Search results for "Isola"

MALDI-TOF characterization of macromonomers

1996

Methacryloyl endfunctionalized oligostyrene macromonomers were characterized by matrix assisted laser desorption ionization/time of flight (MALDI-TOF) spectroscopy and by isocratic and gradient high performance liquid chromatography (HPLC). The molar mass distribution derived by the different techniques coincide for the investigated oligomers. Mixing experiments revealed that the MALDI-TOF peak areas do not necessarily represent the mixing ratio of the components. Combination of gradient HPLC and MALDI-TOF has resolved the chemical composition of the coupling products formed by reaction of the living anion with oxygen.

Separation, isolation and stereochemical assignment of imazalil enantiomers and their quantitation in an in vitro toxicity test

2016

A simple method for the separation of the enantiomers of the fungicide imazalil was developed. Racemic imazalil was separated into its enantiomers with an enantiomeric purity of 99% using HPLC-UV with an enantioselective column (permethylated cyclodextrin) operated in reversed phase mode (water with 0.2% trimethylamine and 0.08% acetic acid and methanol). The absolute configuration of the separated enantiomers was assigned and unequivocally confirmed by optical rotation as well as by vibrational circular dichroism (VCD) and electronic circular dichroism (ECD) combined with ab-initio calculations. The same enantioselective column was also used to develop an HPLC-MS/MS method for the quantifi…

Tra città reale e progetto incompiuto. Sondare i limiti del restauro del moderno applicato alla scala urbana: il caso dell'isolato di Cerda alle spal…

2012

DENSIFY/SCALE DOWN. THE ARCHIPELAGO AS A RESPONSE

2020

L’incalzare delle disposizioni sanitarie connesse alla recente emergenza amplifica le criticità già espresse dall’evolversi dell’organismo urbano. L’alternanza tra opportune necessità di confinamento degli abitanti in gruppi circoscritti e le politiche di distanziamento sociale disposte ad arginare la diffusione del contagio da un virus tanto letale quanto straordinario propone, nel tempo corrente, una generale riflessione sulla composizione della forma urbis per l’affinamento di grammatiche insediative che, a fronte dell’estensione e della dispersione della città informale del Novecento delinea, di contro, nella concentrazione e nella discontinuità del costruito, nella riconoscibilità di u…

Positive selection in development and growth rate regulation genes involved in species divergence of the genus Radix

2015

AbstractBackgroundLife history traits like developmental time, age and size at maturity are directly related to fitness in all organisms and play a major role in adaptive evolution and speciation processes. Comparative genomic or transcriptomic approaches to identify positively selected genes involved in species divergence can help to generate hypotheses on the driving forces behind speciation. Here we use a bottom-up approach to investigate this hypothesis by comparative analysis of orthologous transcripts of four closely related EuropeanRadixspecies.ResultsSnails of the genusRadixoccupy species specific distribution ranges with distinct climatic niches, indicating a potential for natural …

Fréchet Spaces of Holomorphic Functions without Copies of l 1

1996

Let X be a Banach space. Let Hw*(X*) the Frechet space whose elements are the holomorphic functions defined on X* whose restrictions to each multiple mB(X*), m = 1,2, …, of the closed unit ball B(X*) of X* are continuous for the weak-star topology. A fundamental system of norms for this space is the supremum of the absolute value of each element of Hw*(X*) in mB(X*), m = 1,2,…. In this paper we construct the bidual of l1 when this space contains no copy of l1. We also show that if X is an Asplund space, then Hw*(X*) can be represented as the projective limit of a sequence of Banach spaces that are Asplund.

The index of stable critical points

2002

Abstract In this paper we show that in dimension greater or equal than 3 the index of a stable critical point can be any integer. More concretely, given any k∈ Z and n⩾3 we construct a C ∞ vector field on R n with a unique critical point which is stable (in positive and negative time) and has index equal to k. This result extends previous ones on the index of stable critical points.

Divergence and introgression among the virilis group of Drosophila

2022

AbstractSpeciation with gene flow is now widely regarded as common. However, the frequency of introgression between recently diverged species and the evolutionary consequences of gene flow are still poorly understood. The virilis group of Drosophila contains around a dozen species that are geographically widespread and show varying levels of pre-zygotic and post-zygotic isolation. Here, we utilize de novo genome assemblies and whole-genome sequencing data to resolve phylogenetic relationships and describe patterns of introgression and divergence across the group. We suggest that the virilis group consists of three, rather than the traditional two, subgroups. We found evidence of pervasive p…

Efficient estimation of tuned liquid column damper inerter (TLCDI) parameters for seismic control of base‐isolated structures

2022

This paper presents an enhanced base-isolation (BI) system equipped with a novel passive control device composed of a tuned liquid damper and an inerter (TLCDI). With the aim of reducing the seismic response of BI systems, this contribution focuses on the design of the TLCDI providing analytical solutions for the optimal TLCDI parameters, easily implementable in the design phase. The effectiveness of the proposed approach in terms of seismic response reduction and computational gain is validated by comparison with classical numerical optimization techniques. The control performance of two different base-isolated TLCDI-controlled structures is assessed by employing real-ground motion records…

Fault detection for continuous-time switched systems under asynchronous switching

2013

In this chapter, the problem of FD for continuous-time switched systems under asynchronous switching is investigated. The designed FD filter is assumed to be asynchronous with the original systems. Attention is focused on designing a FD filter such that the estimation error between the residual and the fault is minimized in the sense of H ∞ norm. By employing piecewise Lyapunov function and ADT techniques, a sufficient condition for the existence of such a filter is exploited in terms of certain LMIs. Finally, an example is provided to illustrate the effectiveness of the proposed approach.