Search results for "Length"
showing 10 items of 2188 documents
Cooperativity Scaling and Free Volume in Plasticized Polylactide
2019
The authors would like to thank the region Haute Normandie for their financial support and the acquisition of the Broadband Dielectric Spectrometer. R.G. acknowledges U.S. National Science Foundation (Grant no. DMR-1725188) for the acquisition of PAL spectrometer. The experimental evidence of the increase of activation energy associated with the super Arrhenius behavior governing amorphous polylactide by free volume variations has been obtained through a combination of calorimetric, dielectric, and positron annihilation lifetime measurements. The amount of free volume in polylactide was controlled by the amount of acetyltributylcitrate plasticizer in the composition. Plasticization is shown…
DFT calculations of structures, 13C NMR chemical shifts and Raman RBM mode of simple models of ultra small diameter (4,0) zigzag hydroxylated single …
2012
Abstract Selected acenes, cyclic acenes and model zigzag (4,0) single wall carbon nanotubes (SWCNTs) with one hydroxylic group at the open end were fully optimized at the B3LYP/6-31G* level of theory. The impact of molecule size on the B3LYP/pcS-2 calculated 13 C NMR chemical shifts was studied to characterize pristine and tip-monofunctionalized ultra narrow SWCNTs. The harmonic frequency of Raman radial breathing mode (RBM) was determined for monohydroxylated cyclic acenes and correlated with their diameter. A regular convergence of selected CC bond lengths, RBM frequency and carbon chemical shifts upon increasing the size of the systems was observed and fitted toward very large systems wi…
Improvement of flame spraying PEEK coating characteristics using lasers
2011
Flame spraying is frequently used for PEEK coatings elaboration on metallic surfaces. However, this process has a certain number of limitations particularly considering the quality of the coatings like high porosity or low interfacial adherence. For that reason a thermal post-processing is often necessary. From all of the processes which can be used (flame, oven, etc.), laser can be an interesting technology. Then, the aim of this study is to analyse the dependence of the morphological structure (compactness) and the adherence of the flame sprayed PEEK coatings to the stainless steel (304L) and aluminium alloy (AA2017) substrates on laser parameters. Moreover, the influence of the laser bea…
Large monolithic silica-based macrocellular foams with trimodal pore system.
2003
Silica-based materials with hierarchical pore systems at three different length scales (small mesopores–large mesopores–macropores) have been prepared through a nanotectonic approach by using mesoporous nanoparticles as building blocks; the resulting materials present a highly accessible foam-like architecture and can be prepared as large monoliths. Huerta Morillo, Lenin Jose, Lenin.Huerta@uv.es ; Latorre Saborit, Julio, Julio.Latorre@uv.es ; Beltran Porter, Aurelio, Aurelio.Beltran@uv.es ; Beltran Porter, Daniel, Daniel.Beltran@uv.es ; Amoros del Toro, Pedro Jose, Pedro.Amoros@uv.es
Extremely efficient evaluation of chromatic dispersion in realistic photonic crystal fibers
2004
We present a fast and accurate procedure for the evaluation of chromatic dispersion in photonic crystal fibers. It combines an iterative Fourier technique to compute the propagation constant at any fixed wavelength and an analytical approach to calculate its derivatives.
Plasmonic Core–Satellite Assemblies as Highly Sensitive Refractive Index Sensors
2015
Highly sensitive and spectrally tunable plasmonic nanostructures are of great demand for applications such as SERS and parallel biosensing. However, there is a lack of such nanostructures for the midvisible spectral regions as most available chemically stable nanostructures offer high sensitivity in the red to far red spectrum. In this work, we report the assembly of highly sensitive nanoparticle structures using a hydroxylamine mediated core–satellite assembly of 20 nm gold nanoparticle satellites onto 60 nm spherical gold cores. The average number of satellites allows tuning the plasmon resonance wavelength from 543 to 575 nm. The core–satellite nanostructures are stable in pH ranges from…
0.48Tb/s (12x40Gb/s) WDM transmission and high-quality thermo-optic switching in dielectric loaded plasmonics
2012
We demonstrate Wavelength Division Multiplexed (WDM)-enabled transmission of 480Gb/s aggregate data traffic (12x40Gb/s) as well as high-quality 1x2 thermo-optic tuning in Dielectric-Loaded Surface Plasmon Polariton Waveguides (DLSPPWs). The WDM transmission characteristics have been verified through BER measurements by exploiting the heterointegration of a 60 mu m-long straight DLSPPW on a Silicon-on-Insulator waveguide platform, showing error-free performance for six out of the twelve channels. High-quality thermo-optic tuning has been achieved by utilizing Cycloaliphatic-Acrylate-Polymer as an efficient thermo-optic polymer loading employed in a dual-resonator DLSPPW switching structure, …
Improved All-Fiber Acousto-Optic Tunable Bandpass Filter
2017
An all-fiber acousto-optic tunable bandpass filter based on a 1.185-mm long coreless core mode blocker is reported. Experimental results demonstrate a minimal insertion loss of 1.2 dB at the optical resonant wavelength of 1527.7 nm with 3-dB optical bandwidth of 0.83 nm. The optimization of the device takes into account the attenuation of the acoustic wave and leads to an asymmetric configuration in which the coupling section is shorter than the recoupling part. Under the effect of a standing flexural wave the device can be operated as a bandpass modulator. The device exhibits a maximum modulation depth of 28%, 4 dB of insertion loss and 0.97 nm of optical bandwidth at 4.774 MHz.
All-optical nonlinear processing of both polarization state and intensity profile for 40 Gbit/s regeneration applications
2011
International audience; In this paper, we report all-optical regeneration of the state of polarization of a 40-Gbit/s return-to-zero telecommunication signal as well as its temporal intensity profile and average power thanks to an easy-to-implement, all-fibered device. In particular, we experimentally demonstrate that it is possible to obtain simultaneously polarization stabilization and intensity profile regeneration of a degraded light beam thanks to the combined effects of counterpropagating four-wave mixing, self-phase modulation and normal chromatic dispersion taking place in a single segment of optical fiber. All-optical regeneration is confirmed by means of polarization and bit-error…
Group birefringence cancellation in highly birefringent photonic crystal fibre at telecommunication wavelengths
2010
International audience; The spectral dependence of the group modal birefringence in a highly birefringent nonlinear photonic crystal fibre is studied both numerically and experimentally. The sign inversion and the cancellation of the group modal birefringence in the telecommunication window is demonstrated. Two simple experimental techniques are used to evaluate the wavelength of zero polarisation mode dispersion. The experimental results are in excellent agreement with numerical calculations based on vectorial beam propagation method simulations.