars with active disks. The age (8-10Myr) and the proximity of the TWA render it an ideal target to probe the final stages of disk accretion down to brown dwarf masses. The study is based on homogeneous spectroscopic data from 300nm to 2500nm, obtained synopt…

Characterization of particle morphology of biochanin A molecularly imprinted polymers and their properties as a potential sorbent for solid-phase ext…

2014

Abstract Molecularly imprinted polymers (MIPs) with biochanin A as a template were obtained using a bulk polymerization with non-covalent imprinting approach. The polymers were prepared in acetonitrile as porogen, using ethylene glycol dimethacrylate (EDMA) as cross-linking agent. The synthesis, with an application of 1′,1′-azobis(cyclohexanecarbonitrile) (ACHN) as an initiator, has been performed thermally. During the synthesis process the effect of different functional monomers such as methacrylic acid (MAA), acrylamide (AA) and 4-vinylpyridine (4-VP) was investigated. The application of nitrogen sorption porosimetry, scanning electron microscopy (SEM), and Fourier transform infrared spec…

Zur protonenkatalysierten Aralkylierung von 1,2,3-Trimethylindol und 1,2,3,4-Tetrahydrocarbazol mit Arylaldehyden

1987

1,2,3-Trimethylindol (2) liefert mit Benzaldehyden die Kondensationsprodukte 5 und 6, wahrend aus den NH-Indolen 1 und 3 die Verbindungen 7 und 8 entstehen. Proton-catalyzed Aralkylation of 1,2,3-Trimethylindole and 1,2,3,4-Tetrahydrocarbazole with Arylaldehydes Reaction of 1,2,3-trimethylindole (2) with benzaldehydes leads to the condensation compounds 5 and 6, the NH-indoles 1 and 3, however, give 7 and 8.

Optical properties of silver halide fibres: ageing effects

1996

The relation between the structure of fibres extruded from mixed silver halides and their IR optical losses and luminescence properties is studied. The recently established ageing effect of the considerable growth of mean grain size of the fibre's polycrystalline structure (typically from 20 to 1000 nm in two years) is correlated with IR and luminescence measurements. IR spectra measured in the interval show growth of the concentrations of molecular impurities. The luminescence measurements are used for the characterization of the fibre's structure ordering. The luminescence decay kinetics is analysed theoretically in terms of the diffusion-controlled recombination of spatially well-correla…

Temporal Control of Pulses from a High-Repetition-Rate Tunable Ti:Sapphire Laser by Active Q-switching

2003

We investigated the lasing characteristics of a Ti:sapphire laser pumped by a pulsed high-repetition-rate Nd:YAG laser. The pump laser has a pulsewidth of 450 ns, while the Ti:sapphire laser shows a significantly shorter pulse width of 25 ns for suitably intense pumping. The energy conversion efficiency of the laser is more than 10%. To synchronize different lasers and to avoid multiple spiking during one pump pulse, we use a Brewster-cut Pockels cell in the resonator for Q-switching. The temporal profile and conversion efficiency are determined and compared to theoretical estimates.

Effects of Infrared-A Irradiation on Skin: Discrepancies in Published Data Highlight the Need for an Exact Consideration of Physical and Photobiologi…

2010

Skin exposure to infrared (IR) radiation should be limited in terms of irradiance, exposure time and frequency in order to avoid acute or chronic damage. Recommendations aimed at protecting humans from the risks of skin exposure to IR (e.g. ICNIRP, ACGIH) are only defined in terms of acute effects (e.g. heat pain and cardiovascular collapse), whereas the actual exposure conditions (e.g. spectral distribution, exposure geometry, frequency and number of exposures, thermal exchange with the environment, metabolic energy production and regulatory responses) are not taken into consideration. Since the IR component of solar radiation reaching the Earth's surface is mainly IR-A, and considering th…

Analgetische Wirkstoffe, 11. Mitt. Diacylderivate des Butyroguanamins

1986

Coordination properties of adenosine-5'-monophosphate and related ligands towards Me2Sn(IV)2+ in aqueous solution.

2002

Abstract The coordination of Me 2 Sn(IV) 2+ to adenosine-5′-monophosphate (AMP) and the related compounds d -ribose-5-phosphate (R5P), d -glucose-1-phosphate (G1P) and d -glucose-6-phosphate (G6P) in aqueous solution was investigated by means of potentiometric titration, and 1 H-, 31 P-NMR and Mossbauer spectroscopic methods in the pH range 2–11 ( I =0.1 M NaClO 4 , 298 K). The complex of AMP and Me 2 Sn(IV) 2+ precipitated at low pH was characterised by elemental analysis, FT-IR and Mossbauer spectroscopic methods. From a comparison of the p K values obtained in the presence and absence of metal ion and the stability constants for the different systems, the coordination of {N} is excluded,…