Search results for "Krypton"
showing 10 items of 54 documents
Investigation of surface properties of lunar regolith: Part I
2007
This paper describes an initial investigation of the surface properties of three lunar soil samples from the Apollo 11, 12 and 16 missions, respectively. We report on density measurements using a helium pycnometer, adsorption isotherms of krypton applied for the determination of specific surface area of the samples and gravimetric measurement of the isotherms of water, heptane and octane. Electron-microscopic photographs are described and discussed.
Deuterium monolayers physisorbed on krypton-plated graphite: A two-dimensional Ising system
1997
Abstract Neutron-diffraction measurements were used for the first time to investigate the influence of the modification of the graphite substrate potential and of the susbrate symmetry caused by a preadsorbed layer of krypton (Kr). It will be shown that D2 on Kr/graphite presents a new 2D Ising system. The order-disorder transition of this system has been studied.
Theoretical characterization of the photochemical reaction CO2 + O(3P) → CO + O2 related to experiments in solid krypton
2020
Abstract Formation and decomposition of the complex of carbon dioxide and atomic oxygen are characterized by quantum chemistry methods aiming to rationalize experimental studies in solid krypton. The observed FTIR spectra reflected the temporal evolution of the system after irradiation showing the bands of reactants, intermediates and products. Advanced quantum chemistry calculations show that the T-shape complex CO2…O(3P) can be formed in the matrix. Its excitation by the 193 nm light results in the charge-transfer state CO2+…O−, which evolves to the reaction intermediate CO3. The latter species decomposes to CO + O2 following pathways on the excited state energy surfaces.
Investigation of gaseous discharge ion sources for isotope separation on-line
1976
Abstract Gaseous discharge ion sources with circular end extraction have been investigated with the aim of meeting the special requirements of on-line isotope separation. The studies represent an attempt to increase lifetime, temperature and ionization efficiency of the ion source under stable discharge conditions and to reduce the ion current density of usually 1–100 mA/cm2 of low intensity separator sources. The detailed investigation of a modified Nielsen Ion Source is described. The source yields in oscillating electron are operation reproducible ionization efficiencies of 32% for krypton and 45% for xenon. It was found that minor variations of geometry and potentials in a Nielsen-type …
Regional blood flow in deep structures of the brain measured in acute cat experiments by means of a new beta-sensitive semiconductor needle detector.
1967
Regional cerebral blood flow was measured by means of isotope clearance with a new type of solid state beta-sensitive needle detector (diameter 0.9 mm) introduced into the brain tissue in acute cat experiments. The flow values obtained within the cortex were compared with values recorded above the same cortical region with the same needle detector, or with a small GM-tube. The insertion of the needle detector into the brain tissue gave rise to injury (checked histologically) which deformed the clearance curves in a manner suggesting that the normal circulation had been destroyed within the tissue from which the measurements were made.
<title>Hardening and long-range stress effects in LiF caused by high-fluence irradiation with fast Bi, Ni, Kr, and S ions</title>
2005
The limits of the hardening, and the effects of ion-induced internal and long-range stresses in LiF crystals irradiated with Bi, Ni, Kr, and S ions, having a specific energy of the order of 10 MeV/u and the fluence up to 1013cm-2, are studied. A considerable hardness increase, bending of the crystals, formation of dislocations in distant nonirradiated parts of the crystals, and initiation of fracturing under the high-fluence irradiation are observed. It is shown that the irradiation with heavy ions (Bi) gives rise to dislocations and work hardening mainly in the region adjacent to the irradiated one. In the case of lighter ions (Ni and S), the work hardening takes place also inside the irra…
Vibrational characterization of the 1:1 iodine-benzene complex isolated in solid krypton.
2008
The structure and properties of a 1:1 iodine-benzene complex isolated in an inert krypton matrix at low temperature have been studied with infrared and resonance Raman spectroscopy and with MP2 calculations. The structure of the ground-state complex is found to be unsymmetric, and the I-I vibrational frequency is found to be red-shifted by 3.94 cm(-1) upon complexation. The experimental data agree well with computational results, leading to the conclusion that the I2-Bz complex structure is not axial but of above-bond type, identically with other halogen-benzene complexes.
On the difficulty of assessing the specific surface area of magnesium stearate
2001
Abstract The water content of as-received commercial magnesium stearate batches from animal and vegetable sources have been modified by ageing in humid air at room temperature or by vacuum treatment. The complete adsorption–desorption isotherms of nitrogen and krypton vapours by samples of these as received and modified materials have been measured at liquid nitrogen temperature after standardised vacuum degassing. They are greatly affected by the initial water content of the material. In particular: (a) the BET surface area values computed from the adsorption branch vary widely and is increasing with increasing water content; (b) anomalous hysteresis of varying amplitude is observed in all…
A simple expression for electronic stopping force of heavy ions in solids
2012
Abstract A simple expression for the electronic stopping force of heavy ions in solids is proposed based on an adaption of the Bohr’s classical stopping theory. A three-parameter model is constructed by using experimental data for helium, oxygen, argon, krypton and xenon ions in carbon, aluminum, nickel and gold targets at energies from 600 eV/u to 985 MeV/u. Total average agreements between the model and used experimental data are (−4.5 ± 47)% and (−1.6 ± 7.4)% at energies below and above the Bragg peak, respectively. The good overall agreement makes this model a good candidate for future development in stopping force prediction tools.
Onset of deformation in neutron-rich krypton isotopes
1988
Beta-decay properties of neutron-rich35Br isotopes confirm the predicted smooth onset of quadrupole deformation for Z<37 already below N=60. The observed increase of the energy of the first 2+ state in the N=56 nucleus92Kr may indicate octupole softness.