Search results for "Interactions"

Une spéléogenèse à acide sulfurique dans le piémont nord-pyrénéen ?

2018

Tout au long de l’histoire de structuration des Pyrénées, le jeu des grands accidents tectoniquesfont de la zone de piémont nord-pyrénéen une aire privilégiée de circulation de fluides. Parmiceux-ci, la présence de saumures profondes riches en CO2 et H2S a été attestée dans les réservoirspétroliers sud-aquitains d’âge Crétacé. Impliqués dans des processus de migration vers les margesde bassin, ces fluides sont susceptibles de former des cavités dans l’encaissant calcaire là où lesremontées d’H2S entrent en contact avec du dioxygène, produisant ainsi du H2SO4. C’est cettehypothèse de spéléogenèse à acide sulfurique (SAS) que la présente étude cherche à explorer dansles Pyrénées.Les premières…

Effect of host plant quality on male sexual performances and consequences on female reproductive output in a phytophagous moth

2016

The abundance of phytophagous insects is determined by numerous interacting biotic and abiotic factors. In capital-breeding phytophagous insects, larval host plant quality is a key determinant of the adult phenotype and the performance of both males and females. Curiously, if the effect of host plant quality on female reproductive success is well-established, little effort has been conducted to determine this effect on male reproductive success. Moreover, in Lepidoptera, males transfer to females a spermatophore containing sperm and accessory gland products rich in nutrients that could be reinvested into female reproduction. The aim of this thesis was to evaluate how male larval nutrition o…

Solvent-induced free energy landscape and solute-solvent dynamic coupling in a multielement solute

1999

AbstractMolecular dynamics simulations using a simple multielement model solute with internal degrees of freedom and accounting for solvent-induced interactions to all orders in explicit water are reported. The potential energy landscape of the solute is flat in vacuo. However, the sole untruncated solvent-induced interactions between apolar (hydrophobic) and charged elements generate a rich landscape of potential of mean force exhibiting typical features of protein landscapes. Despite the simplicity of our solute, the depth of minima in this landscape is not far in size from free energies that stabilize protein conformations. Dynamical coupling between configurational switching of the syst…

Use of Catalyst in a 3D-QSAR Study of the Interactions between Flavor Compounds and β-Lactoglobulin

2003

This paper reports a 3D-QSAR study using Catalyst software to explain the nature of interactions between flavor compounds and beta-lactoglobulin. A set of 35 compounds, for which dissociation constants were previously determined by affinity chromatography, was chosen. The set was divided into three subsets. An automated hypothesis generation, using HypoGen software, produced a model that made a valuable estimation of affinity and provided an explanation for the lack of correlation previously observed between the hydrophobicity of terpenes and the affinity for the protein. On the basis of these results, it appears that aroma binding to beta-lactoglobulin is caused by both hydrophobic interac…

Determination of the hydrophobicity of organic compounds measured as logPo/w through a new chromatographic method

2009

A new chromatographic method to determine the octanol-water partition coefficient (logP(o/w)) of organic substances is proposed in this paper. This method is based on a previously reported model that relates the retention factor in reversed-phase liquid chromatography with solute (p), mobile phase (P(m)(N)) and stationary phase (P(s)(N)) polarity parameters: logk=(logk)(0)+p(P(m)(N)-P(s)(N)). P(m)(N) values are calculated through expressions that depend only on the organic solvent fraction in the mobile phase. (logk)(0) and P(s)(N) parameters are characteristic of the chromatographic system and are determined from the retention of a selected set of 12 compounds. Then, the p value of a solut…

Event-based criteria in GT-STAF information indices: theory, exploratory diversity analysis and QSPR applications

2012

Versatile event-based approaches for the definition of novel information theory-based indices (IFIs) are presented. An event in this context is the criterion followed in the "discovery" of molecular substructures, which in turn serve as basis for the construction of the generalized incidence and relations frequency matrices, Q and F, respectively. From the resultant F, Shannon's, mutual, conditional and joint entropy-based IFIs are computed. In previous reports, an event named connected subgraphs was presented. The present study is an extension of this notion, in which we introduce other events, namely: terminal paths, vertex path incidence, quantum subgraphs, walks of length k, Sach's subg…

Spin‐Chain‐Star Systems: Entangling Multiple Chains of Spin Qubits

2022

We consider spin-chain-star systems characterized by N-wise many-body interactions between the spins in each chain and the central one. We show that such systems can be exactly mapped into standard spin-star systems through unitary transformations. Such an approach allows the solution of the dynamic problem of an XX$X X$ spin-chain-star model and transparently shows the emergence of quantum correlations in the system, based on the idea of entanglement between chains.

Exotic interactions mediated by a non-Hermitian photonic bath

2022

Photon-mediated interactions between quantum emitters in engineered photonic baths is an emerging area of quantum optics. At the same time, non-Hermitian (NH) physics is currently thriving, spurred by the exciting possibility to access new physics in systems ruled by non-trivial NH Hamiltonians - in particular photonic lattices - which can challenge longstanding tenets such as the Bloch theory of bands. Here, we combine these two fields and study the exotic interaction between emitters mediated by the photonic modes of a lossy photonic lattice described by a NH Hamiltonian. We show in a paradigmatic case study that structured losses in the field can seed exotic emission properties. Photons …

Quantum Chemical Calculations Predict the Diphenyl Diuranium Compound [PhUUPh] To Have a Stable1Ag Ground State

2006

Measurement of the chi(b) (3 P) mass and of the relative rate of chi(b1) (1 P) and chi(b2) (1 P) production

2014

The production of $\chi_b$ mesons in proton-proton collisions is studied using a data sample collected by the LHCb detector, at centre-of-mass energies of $\sqrt{s}=7$ and $8$ TeV and corresponding to an integrated luminosity of 3.0 fb$^{-1}$. The $\chi_b$ mesons are identified through their decays to $\Upsilon(1S)\gamma$ and $\Upsilon(2S)\gamma$ using photons that converted to $e^+e^-$ pairs in the detector. The $\chi_b(3P)$ meson mass, and the relative prompt production rate of $\chi_{b1}(1P)$ and $\chi_{b2}(1P)$ mesons as a function of the $\Upsilon(1S)$ transverse momentum in the $\chi_b$ rapidity range 2.0< $y$<4.5, are measured. Assuming a mass splitting between the $\chi_{b1}(3P)$ an…