Search results for "Interactions"

Crystal structure of chlorido(2-{[2-(4-chlorophenyl)hydrazin-1-ylidene-κN1](phenyl)methyl}pyridine-κN)(η5-pentamethylcyclopentadienyl)iridium(III) te…

2015

The title compound, [Ir(η5-C5Me5)Cl(C18H14ClN3)]B(C6H5)4, is chiral at the metal center and crystallizes as a racemate. In the cation, the hydrazinylidenepyridine ligand isN,N-coordinated through theN-pyridyl andN-hydrazinylidene groups forming a five-membered metallacycle. An intramolecular C—H...Cl hydrogen bond is observed. In the crystal, centrosymmetrically-related cations are connected by C—Cl...π interactions, forming a dimeric structure. The crystal packing is further stabilized by weak interionic C—H...π interactions.

Preparation of potentially porous, chiral organometallic materials through spontaneous resolution of pincer palladium conformers.

2013

Understanding the mechanism by which advanced materials assemble is essential for the design of new materials with desired properties. Here, we report a method to form chiral, potentially porous materials through spontaneous resolution of conformers of a PCP pincer palladium complex ({2,6-bis[(di-t-butylphosphino)methyl]phenyl}palladium(II)halide). The crystallisation is controlled by weak hydrogen bonding giving rise to chiral qtz-nets and channel structures, as shown by 16 such crystal structures for X = Cl and Br with various solvents like pentane and bromobutane. The fourth ligand (in addition to the pincer ligand) on palladium plays a crucial role; the chloride and the bromide primaril…

Réponses de la plante et des microorganismes du sol aux changements environnementaux

2015

Iontophoresis: electrorepulsion and electroosmosis.

2000

Over the last 10-15 years, the electrical enhancement of drug delivery across the skin has undergone intense investigation. During this period, considerable amounts of experimental data have been generated, and the successful enhancement of a diverse array of molecules has been achieved. Indeed, the commercial exploitation of the method can be envisaged within the next few years. Despite this progress, however, the mechanistic understanding of iontophoresis remains a challenging scientific question that is yet to be fully resolved. The routes of permeation under the influence of an applied electrical potential, and the molecular interactions of the transporting drug with these pathways, hav…

B‐DNA structure and stability: the role of nucleotide composition and order

2022

Abstract We have quantum chemically analyzed the influence of nucleotide composition and sequence (that is, order) on the stability of double‐stranded B‐DNA triplets in aqueous solution. To this end, we have investigated the structure and bonding of all 32 possible DNA duplexes with Watson–Crick base pairing, using dispersion‐corrected DFT at the BLYP‐D3(BJ)/TZ2P level and COSMO for simulating aqueous solvation. We find enhanced stabilities for duplexes possessing a higher GC base pair content. Our activation strain analyses unexpectedly identify the loss of stacking interactions within individual strands as a destabilizing factor in the duplex formation, in addition to the better‐known eff…

Faire déguster et parler de son vin pour le faire aimer et le vendre : quelques stratégies dans des interactions producteur-client

2015

International audience; Cette contribution, qui s’inscrit dans le projet global OenoLex Bourgogne, vise une analyse discursive d’interactions authentiques entre des professionnels bourguignons du vin et des clients (potentiels) en contexte de dégustation. Elle présente le corpus original produit dans le cadre du projet et met l’accent sur les stratégies de transmission de connaissancestechniques et sur les argumentaires de vente développés par les producteurs et/ou vendeurs

Study of Σ(1385) and Ξ(1321) hyperon and antihyperon production in deep inelastic muon scattering

2013

Large samples of \Lambda, \Sigma(1385) and \Xi(1321) hyperons produced in deep-inelastic muon scattering off a ^6LiD target were collected with the COMPASS experimental setup at CERN. The relative yields of \Sigma(1385)^+, \Sigma(1385)^-, \bar{\Sigma}(1385)^-, \bar{\Sigma}(1385)^+, \Xi(1321)^-, and \bar{\Xi}(1321)^+ hyperons decaying into \Lambda(\bar{\Lambda})\pi were measured. The heavy hyperon to \Lambda and heavy antihyperon to \bar{\Lambda} yield ratios were found to be in the range 3.8% to 5.6% with a relative uncertainty of about 10%. They were used to tune the parameters relevant for strange particle production of the LEPTO Monte Carlo generator.

Extracting (good) discourse examples from an oral specialised corpus of wine tasting interactions

2015

International audience; This article outlines the semi-automated extraction of dictionary examples used in the compilation of a professional online dictionary of wine tasting. Named OenoLex Bourgogne, this dictionary was started to respond to the demand for a lexicographic information tool from the French wine industry of Burgundy, the Bureau Interprofessionnel des Vins de Bourgogne.

Effective Hamiltonians in Nonrelativistic Quantum Electrodynamics

2021

In this paper, we consider some second-order effective Hamiltonians describing the interaction of the quantum electromagnetic field with atoms or molecules in the nonrelativistic limit. Our procedure is valid only for off-energy-shell processes, specifically virtual processes such as those relevant for ground-state energy shifts and dispersion van der Waals and Casimir-Polder interactions, while on-energy-shell processes are excluded. These effective Hamiltonians allow for a considerable simplification of the calculation of radiative energy shifts, dispersion, and Casimir-Polder interactions, including in the presence of boundary conditions. They can also provide clear physical insights int…

Neutrino-nuclear responses for astro-neutrinos, single beta decays and double beta decays

2019

Neutrino–nuclear responses associated with astro-neutrinos, single beta decays and double beta decays are crucial in studies of neutrino properties of interest for astro-particle physics. The present report reviews briefly recent studies of the neutrino–nuclear responses from both experimental and theoretical points of view in order to obtain a consistent understanding of the many facets of the neutrino–nuclear responses. Subjects discussed in this review include (i) experimental studies of neutrino–nuclear responses by means of single beta decays, charge-exchange nuclear reactions, muon- photon- and neutrino–nuclear reactions, and nucleon-transfer reactions, (ii) implications of and discus…