Search results for "LIMIT"
showing 10 items of 2826 documents
Design and development of heterologous competitive immunoassays for the determination of boscalid residues
2014
Boscalid is a modern agrochemical belonging to the so-called chemical class of succinate dehydrogenase inhibitor fungicides. With the aim of developing rapid analytical screening methods for this relevant compound, we herein report the synthesis of new boscalid mimics and the study of their suitability for the production of polyclonal antibodies. Aliphatic spacer arms equivalent in length and composition were tethered at two different aromatic rings of the target molecular structure. These haptens, besides being used for immunization, were employed in the development of heterologous competitive enzyme-linked immunosorbent assays (cELISAs) in order to improve assay detectability. Direct and …
Detection of Hypoxanthine from Inosine and Unusual Hydrolysis of Immunosuppressive Drug Azathioprine through the Formation of a Diruthenium(III) Syst…
2021
Hypoxanthine (hpx) is an important molecule for both biochemistry research and biomedical applications. It is involved in several biological processes associated to energy and purine metabolism and has been proposed as a biomarker for a variety of disease states. Consequently, the discovery and development of systems suitable for the detection of hypoxanthine is pretty appealing in this research field. Thus, we have obtained a stable diruthenium (III) compound in its dehydrated and hydrated forms with formula [{Ru(µ
Accurate Treatment of Large Supramolecular Complexes by Double-Hybrid Density Functionals Coupled with Nonlocal van der Waals Corrections.
2015
In this work, we present a thorough assessment of the performance of some representative double-hybrid density functionals (revPBE0-DH-NL and B2PLYP-NL) as well as their parent hybrid and GGA counterparts, in combination with the most modern version of the nonlocal (NL) van der Waals correction to describe very large weakly interacting molecular systems dominated by noncovalent interactions. Prior to the assessment, an accurate and homogeneous set of reference interaction energies was computed for the supramolecular complexes constituting the L7 and S12L data sets by using the novel, precise, and efficient DLPNO-CCSD(T) method at the complete basis set limit (CBS). The correction of the bas…
Emissions and spatial variability of N2O, N2 and nitrous oxide mole fraction at the field scale, revealed with 15N isotopic techniques.
2006
Abstract The accurate measurement of nitrous oxide (N 2 O) and dinitrogen (N 2 ) during the denitrification process in soils is a challenge which will help to estimate the contribution of soil N 2 O emissions to global warming. Oxygen concentration, nitrate concentration and carbon availability are generally the main factors that control soil denitrification rate and the amount of N 2 O or N 2 emitted. The aim of this paper is to present a database of the N 2 O mole fraction measured at the field scale, and to test hypotheses concerning its regulation. A 15 N-nitrate tracer solution was added to 36 undisturbed soil cores on a 20 m×20 m cultivated field plot. Fluxes of CO 2 , N 2 O and N 2 f…
Partial molar enthalpies and reaction enthalpies from equilibrium molecular dynamics simulation
2014
We present a new molecular simulation technique for determining partial molar enthalpies in mixtures of gases and liquids from single simulations, without relying on particle insertions, deletions, or identity changes. The method can also be applied to systems with chemical reactions. We demonstrate our method for binary mixtures of Weeks-Chandler-Anderson particles by comparing with conventional simulation techniques, as well as for a simple model that mimics a chemical reaction. The method considers small subsystems inside a large reservoir (i.e., the simulation box), and uses the construction of Hill to compute properties in the thermodynamic limit from small-scale fluctuations. Results …
Principal part of multi-parameter displacement functions
2012
This paper deals with a perturbation problem from a period annulus, for an analytic Hamiltonian system [J.-P. Françoise, Ergodic Theory Dynam. Systems 16 (1996), no. 1, 87–96 ; L. Gavrilov, Ann. Fac. Sci. Toulouse Math. (6) 14(2005), no. 4, 663–682. The authors consider the planar polynomial multi-parameter deformations and determine the coefficients in the expansion of the displacement function generated on a transversal section to the period annulus. Their first result gives a generalization to the Françoise algorithm for a one-parameter family, following [J.-P. Françoise and M. Pelletier, J. Dyn. Control Syst. 12 (2006), no. 3, 357–369. The second result expresses the principal terms in …
"Table 3" of "Search for magnetic monopoles and stable high-electric-charge objects in 13 TeV proton-proton collisions with the ATLAS detector"
2019
Observed 95% confidence-level upper limits on the cross section for Drell-Yan spin-1/2 monopole production as a function of mass for magnetic charges $|g|=1g_D$ and $|g|=2g_D$.
"Table 1" of "Search for magnetic monopoles and stable high-electric-charge objects in 13 TeV proton-proton collisions with the ATLAS detector"
2019
Observed 95% confidence-level upper limits on the cross section for Drell-Yan spin-0 monopole production as a function of mass for magnetic charges $|g|=1g_D$ and $|g|=2g_D$.
Aidòs. Percorsi di etica del limite
2022
Come già Platone intuì con il mito di Protagora, la tecnica è figlia della finitezza. C’è tecnica, infatti, lì dove c’è bisogno di migliorare; ma lo stesso bisogno di migliorare è segno che non c’è ancora compimento. Nel crescente darsi da fare della tecnologia per strappare alla vita la sua imperfezione si nasconde così uno strano paradosso: lo scopo della tecnica non può che essere il proprio togliersi. Solo lì dove non ci sarà più tecnica, infatti, potrà esserci quella pienezza a cui l’uomo, tramite la tecnica, aspira. Ne consegue che il progresso qualitativo e quantitativo della tecnologia, lungi dall’avvicinarci gradualmente a un ultimo limite che sarà finalmente superato, è cifra di u…
Plantas : Un caso especial de evolución y morfogénesis
1995
Este trabajo versa sobre teoría evolutiva (especialmente mecanismos evolutivos y evolución mortologica) y paleobotánica. Las plantas fósiles conservan muy bien su estructura histológica. y por ello poseen un alto contenido de información, la evolución dc ¡as 1>1 a ntas tiene aspectos específicos: no l>ay secuestro (le la línea gerrn i nial (WLISMANN) y la poliploidía es un mecanismo de aislamiento reproductivo frecuente Los conceptos de la Morfodinámica de SEI LACHER son útiles para eí>tender las ¡iniilaciones en la evolución (le las plantas La heterocron ja es otro canipo a tener en cuenta. -Miquel.De.Renzi@uv.es