Search results for "Isoindole"

showing 10 items of 83 documents

The Reactivity of 4’-Substituted Spiro[Isoindole-1,3’-pyrazoles] Derivatives: Substitution/Elimination Reactions and Access to Biaryl Derivatives

2017

This paper describes aspects of the chemistry of 4’-substituted spiro [indole-1,3’-pyrazoles]. These compounds underwent substitution and/or elimination reactions to afford some new spiro- as well as biaryl derivatives of potential pharmaceutical relevance. Mechanistic considerations are discussed as well.

Pharmacologychemistry.chemical_compoundElimination reaction4’-substituted spiro [indole-13’-pyrazoles] elimination reactions biaryl derivatives Mechanistic considerationschemistryOrganic ChemistrySubstitution (logic)Reactivity (chemistry)Settore CHIM/06 - Chimica OrganicaIsoindoleSettore CHIM/08 - Chimica FarmaceuticaCombinatorial chemistryAnalytical ChemistryHETEROCYCLES
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2-(2-Iodoethyl)isoindole-1,3-dione

2007

The title compound, C10H8INO2, is an N-substituted phthalimide derivative in which the crystallographic inter­molecular contact pattern consists of I⋯I, C—H⋯I, C—H⋯O and aromatic π–π inter­actions.

Phthalimidechemistry.chemical_compoundchemistryGeneral Materials ScienceGeneral ChemistryCondensed Matter PhysicsIsoindoleMedicinal chemistryDerivative (chemistry)Acta Crystallographica Section E Structure Reports Online
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A novel pro-apoptotic role of zinc octacarboxyphthalocyanine in melanoma me45 cancer cell's photodynamic therapy (PDT)

2018

Abstract Zn-based phthalocyanine acts as drug or photosensitizer in photodynamic therapy (PDT) for the treatment of cancer cells. The activated zinc octacarboxyphthalocyanine (ZnPcOC) reacts with oxygen, to generate reactive oxygen species for the damage of melanoma cancer cells, Me45. This in vitro study aimed at investigating the cytotoxic effects of different concentrations of ZnPcOC activated with a diode laser (λ = 685 nm) on Me45, and normal human fibroblast cells, NHDF. To perform this study 104 cells/ml were seeded in 96-well plates and allowed to attach overnight, after which cells were treated with different concentrations of ZnPcOC (10, 20 and 30 μM). After 4 h, cells were irradi…

Programmed cell deathIndolesCell Survivalmedicine.medical_treatmentPhotodynamic therapy (PDT)030303 biophysicsBiophysicsApoptosisPhotodynamic therapy02 engineering and technologyIsoindolesZinc octacarboxyphthalocyanine (ZnPcOC)PhotosensitizersCell Line03 medical and health sciencesCell Line TumorOrganometallic CompoundsmedicineHumansCytotoxic T cellRadiology Nuclear Medicine and imagingPhotosensitizerViability assayMelanoma0303 health sciencesPhotosensitizing AgentsRadiationRadiological and Ultrasound TechnologyChemistryMelanomaReactive oxygen species (ROS)UV–Vis spectraFibroblasts021001 nanoscience & nanotechnologymedicine.diseasePhotochemotherapyZinc CompoundsApoptosisCancer cellCancer researchMelanoma Me45 cancer cellsLasers SemiconductorPro-apoptotic activityReactive Oxygen Species0210 nano-technologyJournal of Photochemistry and Photobiology B-Biology
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Hypoxia-induced dysfunction of rat diaphragm

2004

Contains fulltext : 47331.pdf (Publisher’s version ) (Closed access) Oxidants may play a role in hypoxia-induced respiratory muscle dysfunction. In the present study we hypothesized that hypoxia-induced impairment in diaphragm contractility is associated with elevated peroxynitrite generation. In addition, we hypothesized that strenuous contractility of the diaphragm increases peroxynitrite formation. In vitro force-frequency relationship, isotonic fatigability, and nitrotyrosine levels were assessed under hypoxic (Po(2) approximately 6.5 kPa) and hyperoxic (Po(2) approximately 88.2 kPa) control conditions and also in the presence of authentic peroxynitrite (60 min), ebselen (60 min), and t…

Pulmonary and Respiratory MedicineAzolesMalemedicine.medical_specialtyPhysiologyDiaphragmAetiology screening and detection [ONCOL 5]In Vitro TechniquesIsoindolesNitric oxideContractilitychemistry.chemical_compoundTranslational research [ONCOL 3]Physiology (medical)Internal medicineOrganoselenium CompoundsPeroxynitrous AcidmedicineRespiratory muscleAnimalsRespiratory systemEnzyme InhibitorsRats WistarHypoxiaHeart lung and circulation [UMCN 2.1]Renal disorder [IGMD 9]omega-N-MethylarginineNitrotyrosineCell BiologyHypoxia (medical)Tissue engineering and pathology [NCMLS 3]musculoskeletal systemRatsPathogenesis and modulation of inflammation [N4i 1]EndocrinologychemistryBiochemistryMuscle FatigueTyrosineRat DiaphragmLipid Peroxidationmedicine.symptomPeroxynitriteMuscle ContractionAmerican Journal of Physiology - Lung Cellular and Molecular Physiology
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Aza-isoindolo and isoindolo-azaquinoxaline derivatives with antiproliferative activity

2015

Abstract Three new ring systems, pyrido[2′,3′:3,4]pyrrolo[1,2- a ]quinoxalines, pyrido[3′,2′:3,4]pyrrolo[1,2- a ]quinoxalines and pyrido[2′,3′:5,6]pyrazino[2,1- a ]isoindoles, were synthesized through an aza-substitution on the already active isoindolo-quinoxaline system and in particular in the position 7 or 4 of the isoindole moiety and in position 5 of the quinoxaline portion. All new compounds were screened by the National Cancer Institute (Bethesda, MD) against a panel of 60 human tumor cell lines. Biological results of the most active derivatives, with pGI 50 values between 7.09 and 7.27, confirmed the importance of the presence of methoxy substituents for biological activity. The ant…

QuinoxalineIsoindolesAzaisoindolo-quinoxalinesStereochemistryAntiproliferative activity; Apoptosis; Azaisoindolo-quinoxalines; DNA interaction; Isoindolo-azaquinoxalines; Quinoxalines; Antineoplastic Agents; Apoptosis; Aza Compounds; Cell Line Tumor; Cell Proliferation; Dose-Response Relationship Drug; Drug Screening Assays Antitumor; Humans; Isoindoles; Molecular Structure; Quinoxalines; Structure-Activity Relationship; Drug Discovery3003 Pharmaceutical Science; Organic Chemistry; Pharmacology; Medicine (all)ApoptosisAntineoplastic AgentsAntiproliferative activityIsoindolesRing (chemistry)Drug Screening AssaysCell LineDose-Response Relationshipchemistry.chemical_compoundStructure-Activity RelationshipQuinoxalineCell Line TumorQuinoxalinesDrug DiscoverymedicineMoietyHumansAntiproliferative activity; Apoptosis; Azaisoindolo-quinoxalines; DNA interaction; Isoindolo-azaquinoxalines; Quinoxalines; Drug Discovery3003 Pharmaceutical Science; Organic Chemistry; PharmacologyCell ProliferationPharmacologyAza CompoundsAzaisoindolo-quinoxalineTumorDose-Response Relationship DrugMolecular StructureDrug Discovery3003 Pharmaceutical ScienceMedicine (all)Organic ChemistryApoptosiBiological activityGeneral MedicineAntitumorCell cycleSettore CHIM/08 - Chimica FarmaceuticaDNA interactionSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialiMechanism of actionchemistryIsoindolo-azaquinoxalineDrug Screening Assays Antitumormedicine.symptomDrugIsoindoleIsoindolo-azaquinoxalines
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CCDC 263681: Experimental Crystal Structure Determination

2005

Related Article: D.Schollmeyer, R.Hoffmann, J.Mattay|2005|Acta Crystallogr.,Sect.E:Struct.Rep.Online|61|o290|doi:10.1107/S1600536805000140

Space GroupCrystallography(-)-(3a'S4'S9b'S1R2S5R)-4'-Ethyl-3a'4'5'7'8'9b'-hexahydro-2-isopropyl-5-methyl-2'-phenylspiro(cyclohexane-17'-dioxino(32-e)isoindole)-1'3'9'-trioneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1547096: Experimental Crystal Structure Determination

2018

Related Article: Himadri Sekhar Sarkar, Sujoy Das, Kari Rissanen, Prithidipa Sahoo|2017|Anal.Chem.|89|13054|doi:10.1021/acs.analchem.7b04430

Space GroupCrystallography3'6'-bis(diethylamino)-2-(pyridin-2-yl)spiro[isoindole-19'-xanthen]-3(2H)-oneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 831724: Experimental Crystal Structure Determination

2013

Related Article: B.Maggio, D.Raffa, M.V.Raimondi, F.Plescia, M.L.Trincavelli, C.Martini, F.Meneghetti, L.Basile, S.Guccione, G.Daidone|2012|Eur.J.Med.Chem.|54|709|doi:10.1016/j.ejmech.2012.06.028

Space GroupCrystallographyCrystal System4'-Hydroxy-255'-trimethyl-2'-phenyl-2'4'-dihydrospiro[isoindole-13'-pyrazol]-3(2H)-one ethanol solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1969794: Experimental Crystal Structure Determination

2019

Related Article: L. Tapmeyer, M. Beske, J. Plackmeyer|2019|IUCrData|4|x191629|doi:10.1107/S2414314619016298

Space GroupCrystallographyCrystal SystemCrystal Structure1133-tetraethyl-5-nitro-23-dihydro-1H-isoindoleCell ParametersExperimental 3D Coordinates
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CCDC 930310: Experimental Crystal Structure Determination

2013

Related Article: Aaron Breivogel, Michael Meister, Christoph Förster, Frédéric Laquai, Katja Heinze|2013|Chem.-Eur.J.|19|13745|doi:10.1002/chem.201302231

Space GroupCrystallographyCrystal SystemCrystal Structure2-(26-Dibromopyridin-4-yl)-1H-isoindole-13(2H)-dioneCell ParametersExperimental 3D Coordinates
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