Search results for "Kaolin"
showing 10 items of 90 documents
Characterization of the porous structure of Chilean volcanic soils by nitrogen adsorption and mercury porosimetry
2004
Pore volume, specific surface area (SSA), and total intragranular porosity (TIP) of Chilean soils derived from volcanic materials were studied. Soil samples involving the 0-15 and 15-30 cm depth of virgin and cultivated Collipulli (Ultisol) and Diguillin (Andisol) soils at two particle size fractions (<1 mm and <2 µm) were considered. From mercury porosimetry and N2 adsorption, mainly mesopores (pore diameter, dpore, about 10 nm) were determined for <1 mm Collipulli samples. Diguillin <1 mm soil shows macroporosity with dpore from 70 nm to 7000 nm. The clay fraction of Collipulli has macropores (dpore from 2000 nm to 40000 nm) and mesopores (dpore from 3 nm to 23 nm), while for Diguillin cl…
sgp120 and the contact system in hereditary angioedema: A diagnostic tool in HAE with normal C1 inhibitor
2020
Mutations in Factor XII, plasminogen gene, angiopoietin-1 gene and kininogen 1 gene have been found in some patients with hereditary angioedema with normal C1 inhibitor (HAE-nl-C1inh), but the underlying disease mechanisms remain unclear. Additionally, there are no accepted biomarkers for this disease. Because the contact system has been implicated in hereditary angioedema with C1 inhibitor deficiency (HAE-C1inh), we studied the fragmentation patterns of serum glycoprotein 120 (sgp120), a protein that is highly susceptible to cleavage by kallikrein, in 31 HAE-C1inh and 13 HAE-nl-C1inh patient plasma samples. Compared to normal controls, the majority of plasma samples from patients with HAE-…
Retention of Vanadium(V), Molybdenum(VI) and Tungsten(VI) by Kaolin
1993
Abstract The ability of kaolin (approximately H2Al2Si2O8 · H2O), a well known clay mineral constituent, to retain V(V) andMo(VI) species from 10−5 and 10−4 M solutions, and W(VI) species from 10−4 M solutions was investigated in the pH range 2–7.5 using a solid/liquid ratio 1:100 (w:v). The equilibration time in the adsorption studies was 72 h, and the shaking time in the desorption studies was 17 h. 0.02 M KCl was used as ionic medium and desorbing liquid. V(V), Mo(VI) and W(VI) were all retained by kaolin to some extent, and the amounts of the elements which could be washed away from kaolin with 0.02 M KCl were very small. The pH dependence of the adsorption was considerable: when added a…
Selective adsorption of oppositely charged PNIPAAM on halloysite surfaces: a route to thermo-responsive nanocarriers.
2018
Halloysite nanotubes were functionalized with stimuli-responsive macromolecules to generate smart nanohybrids. Poly(N-isopropylacrylamide)-co-methacrylic acid (PNIPAAM-co-MA) was selectively adsorbed into halloysite lumen by exploiting electrostatic interactions. Amine-terminated PNIPAAM polymer was also investigated that selectively interacts with the outer surface of the nanotubes. The adsorption site has a profound effect on the thermodynamic behavior and therefore temperature responsive features of the hybrid material. The drug release kinetics was investigated by using diclofenac as a non-steroidal anti-inflammatory drug model. The release kinetics depends on the nanoarchitecture of th…
Distribution of clay minerals in Early Jurassic Peritethyan seas: palaeoclimatic significance inferred from multiproxy comparisons.
2009
13 pages; International audience; A set of published, unpublished, and new clay mineral data from 60 European and Mediterranean localities allows us to test the reliability of clay minerals as palaeoclimatic proxies for the Pliensbachian–Toarcian period (Early Jurassic) by reconstructing spatial and temporal variations of detrital fluxes at the ammonite biochronozone resolution. In order to discuss their palaeoclimatic meaning, a compilation of low-latitude belemnite δ18O, δ13C, Mg/Ca, and 87Sr/86Sr values is presented for the first time for the whole Pliensbachian– Toarcian period. Once diagenetic and authigenic biases have been identified and ruled out, kaolinite content variation is cons…
Experimental alteration of granitic rocks: Implications for the evolution of geothermal brines in the Upper Rhine Graben, Germany
2020
Abstract Geothermal energy exploitation in the Upper Rhine Graben (URG) chiefly has targeted faults and fractures within or connected with the crystalline basement, where hot fluids of c. 200 °C circulate at depths of c. 5 km. Formation fluids of the crystalline basement are highly saline, NaCl-dominated brines, whereas shallow crystalline basement water ( The trace element concentrations of the leachates are hereby related to the composition and stability of minerals in the rocks and can be directly linked to the proposed and observed dissolution processes at the different temperatures. In experiments with pure water at 70 °C, representing the recharge or infiltration conditions, water-roc…
Halloysite Nanotubes Loaded with Calcium Hydroxide: Alkaline Fillers for the Deacidification of Waterlogged Archeological Woods
2018
A novel green protocol for the deacidifying consolidation of waterlogged archaeological woods through aqueous dispersions of polyethylene glycol (PEG) 1500 and halloysite nanotubes containing calcium hydroxide has been designed. First, we prepared functionalized halloysite nanotubes filled with Ca(OH)2 in their lumen. The controlled and sustained release of Ca(OH)2 from the halloysite lumen extended its neutralization action over time, allowing the development of a long-term deacidification of the wood samples. A preliminary thermomechanical characterization of clay/polymer nanocomposites allows us to determine the experimental conditions to maximize the consolidation efficiency of the wood…
Ground-based off-line aerosol measurements at Praia, Cape Verde, during the Saharan Mineral Dust Experiment: microphysical properties and mineralogy
2011
A large field experiment of the Saharan Mineral Dust Experiment (SAMUM) was performed in Praia, Cape Verde, in January and February 2008. This work reports on the aerosol mass concentrations, size distributions and mineralogical composition of the aerosol arriving at Praia. Three dust periods were recorded during the measurements, divided by transitional periods and embedded in maritime-influenced situations. The total suspended particle mass/PM 10 /PM 2.5 were 250/180/74 μg/m 3 on average for the first dust period (17–21 January) and 250/230/83 μg/m 3 for the second (24–26 January). The third period (28 January to 2 February) was the most intensive with 410/340/130 μg/m 3 . Four modes were…
Comparative study on immersion freezing utilizing single-droplet levitation methods
2021
Immersion freezing experiments were performed utilizing two distinct single-droplet levitation methods. In the Mainz vertical wind tunnel, supercooled droplets of 700 µm diameter were freely floated in a vertical airstream at constant temperatures ranging from −5 to −30 ∘C, where heterogeneous freezing takes place. These investigations under isothermal conditions allow the application of the stochastic approach to analyze and interpret the results in terms of the freezing or nucleation rate. In the Mainz acoustic levitator, 2 mm diameter drops were levitated while their temperature was continuously cooling from +20 to −28 ∘C by adapting to the ambient temperature. Therefore, in this case th…
Ice nucleation properties of the most abundant mineral dust phases
2008
[1] The ice nucleation properties of the nine most abundant minerals occurring in desert aerosols (quartz, albite, microcline, kaolinite, montmorillonite, illite, calcite, gypsum, and hematite) were investigated by environmental scanning electron microscopy (ESEM). In this instrument, the pure minerals are exposed to water vapor at variable pressures and temperatures. The crystallization of ice on the mineral particles is observed by secondary electron imaging, and the supersaturation for an activated particle fraction of 1–3% is determined as function of temperature. In all experiments, condensation of water prior to ice formation was not observed within detectable limits, even at water su…