Search results for "Isotropic"

Micro-Raman spectroscopic characterization of a CR-39 detector.

2013

Characterization by micro-Raman spectroscopy of polymeric materials used as nuclear track detectors reveals physico-chemical and morphological information on the material's molecular structure. In this work, the nuclear track detector poly(allyl diglycol carbonate), or Columbia Resin .39 (CR-39), was characterized according to the fluence of alpha particles produced by a 226Ra source and chemical etching time. Therefore, damage of the CR-39 chemical structure due to the alpha-particle interaction with the detector was analyzed at the molecular level. It was observed that the ionization and molecular excitation of the CR-39 after the irradiation process entail cleavage of chemical bonds and…

A three-dimensional boundary element model for the analysis of polycrystalline materials at the microscale

2012

A three-dimensional multi-domain anisotropic boundary element formulation is presented for the analysis of polycrystalline microstructures. The formulation is naturally expressed in terms of intergranular displacements and tractions that play an important role in polycrystalline micromechanics, micro-damage and micro-cracking. The artificial morphology is generated by Hardcore Voronoi tessellation, which embodies the main statistical features of polycrystalline microstructures. Each crystal is modeled as an anisotropic elastic region and the integrity of the aggregate is restored by enforcing interface continuity and equilibrium between contiguous grains. The developed technique has been ap…

Optical properties of the low-molecular amorphous azochromophores and their application in holography

2015

The films based on the low-molecular amorphous azochromophore 2-(3-(4-((4- (Ethyl(2-(trityloxy)ethyl)amino)phenyl)diazenyl)styryl)-5,5-dimethylcyclohex-2-enylidene) malononitrile (IWK-2M) were prepared. The optical properties of the material, such as transmittance and reflection spectra of the film, sensitivity to polarization holographic recording by two wavelengths (405 and 532 nm) were studied. The direct relief formation during the polarization holographic recording was explored, relief depth dependence on exposure and record beam intensity was investigated. The holographic matrix on this material base was produced without chemical etching process; the replication of holographic image w…

Automatic Extraction of Blood Vessels, Bifurcations and End Points in the Retinal Vascular Tree

2008

In this paper we present an effective algorithm for automated extraction of the vascular tree in retinal images, including bifurcations, crossovers and end-points detection. Correct identification of these features in the ocular fundus helps the diagnosis of important systematic diseases, such as diabetes and hypertension. The pre-processing consists in artefacts removal based on anisotropic diffusion filter. Then a matched filter is applied to enhance blood vessels. The filter uses a full adaptive kernel because each vessel has a proper orientation and thickness. The kernel of the filter needs to be rotated for all possible directions. As a consequence, a suitable kernel has been designed …

Sensing properties of assembled Bi2S3nanowire arrays

2015

Bismuth sulfide (Bi2S3) nanowires were grown in porous aluminium oxide template and a selective chemical etching was applied to transfer the nanowires to a solution. Well aligned nanowire arrays were assembled on pre-patterned silicon substrates employing dielectrophoresis. Electron beam lithography was used to connect aligned individual nanowires to the common macroelectrode. In order to evaluate the conductometric sensing performance of the Bi2S3 nanowires, current–voltage characteristics were measured at different relative humidity (RH) levels (5–80%) / argon medium. The response of the Bi2S3 nanowires depending of RH is found to be considerably different from those reported for other ty…

AN EFFICIENT SOLUTION OF HETEROGENEOUS ANISOTROPIC CONVECTION/DIFFUSION TRANSPORT PROBLEMS

2012

Semiflexible Polymers in the Bulk and Confined by Planar Walls

2016

Semiflexible polymers in solution under good solvent conditions can undergo an isotropic-nematic transition. This transition is reminiscent of the well-known entropically-driven transition of hard rods described by Onsager’s theory, but the flexibility of the macromolecules causes specific differences in behavior, such as anomalous long wavelength fluctuations in the ordered phase, which can be understood by the concept of the deflection length. A brief review of the recent progress in the understanding of these problems is given, summarizing results obtained by large-scale molecular dynamics simulations and density functional theory. These results include also the interaction of semiflexib…

A cohesive boundary element approach to material degradation in three-dimensional polycrystalline aggregates

2013

A new three-dimensional grain-level formulation for intergranular degradation and failure in polycrystalline materials is presented. The polycrystalline microstructure is represented as a Voronoi tessellation and the boundary element method is used to express the elastic problem for each crystal of the aggregate. The continuity of the aggregate is enforced through suitable conditions at the intergranular interfaces. The grain-boundary model takes into account the onset and evolution of damage by means of an irreversible linear cohesive law, able to address mixed-mode failure conditions. Upon interface failure, a non-linear frictional contact analysis is introduced for addressing the contact…

EFFICIENT SOLUTION OF HETEROGENEOUS ANISOTROPIC DIFFUSION PROBLEMS

2012

Molecular correlation functions for uniaxial ellipsoids in the isotropic state

2006

We perform event-driven molecular dynamics simulations of a system composed by uniaxial hard ellipsoids for different values of the aspect-ratio and packing fraction . We compare the molecular orientational-dependent structure factors previously calculated within the Percus-Yevick approximation with the numerical results. The agreement between theoretical and numerical results is rather satisfactory. We also show that, for specific orientational quantities, the molecular structure factors are sensitive to the particle shape and can be used to distinguish prolate from oblate ellipsoids. A first-order theoretical expansion around the spherical shape and a geometrical analysis of the configura…