Search results for "Interaction"
showing 10 items of 5710 documents
Sociologia del crimine. Le prospettive costruzioniste
2022
The volume has an outstanding reputation for its distinctive and systematic contribution to the criminological literature. Through detailed examples and analysis, it shows how crime is a product of processes of criminalisation constituted through the interactional and organizational use of language. In this welcome second edition, the book reviews and evaluates the current state of criminological theory from this "grammatical" perspective. It maintains and develops its critical and subversive stance but greatly widens its theoretical range, including dedicated chapters on gender, race, class and the post-als including postcolonialism. It now also provides questions, exercises and further re…
Host-Guest Complexes of C-Ethyl-2-methylresorcinarene and Aromatic
2017
Abstract The C‐ethyl‐2‐methylresorcinarene (1) forms 1:1 in‐cavity complexes with aromatic N,N′‐dioxides, only if each of the aromatic rings has an N−O group. The structurally different C‐shaped 2,2′‐bipyridine N,N′‐dioxide (2,2′‐BiPyNO) and the linear rod‐shaped 4,4′‐bipyridine N,N′‐dioxide (4,4′‐BiPyNO) both form 1:1 in‐cavity complexes with the host resorcinarene in C 4v crown and C 2v conformations, respectively. In the solid state, the host–guest interactions between the 1,3‐bis(4‐pyridyl)propane N,N′‐dioxide (BiPyPNO) and the host 1 stabilize the unfavorable anti‐gauche conformation. Contrary to the N,N′‐dioxide guests, the mono‐N‐oxide guest, 4‐phenylpyridine N‐oxide (4PhPyNO), does …
Conformational investigation of α,β‐dehydropeptides. XV: N‐acetyl‐α,β‐dehydroamino acid N ′N ′‐dimethylamides: conformational properties from infrare…
2005
The FTIR spectra were analysed in the region of the nu(s)(N-H), AI(C=O) and nu(s)(Calpha=Cbeta) bands for a series of Ac-DeltaXaa-NMe2, where DeltaXaa = DeltaAla, (Z)-DeltaAbu, (Z)-DeltaLeu, (Z)-DeltaPhe and DeltaVal, to determine a predominant solution conformation of these alpha,beta-dehydropeptide-related molecules. Measurements were taken in CCl4, DCM and MeCN solutions. In the same way, spectra of saturated analogues Ac-Xaa-NMe2, where Xaa = Ala, Abu, Leu, Phe and Val, were investigated. To help interpret the spectroscopic results, conformational maps were calculated by the B3LYP/6-31+G** method. Also, the relative energies of all conformers of the dehydro compounds in vacuo as well as…
Methionine in a protein hydrophobic core drives tight interactions required for assembly of spider silk
2019
Web spiders connect silk proteins, so-called spidroins, into fibers of extraordinary toughness. The spidroin N-terminal domain (NTD) plays a pivotal role in this process: it polymerizes spidroins through a complex mechanism of dimerization. Here we analyze sequences of spidroin NTDs and find an unusually high content of the amino acid methionine. We simultaneously mutate all methionines present in the hydrophobic core of a spidroin NTD from a nursery web spider’s dragline silk to leucine. The mutated NTD is strongly stabilized and folds at the theoretical speed limit. The structure of the mutant is preserved, yet its ability to dimerize is substantially impaired. We find that side chains of…
Interactions and patterns between species diversity and genetic diversity
2015
Naja, normal und normal. Zur Syntax, Semantik und Pragmatik der x-und-x-Konstruktion im Deutschen
2012
This article deals with the syntax, semantics and pragmatics of the x und x (‘x and x’) construction in German, cf. A: Schade, dass die [Schabracken] so teuer sind! B: Naja, teuer und teuer, wenn die Qualitat stimmt, dann finde ich den Preis okay. (A: ‘What a pity that the horsetrappers are so expensive!’ B: ‘Well, expensive and expensive, if the quality is good, the price is fine with me.’). The specific discourse function of this construction is to negotiate the situational meaning of a previously used lexical item. Typologically, it has been claimed that the pattern is language-specific for Scandinavian. The paper challenges this assumption, providing empirical evidence from a questionna…
Multimodale Analyse von Interaktion im fremdsprachlichen Klassenzimmer
2016
The article offers a contribution to the interaction research in the foreign language teaching and learning. It starts with an overview of various research approaches to the foreign language teaching and learning, from the 60s to the present days. A multimodal analysis of an excerpt of videorecorded classroom interaction is then provided. The analysis is focused on several aspects of classroom participation and teaching sequences. Some implications of the present research for teachers' training are finally provided.
(In)congruence between presupposing teacher turns and the student’s epistemic stance : case analysis of teacher turns that presuppose the student to …
2017
Episteemisyyden eli tietoon pääsyn tutkiminen luokkahuonevuorovaikutuksessa on kasvattanut suosiotaan keskustelunanalyyttisessa tutkimuksessa viime vuosina. Kasvavan kiinnostuksen taustalla on ajatus siitä, että oppiminen tapahtuu vuorovaikutuksessa toisten kanssa, kun taas vuorovaikutusta ajaa eteenpäin osallistujien välinen tiedollinen epäsymmetria. Tämän tutkimuksen tarkoitus on lisätä tietoa episteemisyydestä luokkahuonevuorovaikutuksessa. Tarkastelin opettajan aloitevuoroja, joihin oli sisäänrakennettuna oletus oppilaan pääsystä tietoon eli oletus siitä, että oppilas tietää vastauksen kysymykseen. Lisäksi tarkastelin oppilaiden vastauksia opettajan kysymyksiin, sekä niitä seuraavia ope…
Teacher smiles as an interactional and pedagogical resource in the classroom
2020
In classroom settings, laughter and smiles are resources for action that are available to both teachers and students. Recent interactional studies have documented how students use these resources to deal with trouble of various kind, but less is known about the sequential and activity contexts of teachers’ laughter-relevant practices, as well as their pedagogical functions. We use multimodal conversation analysis (CA) to investigate the interactional unfolding and pedagogical orientations of teacher smiles during instructional IRE (initiation-response-evaluation) sequences in a corpus of 37 bilingual lessons collected in schools in Finland and Spain. In analysing the focal smiles, we pay at…
Clarification requests as a method of pursuing understanding in CLIL physics lectures
2018
AbstractUsing multimodal conversation analysis, this article examines how students strive to resolve non-understandings through requests for clarification during teacher-fronted physics lectures ta...