Search results for "Interfaces"

Ion-ion correlation and charge reversal at titrating solid interfaces

2009

Confronting grand canonical titration Monte Carlo simulations (MC) with recently published titration and charge reversal (CR) experiments on silica surfaces by Dove et al. and van der Heyden it et al, we show that ion-ion correlations quantitatively explain why divalent counterions strongly promote surface charge which, in turn, eventually causes a charge reversal (CR). Titration and CR results from simulations and experiments are in excellent agreement without any fitting parameters. This is the first unambiguous evidence that ion-ion correlations are instrumental in the creation of highly charged surfaces and responsible for their CR. Finally, we show that charge correlations result in "a…

Mobile supported monolayers of ionic amphiphiles: variation of domain morphology via preadsorbed polyelectrolytes

1992

Formal Concept Analysis of Musicians' Awareness for Musical Expression

2009

This paper proposes a logical framework that visualizes musicians' conceptual structures that are acquired in skill communication processes for musical expression as rhetoric. Generally, these conceptual structures are difficult to show difference between experts and beginners. So, we first carry out a theoretical analysis of musicians' awareness for musical expression using Channel theory and Formal Concept Analysis (FCA). Then, we propose a representation that shows the level of musicians' skills of musical expression. Finally, we discussed about hierarchy of musicians' conceptual structure.

Possibilities of Elementary Musical Lessons for Children Communication Skills

2012

Object of the paper - explore the possibilities of musical lesson for the child for communication skills. The paper was used for theoretical metod - analysis of scientific literature and empirical research method – pedagogical observations of individual and group lessons. Theoretically and practically explored and described possibilities of music lessons for communication skills. The author main conclusions of the study: 1. By participating in the musical play, children are encouraged musical hearing, physical coordination, language development, emotional and social development, communication and independence skills, etc. 2. When creating classesmodels to integrate all the musical creativit…

La « Révolution Conservatrice » en linguistique : linguiste Staline entre « notions essentielles » et l’esprit de Weimar

2021

Fascicule en libre accès sur le site de l'éditeur - ISBN : 978-5-91674-626-6; International audience; Publié lors de la discussion linguistique de 1950, le texte de Staline laisse entendre une continuité avec la tradition, ce qui implique l’image d’une société soviétique qui a réussi à conserver son caractère «traditionnaliste» malgré des coupures historiques évidentes. Cette «continuité» serait en grande partie assurée par la langue dite nationale. Plusieurs éléments «révolutionnaires-conservateurs» du texte de Staline font penser à la métaphore de l’«Allemagne russe» comme à l’une de ses sources conceptuelles.

Role of Ge nanoclusters in the performance of photodetectors compatible with Si technology

2013

In this work, we investigate the spectral response of metal-oxide- semiconductor photodetectors based on Ge nanoclusters (NCs) embedded in a silicon dioxide (SiO2) matrix. The role of Ge NC size and density on the spectral response was evaluated by comparing the performance of PDs based on either densely packed arrays of 2 nm-diameter NCs or a more sparse array of 8 nm-diameter Ge NCs. Our Ge NC photodetectors exhibit a high spectral responsivity in the 500-1000 nm range with internal quantum efficiency of ~ 700% at - 10 V, and with NC array parameters such as NC density and size playing a crucial role in the photoconductive gain and response time. We find that the configuration with a more…

Noble metal nanoparticles in organic matrix

2020

Abstract The purpose of this work is the synthesis and study of the properties of nanocomposite structures created by noble metal (silver) nanoparticles (NP's), an exciting class of materials with unique properties differ from both bulk and atomic behavior, which are self-organize in a thin organic film of copper phthalocyanine (CuPc). The structure and morphology of this material, depending on the amount of deposited silver, was studied in ultrahigh vacuum using transmission electron microscopy (TEM) and photoelectron spectroscopy (PES). Metallic atoms deposited on the surface of an organic substrate diffuse into the substrate, forming NPs with a narrow size distribution, which correlates …

Nanocomposites by Electrostatic Interactions:  1. Impact of Sublayer Quality on the Organization of Functionalized Nanoparticles on Charged Self-Asse…

2000

Bis-benzamidines were studied as linkers for the formation of gold nanoparticle assemblies on planar gold surfaces modified with ω-mercaptohexadecanoic acid. In situ ellipsometry, external reflecti...

Ce:YAG nanoparticles embedded in a PMMA matrix: preparation and characterization

2010

A Ce:YAG-poly(methyl methacrylate) composite was prepared using in situ polymerization by embedding the Ce:YAG nanopowder in a blend of methyl methacrylate (MMA) and 2-methacrylic acid (MAA) monomers and activating the photopolymerization using a radical initiator. The obtained nanocomposite was yellow and transparent. Its characterization was performed using transmission electron microscopy, small angle X-ray scattering, (13)C cross-polarization magic-angle spinning nuclear magnetic resonance, and photoluminescence spectroscopy. Results showed that Ce:YAG nanoparticles are well dispersed in the polymeric matrix whose structure is organized in a lamellar shape. The luminescence properties o…

Au-PVA Nanocomposite Negative Resist for One-Step Three-Dimensional e-Beam Lithography

2009

Au nanoparticles are synthesized in situ upon the electron beam exposure of a poly(vinyl alcohol) (PVA) thin film containing Au(III). The e-beam-irradiated areas are insoluble in water (negative-tone resist), and Au-PVA nanocomposite patterns with a variable profile along the structure can be thus generated (3D lithography) in a single step. A local characterization of the generated patterns is performed by high-resolution transmission electron microscopy and UV-vis localized surface plasmon resonance microspectroscopy. This characterization confirms the presence of crystalline nanoparticles and aggregates.