Search results for "LINESHAPE"
showing 4 items of 4 documents
Collisional effects on spectral line shape from the Doppler to the collisional regime: A rigorous test of a unified model
2000
International audience; The paper presents high resolution Raman investigations of the Q(1) line of H-2 in Ar mixture from low density (Doppler regime) to high density (collisional regime) analyzed with a unique line shape profile. Measurements are performed by stimulated Raman gain spectroscopy between 300 and 1000 K in a wide density range (from 0.2 to 11 amagat). All the observed spectral features are accurately described by a unified model recently proposed by two of the authors. This model accounts for a velocity-memory process, not restricted to the usual hard and soft limits. It also includes correlation between velocity- and phase-changing collisions. An exhaustive analysis of vario…
Symmetry-adapted tensorial formalism to model rovibrational and rovibronic spectra of molecules pertaining to various point groups
2004
International audience; We present a short review on the tensorial formalism developed by the Dijon group to solve molecular spectroscopy problems. This approach, originally devoted to the rovibrational spectroscopy of highly symmetrical species (spherical tops) has been recently extended in several directions: quasi-spherical tops, some symmetric and asymmetric tops, and rovibronic spectroscopy of spherical tops in a degenerate electronic state. Despite its apparent complexity (heavy notations, quite complex mathematical tools), these group theoretical tensorial methods have a great advantage of flexibility: a systematic expansion of effective terms for any rovib- rational/rovibronic probl…
Lambda(1405) poles obtained from pi(0)Sigma(0) photoproduction data
2013
We present a strategy to extract the position of the two Lambda(1405) poles from experimental photoproduction data measured recently at different energies in the gamma p -> K+pi(0)Sigma(0) reaction at Jefferson Laboratory. By means of a chiral dynamics motivated potential with free parameters, we solve the Bethe-Salpeter equation in the coupled channels (K) over barN and pi Sigma in isospin I = 0 and parametrize the amplitude for the photonuclear reaction in terms of a linear combination of the pi Sigma -> pi Sigma and (K) over barN -> pi Sigma scattering amplitudes in I = 0, with a different linear combination for each energy. Good fits to the data are obtained with some sets of parameters…
Speed-dependent line profile: A test of a unified model from the Doppler to the collisional regime for molecule-molecule collisions
2000
International audience; A speed-dependent line profile combining soft and hard fully correlated Dicke-narrowing collisions was recently successfully tested on Ar-broadened H-2 spectra in a wide density and temperature range. A further test for mixtures of H-2 in nitrogen molecules (instead of Ar atoms) is presented. This test is also based on high resolution Raman investigation of the isotropic Q(1) line of H-2 from low to high density at various temperatures. The same consistency of the speed-dependent line profile as for H-2-Ar is obtained for H-2-N-2 through a remarkable agreement with all the data by using a unique set of four parameters (the collisional width and shift, the kinetic fre…