Search results for "LEVEL"
showing 10 items of 3465 documents
Unravelling the kinetics and molecular mechanism of the degenerate Cope rearrangement of bullvalene
2020
The kinetics and molecular mechanism of the gas phase degenerate Cope rearrangement (DCR) of bullvalene have been investigated by applying quantum mechanical calculations. Highly accurate energies (CBS-QB3 and CBS-APNO) and RRKM calculations were employed to study the kinetics and ‘fall-off’ behavior. It was found that the DCR of bullvalene (C3v) occurs through a bishomoaromatic transition structure (C2v) with an energy barrier of ∼49 kJ mol−1. The calculated activation energy and enthalpy were in good agreement with the available values in the literature, but lower than those of common Cope rearrangement; this result is related to the high stabilization energy due to the interaction of the…
Unveiling the Occurrence of Co(III) in NiCo Layered Electroactive Hydroxides: The Role of Distorted Environments
2020
Co- and Ni-based layered hydroxides constitute a unique class of two-dimensional inorganic materials with exceptional chemical diversity, physicochemical properties and outstanding performance as supercapacitors and overall water splitting catalysts. Recently, the occurrence of Co(III) in these phases has been proposed as a key factor that enhance their electrochemical performance. However, the origin of this centers and control over its contents remains as an open question. We employed the Epoxide Route to synthesize a whole set of α-NiCo layered hydroxides. The PXRD and XAS characterization alert about the occurrence of Co(III) as a consequence of the increment in the Ni content. DFT+U si…
Volcanic structures investigation through SAR and seismic interferometric methods: The 2011-2013 Campi Flegrei unrest episode
2019
Observations from satellites provide high-resolution images of ground deformation allowing to infer deformation sources by developing advanced modeling of magma ascent and intrusion processes. Nevertheless, such models can be strongly biased without a precise model of the internal structure of the volcano. In this study, we jointly exploited two interferometric techniques to interpret the 2011–2013 unrest at Campi Flegrei caldera (CFc). The first is the Interferometric Synthetic Aperture Radar (InSAR) technique, which provides highly-resolved spatial and temporal images of ground deformation. The second is the Ambient Noise Tomography (ANT), which images subsurface structures, providing the…
Environmental and biological factors are joint drivers of mercury biomagnification in subarctic lake food webs along a climate and productivity gradi…
2021
Subarctic lakes are getting warmer and more productive due to the joint effects of climate change and intensive land-use practices (e.g. forest clear-cutting and peatland ditching), processes that potentially increase leaching of peat- and soil-stored mercury into lake ecosystems. We sampled biotic communities from primary producers (algae) to top consumers (piscivorous fish), in 19 subarctic lakes situated on a latitudinal (69.0-66.5 degrees N), climatic (+3.2 degrees C temperature and +30% precipitation from north to south) and catchment land-use (pristine to intensive forestry areas) gradient. We first tested how the joint effects of climate and productivity influence mercury biomagnific…
A record of seafloor methane seepage across the last 150 million years
2020
<p>Methane seepage at the seafloor is a source of carbon in the marine environment and has long been recognized as an important window into the deep geo-, hydro-, and bio-spheres. However, the processes and temporal patterns of natural methane emission over multi-million-year time scales are still poorly understood. The microbially-mediated methane oxidation leads to the precipitation of authigenic carbonate minerals within subseafloor sediments, thus providing a potentially extensive record of past methane emission. In this study, we used data on methane-derived authigenic carbonates to build a proxy time series of seafloor methane emission over the last 150 My. We quantitat…
Toward a Comprehensive Dam Monitoring: On-Site and Remote-Retrieved Forcing Factors and Resulting Displacements (GNSS and PS–InSAR)
2021
Many factors can influence the displacements of a dam, including water level variability and environmental temperatures, in addition to the dam composition. In this work, optical-based classification, thermal diachronic analysis, and a quasi-PS (Persistent Scatter) Interferometric SAR technique have been applied to determine both forcing factors and resulting displacements of the crest of the Castello dam (South Italy) over a one-year time period. The dataset includes Sentinel-1A images acquired in Interferometric Wide swath mode using the Terrain Observation with Progressive Scans SAR (TOPSAR); Landsat 8 Thermal Infrared Sensor (TIRS) thermal images, and Global Navigation Satellite System …
Towards a long-term dataset of ELBARA-II measurements assisting SMOS level-3 land product and algorithm validation at the Valencia Anchor Station
2015
[EN] The Soil Moisture and Ocean Salinity (SMOS) mission was launched on 2nd November 2009 with the objective of providing global estimations of soil moisture and sea salinity. The main activity of the Valencia Anchor Station (VAS) is currently to assist in a long-term validation of SMOS land products. This study focus on a level 3 SMOS data validation with in situ measurements carried out in the period 2010-2012 over the VAS. ELBARA-II radiometer is placed in the VAS area, observing a vineyard field considered as representative of a major proportion of an area of 50×50 km, enough to cover a SMOS footprint. Brightness temperatures (TB) acquired by ELBARA-II have been compared to those obser…
Numerical evidence for thermohaline circulation reversals during the Maastrichtian
2005
[1] The sensitivity of the Maastrichtian thermohaline circulation to the opening/closing of marine communications between the Arctic and North Pacific oceans is investigated through a set of numerical experiments using the model CLIMBER-2 (Earth Model of Intermediate Complexity). We show here that the opening or closing of an Arctic-Pacific marine gateway induces transitions between different equilibrium states of the thermohaline circulation. Sensitivity tests of the inferred modes of thermohaline circulation to atmospheric CO2 level changes have also been explored. An abrupt switch in deep convection from high northern to high southern latitudes, a change consistent with isotopic evidence…
Historical analysis of rainfall-triggered rockfalls: the case study of the disaster of the ancient hydrothermal Sclafani Spa (Madonie Mts, northern-c…
2017
Abstract. In 1851, the region of Sicily experienced many rainstorm-induced landslides. On 13 March 1851, a rainstorm brought about a severe rockfall disaster near the small town of Sclafani (Madonie Mountains, northern-central Sicily, Italy). Rocks detached from the carbonate crest of Mt Sclafani (813 m above sea level) and fell downslope, causing the collapse of the ancient hydrothermal spa (about 430 m above sea level) and burying it. Fortunately, there were no injuries or victims. Given its geological, geomorphological and tectonic features, the calcareous–dolomitic and carbonate–siliciclastic relief of Mt Sclafani is extremely prone to landsliding. This study combines the findings of de…
The influence of the wind direction and plants on the variability of topsoil magnetic susceptibility in industrial and urban areas of southern Poland
2016
Volume magnetic susceptibility (κ) was measured on the soil surface and in the vertical topsoil profile within a 300 km2 area located in an urban-industrial conurbation. The results were compared to plant species compositions in the forest storeys, elevation above sea level, and terrain geomorphology. The content and mineral composition of the magnetic fraction were determined in the soil horizons. It was found that the extent of the area with enhanced topsoil magnetic susceptibility was similar to the dominant wind direction (south–west). Enhanced κ values were observed for the soil at the forest margin on the leeward side of the emitters as well as at sites located on exposed local elevat…