Search results for "Ionization."
showing 10 items of 1229 documents
Comparison of various liquid chromatographic methods for the analysis of avermectin residues in citrus fruits.
2001
Abstract Various liquid chromatographic (LC) techniques for analyzing avermectin (Abamectin) were compared after extraction of residues from citrus fruit samples by matrix solid-phase dispersion (MSPD). LC with UV and fluorescence detection were used as also was LC coupled to the mass spectrometer by an electrospray interface. The results obtained by the three methods were compared in terms of sensitivity and selectivity. The combination of MSPD extraction and LC with fluorescence detection have made it possible to quantify 0.5 μg kg −1 of Abamectin in 0.5 g of orange sample, with an overall average recovery of 94%. The procedure provides a simple and sensitive method for monitoring Abamect…
Nanoelectrospray with ion-trap mass spectrometry for the determination of beta-casomorphins in derived milk products.
2009
Beta-casomorphins (b-CMs) are bioactive peptides derived from casein with opioid agonist effects similar to morphine. The use of electrospray (ESI) with quadrupole ion-trap mass spectrometry (QIT-MS) for these compounds in two matrices, cheese and milk, was examined. It was compared to a liquid chromatography (LC) coupled to mass spectrometry (LC-MS), and a "soft" ionisation technique, NanoMate, with selected ion monitoring (SIM), which are unreliable for the determination of trace casomorphins in derived milk products. b-CM mass fragmentation pathways were done for the four most common b-CMs: beta-casomorphin (1-5) bovine (b-CM-5), beta-casomorphin (1-7) bovine (b-CM-7), [D-Ala2, D-Pro4,Ty…
Analysis of meat samples for anabolic steroids residues by liquid chromatography/tandem mass spectrometry.
2007
A rapid, specific and highly sensitive multi-residue method for the determination of anabolic steroid residues in bovine, pork and poultry muscle tissues was developed. The sample preparation involves enzymatic digestion followed by extraction with methanol. The crude extract was cleaned up by solid-phase extraction (SPE) combining C18 and NH2 columns. The detection was carried out by a highly sensitive liquid chromatography/electrospray ionization tandem mass spectrometry (LC/ESI-MS/MS) method using both positive and negative ionization modes. Natural and synthetic steroids covering different polarities could be extracted, concentrated and purified using one single method. Mobile phase com…
Fire safety investigation for road tunnel ventilation systems – An overview
2014
Abstract In recent years, research activities about fire events in tunnel have received a significant impulse, especially after several accidents. The Computational Fluid Dynamic (CFD) has a fundamental role about. Researchers have spent resources on various topics involving numerical tools as the performance of a ventilation system, the influence of this on the air flow motion in the tunnel or the methods for fire schematization, fire-induced smoke characterization, turbulence models, etc. One of the main phenomena to consider for the safety when a fire occurs in a tunnel is the possibility of the fire-induced smoke to rise the tunnel (backlayering). A well-designed ventilation system shal…
Finite-Difference Time-Domain Simulation of Towers Cascade Under Lightning Surge Conditions
2015
In this paper, the simulation of towers cascade under lightning surge conditions is presented. Finite-difference time-domain method is used to solve both the Maxwell's and telegraph equations. Maxwell's equations and the time-domain resistivity model of Darveniza are used to simulate the nonlinear behavior of the grounding system. Telegraph equations are used to describe the propagation in the overhead lines. Multiple ionizations, on different grounding electrodes belonging to various towers, can be implemented simultaneously, without making assumptions on the shape of the ionized areas.
On the sway stability improvement of car–caravan systems by articulated connections
2015
The present analysis is addressed to some promising connection arrangements between the towing vehicles and the towed trailers, where the two units are linked by four-bar isosceles trapeziums in place of the conventional pintle hitch. Two types of instability, of the divergent type or the oscillating type, may be analysed by the Routh–Hurwitz criterion or by the direct analysis of the characteristic equation. The constant term of this equation vanishes at the divergent instability threshold (zero of a real root), whereas the equation splits into two lower degree algebraic ‘sub-equations’ when the oscillating instability arises (pair of pure imaginary roots). A large field of geometrical con…
Finite difference time domain simulation of earth electrodes soil ionisation under lightning surge condition
2008
The non linear effects of soil ionisation on the behaviour of earth electrodes are investigated by a finite difference time domain numerical scheme. A time variable soil resistivity is used in order to simulate the soil breakdown; step by step the resistivity value is controlled by the local instantaneous value of the electric field compared with the electrical strength, fixed for the soil. No a priori hypothesis about the geometrical shape of the ionised zone around the electrodes has to be enforced. Simulation results related to complex earth electrodes of limited extension are reported. The model has been validated by comparing the computed results with data available in technical litera…
Recent Development in Analytical Methods for Identification of Off-Flavour Compounds
1983
The best resolution of individual off-flavour compounds is achieved by glass or quartz capillary gas chromatography. A special two-column system was used by which simultaneous instrumental detection and sniffing (odour desorption) of odorous compounds could be done. The measuring detectors were flame ionization (FID), electron capture (ECD), flame photometric (FPD) and a mass spectrometer (MS). Structural assignments of the odorous substances were done from MS data and verified by model compounds. Before the GC run the sample was collected at the head of the double column using a cold trap device. The sample for analysis was injected in liquid form or, more efficiently, thermally desorbed f…
Rapid and improved identification of drinking water bacteria using the Drinking Water Library, a dedicated MALDI-TOF MS database.
2021
Abstract According to the European Directives (UE) 2020/2184 and 2009/54/EC, which establishes the sanitary criteria for water intended for human consumption in Europe, water suitable for human consumption must be free of the bacterial indicators Escherichia coli, Clostridium perfringens and Enterococcus spp. Drinking water is also monitored for heterotrophic bacteria, which are not a human health risk, but can serve as an index of bacteriological water quality. Therefore, a rapid, accurate, and cost-effective method for the identification of these colonies would improve our understanding of the culturable bacteria of drinking water and facilitate the task of water management by treatment f…
Measurement of pollution levels of N-nitroso compounds of health concern in water using ultra-performance liquid chromatography–tandem mass spectrome…
2017
International audience; This paper reports the development of a highly sensitive analytical method combining solid-phase extraction (SPE) with ultra-high performance liquid chromatography coupled with tandem mass spectrometry (UHPLC–MS/MS), for the monitoring of ultra-trace levels of N-nitrosamines in water samples. Under optimized analytical conditions, chromatographic separation was performed in 3 min, in isocratic mode, using an Acquity UHPLC C18 column and a mobile phase consisting of acetonitrile, water, and formic acid (60:40:0.1, v/v/v) at a flow rate of 0.4 mL min−1. Electrospray ionization tandem interface was employed prior to mass spectrometric detection. Good linearity (R2 ≥ 0.9…