Search results for "Interaction"
showing 10 items of 5710 documents
Extension of the linear solvent strength retention model including a parameter that describes the elution strength changes in liquid chromatography.
2020
Modelling the retention behaviour of solutes in liquid chromatography, based on the composition of the mobile phase is a common task in the chromatographic practice. Along the development of liquid chromatography (LC), several models have been proposed to help in understanding the retention mechanisms, and especially, allow the prediction of retention times with optimisation purposes. Particular models are used for different LC modes, such as normal phase (NPLC), reversed phase (RPLC), hydrophilic interaction (HILIC), and micellar (MLC). In this work, a general equation is proposed that includes a parameter (the elution degree, g), which characterises the way the elution strength varies wit…
Testing experimental designs in liquid chromatography (I): Development and validation of a method for the comprehensive inspection of experimental de…
2020
The basis of interpretive optimisation in liquid chromatography is the prediction of resolution, from appropriate solute retention models. The reliability of the process depends critically on the quality of the experimental design. This work develops, validates and applies a general methodology aimed to evaluate the quality of any training experimental design, which will be applied in Part II to design optimisation. The methodology is based on the systematic evaluation of the uncertainties associated to the prediction of retention times in comprehensive scans of both isocratic and gradient experimental conditions. It is able to evaluate comprehensively experimental designs of arbitrary comp…
Narrow Band Solid-Liquid Composite Arrangements: Alternative Solutions for Phononic Crystal-Based Liquid Sensors
2019
Periodic elastic composite structures attract great attention. They offer the ability to design artificial properties to advance the control over the propagation of elastic/acoustic waves. In previous work, we drew attention to composite periodic structures comprising liquids. It was shown that the transmission spectrum of the structure, specifically a well-isolated peak, follows the material properties of liquid constituent in a distinct manner. This idea was realized in several liquid sensor concepts that launched the field of phononic crystal liquid sensors. In this work we introduce a novel concept&mdash
Ferromagnetic kinetic exchange interaction in magnetic insulators
2020
The superexchange theory predicts dominant antiferromagnetic kinetic interaction when the orbitals accommodating magnetic electrons are covalently bonded through diamagnetic bridging atoms/groups. Here we show that explicit consideration of magnetic and (leading) bridging orbitals, together with the electron transfer between the former, reveals a strong ferromagnetic kinetic exchange contribution. First principle calculations show that it is comparable in strength with antiferromagnetic superexchange in a number of magnetic materials with diamagnetic metal bridges. In particular, it is responsible for a very large ferromagnetic coupling ($-10$ meV) between the iron ions in a Fe$^{3+}$-Co$^{…
Les effets de la vie privée/vie au travail sur l’attachement au travail: le rôle médiateur du fonctionnement interne de l’équipe.
2011
Work related stress and well-being: the roles of direct action coping and palliative coping
2006
The purpose of the present study is to analyze the roles of direct action coping and palliative coping in the relationship between work stressors and psychological well-being, as well as their possible interactions, in a sample of 464 bank employees. Hierarchical regression analyses showed main effects of direct action coping on well-being. Palliative coping predicts higher levels of psychological distress. Contrary to what was expected, the interactions between work stressors and direct action coping were not significant. Palliative coping interacted with work stressors when predicting psychosomatic complaints. The interaction between the two types of coping was significant on psychosomati…
Towards automatic assessment of government web sites
2013
This paper presents an approach for automatic assessment of web sites in large scale e-Government surveys. The approach aims at supplementing and to some extent replacing human evaluation which is typically the core part of these surveys.The heart of the solution is a colony inspired algorithm, called the lost sheep, which automatically locates targeted governmental material online. The algorithm centers around classifying link texts to determine if a web page should be downloaded for further analysis.The proposed algorithm is designed to work with minimum human interaction and utilize the available resources as best possible. Using the lost sheep, the people carrying out a survey will only…
Your friends mention It. What about visiting it? A mobile social-based sightseeing application
2016
In this short poster paper, we present an application for suggesting attractions to be visited by users, based on social signal processing techniques.
Comprehensive Analysis of Innovative Cross-Platform App Development Frameworks
2017
Combined People Position and Compass Detection for Context-aware Service Provision
2006
A novel technique is discussed for people identification and position sensing in augmented reality by the use of two cooperating technologies. People are provided with RFID tags for localization and context definition, and then visually investigated for identity checking and compass detection. The two technologies are discussed within an implementation of a case study dealing with context aware service provision for students in a campus.