Search results for "LEAN"
showing 10 items of 3611 documents
Crystalline-Size Dependence of Dual Emission Peak on Hybrid Organic Lead-Iodide Perovskite Films at Low Temperatures
2018
In this work, we have investigated the crystalline-size dependence of optical absorption and photoluminescence emission of CH3NH3PbI3 films, which is necessary to identify the potential practical applications of the gadgets based on perovskite films. This study was carried out at low temperatures to minimize the extra complexity induced by thermal effects. The purpose was to clarify the origin of the dual emission peak previously reported in the literature. We found that the grain size is responsible for the appearance or disappearance of this dual emission on CH3NH3PbI3 at low temperatures, whereas we have inferred that the thickness of the perovskite layer is a much more important factor …
N2-, O2- and air-broadened half-widths and line shifts for transitions in the nu3 band of methane in the 2726- to 3200-cm-1 spectral region
2008
International audience; Complex Robert-Bonamy calculations of the pressure-broadened half-width and the pressure-induced line shift are made for some 4000 transitions in the [nu]3 band of methane with N2, O2, and air as the perturbing gases. This work focuses on A and F symmetry transitions in the spectral range 2726 to 3200 cm-1. More work is needed on the intermolecular potential before calculations can be made for the E-symmetry transitions. The calculations are made at 225 and 296 K in order to determine the temperature dependence of the half-width. The calculations are compared with measurements. These data are to support remote sensing of the Earth and Titan atmospheres.
Energy harvesting by waste acid/base neutralization via bipolar membrane reverse electrodialysis
2020
Bipolar Membrane Reverse Electrodialysis (BMRED) can be used to produce electricity exploiting acid-base neutralization, thus representing a valuable route in reusing waste streams. The present work investigates the performance of a lab-scale BMRED module under several operating conditions. By feeding the stack with 1 M HCl and NaOH streams, a maximum power density of ~17 W m−2 was obtained at 100 A m−2 with a 10-triplet stack with a flow velocity of 1 cm s−1, while an energy density of ~10 kWh m−3 acid could be extracted by a complete neutralization. Parasitic currents along feed and drain manifolds significantly affected the performance of the stack when equipped with a higher number of t…
Effect of different aqueous solutions of pure salts and salt mixtures in reverse electrodialysis systems for closed-loop applications
2018
Abstract Reverse Electrodialysis (RED) in a closed-loop arrangement is a viable way to convert low-grade heat into electric power. The present work experimentally investigates the use of pure salt- and equimolar two salts-water solutions as feeds in a lab-scale RED unit. RED performances were analysed in terms of Open Circuit Voltage (OCV), stack resistance and corrected power density. The pure salts and the mixtures employed were chosen via a computational analysis. Effect of feed solution velocity and concentration was investigated. Results concerning the pure salt-water experiments show that NH4Cl is the most performing salt in the concentration range probed, while higher power density v…
Membrane distillation heat transfer enhancement by CFD analysis of internal module geometry
2011
Module geometry optimisation can be a crucial matter in all separation processes using selective or hydrophobic membranes, e.g. reverse osmosis (RO) and membrane distillation (MD). In fact the choice of suitable channel shape and size can dramatically affect the performance of the process. With reference to the membrane distillation process, temperature polarization phenomena and pres¬sure drops along the channels largely affect the process efficiency (i.e. the efficient use of temperature driving force for the passage of vapour through the membrane) as well as pressure distribution, module mechanical resistance and pumping costs. Several works have been presented so far in literature on th…
Electrical conductivity as a state indicator for the start-up period of anaerobic fixed-bed reactors.
2016
The aim of this work was to analyse the applicability of electrical conductivity sensors for on-line monitoring the start-up period of an anaerobic fixed-bed reactor. The evolution of bicarbonate concentration and methane production rate was analysed. Strong linear relationships between electrical conductivity and both bicarbonate concentration and methane production rate were observed. On-line estimations of the studied parameters were carried out in a new start-up period by applying simple linear regression models, which resulted in a good concordance between both observed and predicted values. Electrical conductivity sensors were therefore identified as an interesting method for monitori…
Thermal-hydraulic behaviour of the DEMO divertor plasma facing components cooling circuit
2017
Abstract Within the framework of the Work Package DIV 1 – “Divertor Cassette Design and Integration” of the EUROfusion action, a research campaign has been jointly carried out by ENEA and University of Palermo to investigate the thermal-hydraulic performances of the DEMO divertor cassette cooling system. A comparative evaluation study has been performed considering three different options for the cooling circuit layout of the divertor Plasma Facing Components (PFCs). The potential improvement in the thermal-hydraulic performance of the cooling system, to be achieved by modifying cooling circuit layout, has been also assessed and discussed in terms of optimization strategy. The research acti…
The design of the DONES lithium target system
2019
Abstract In the framework of the EU fusion roadmap implementing activities, an accelerator-based Li(d,xn) neutron source called DONES (Demo-Oriented early NEutron Source) is being designed within the EUROfusion Work Package Early Neutron Source as an essential irradiation facility for testing candidate materials for DEMO reactor and future fusion power plants. DONES will employ a high speed liquid lithium jet struck by a 125 mA, 40 MeV deuteron beam to generate the intense neutron flux used to irradiate the material samples up to the desired level of displacement damage (˜10 dpa/fpy for iron in 0.3 l) and He production rates (˜10-13 appm He/dpa). In order to rapidly achieve a sound and stab…
Parametric study of the influence of First Wall cooling water on the Water Cooled Lithium Lead Breeding Blanket nuclear response
2019
Abstract In the framework of EUROfusion Work Package International Cooperation R&D activities, a close collaboration has been started among University of Palermo, ENEA Brasimone and ENEA Frascati for the development of the Water Cooled Lithium Lead (WCLL) Breeding Blanket (BB) concept. In this context, a research campaign has been carried out at the University of Palermo in order to investigate the influence of First Wall (FW) cooling water configuration on the nuclear response of the WCLL BB under irradiation in EU-DEMO, in order to gain useful indications for the WCLL BB pre-conceptual designs. To this end, three-dimensional nuclear analyses have been performed by MCNP5 v. 1.6 Monte Carlo…
The Athena X-ray Integral Field Unit: a consolidated design for the system requirement review of the preliminary definition phase
2023
The Athena X-ray Integral Unit (X-IFU) is the high resolution X-ray spectrometer, studied since 2015 for flying in the mid-30s on the Athena space X-ray Observatory, a versatile observatory designed to address the Hot and Energetic Universe science theme, selected in November 2013 by the Survey Science Committee. Based on a large format array of Transition Edge Sensors (TES), it aims to provide spatially resolved X-ray spectroscopy, with a spectral resolution of 2.5 eV (up to 7 keV) over an hexagonal field of view of 5 arc minutes (equivalent diameter). The X-IFU entered its System Requirement Review (SRR) in June 2022, at about the same time when ESA called for an overall X-IFU redesign (i…