Search results for "Linear"

Liquid/Liquid Demixing in the System n-Hexane/Narrowly Distributed Linear Polyethylene

2004

Demixing conditions were measured visually for solutions of three narrowly distributed polyethylene samples (M ranging from 6.5 to 380 kg/mol) in n-hexane up to 500 K and 150 bar. This information yields the critical line for infinite molar mass; i.e., it specifies the pT area within which one is safe from phase separation irrespective of the molar mass of the polymer and of the composition of the mixture. The experimental findings are in good qualitative agreement with the predictions of the Sanchez−Lacombe theory applied without any adjustable parameters. The influences of molar masses are, however, underestimated, and the resulting critical compositions are too small. For a more quantita…

Rheological properties and morphology in LLDPE and PC based blends

1990

Abstract During an interlaboratory project on polymer blends (Technical Working Party-Polymer Blends-VAMAS), the rheological characteristics of some samples of blends of polycarbonate with linear low density polyethylene have been evaluated with the aid of a capillary rheometer. Some morphological observations on the extruded samples have also been performed through SEM and an attempt has been made to correlate the macroscopic and microscopic results.

Nonlinear Transport in Hybrid Polypyrrole–Gold Nanostructures

2010

We have studied charge transport in nanometer scale films of polypyrrole (PPy) that were grown electrochemically onto discontinuous ultrathin films of gold. The gold films consisted of 100 nm size islands, separated from each other by nanometer-size gaps. The thickness of PPy can be varied from 30 to 200 nm. The I-V characteristics of these hybrid PPy-Au nanostructures show strong non-linearity at low temperatures, and in particular for the more insulating samples. The hopping transport is further verified from the log / versus V-1/4 plots. Furthermore, the I-V data follow an empirical relation dlog//dV(1/4) similar to T-1/2.

Acoustic modes in metallic nanoparticles: atomistic versus elasticity modeling

2009

The validity of the linear elasticity theory is examined at the nanometer scale by investigating the vibrational properties of silver and gold nanoparticles whose diameters range from about 1.5 to 4 nm. Comparing the vibration modes calculated by elasticity theory and atomistic simulation based on the Embedded Atom Method, we first show that the anisotropy of the stiffness tensor in elastic calculation is essential to ensure a good agreement between elastic and atomistic models. Second, we illustrate the reduction of the number of vibration modes due to the diminution of the number of atoms when reducing the nanoparticles size. Finally, we exhibit a breakdown of the frequency-spectra scalin…

On the Use of L-shaped Granular Chains for the Assessment of Thermal Stress in Slender Structures

2014

Slender beams subjected to compressive load are common in civil engineering. The rapid in-situ measurement of this stress may help preventing structural anomalies. In this article, we describe the coupling mechanism between highly nonlinear solitary waves (HNSWs) propagating along an L- shaped granular system and a beam in contact with the gran- ular medium. We evaluate the use of these waves to measure stress in thermally loaded structures and to estimate the neutral temperature, i.e. the temperature at which the stress is null. We investigate numerically and experimentally one and two L- shaped chains of spherical particles in contact with a prismatic beam subjected to heat. We find that …

Conservative averaging method for solving some nonlinear heat transfer problems related to combustion

2020

Seeded intermodal four-wave mixing in a highly multimode fiber

2018

International audience; We experimentally and theoretically investigate the process of seeded intermodal four-wave mixing in a graded-index multimode fiber, pumped in the normal dispersion regime. By using a fiber with a 100-mu m core diameter, we generate a parametric sideband in the C-band (1530-1565 nm), hence allowing the use of an erbium-based laser to seed the mixing process. To limit nonlinear coupling between the pump and the seed to low-order fiber modes, the waist diameter of the pump beam is properly adjusted. We observe that the superimposed seed stimulates the generation of new spectral sidebands. A detailed characterization of the spectral and spatial properties of these sideb…

Octave-spanning ultraflat supercontinuum with soft-glass photonic crystal fibers

2009

We theoretically identify some photonic-crystal-fiber structures, made up of soft glass, that generate ultrawide (over an octave) and very smooth supercontinuum spectra when illuminated with femtosecond pulsed light. The design of the fiber geometry in order to reach a nearly ultraflattened normal dispersion behavior is crucial to accomplish the above goal. Our numerical simulations reveal that these supercontinuum sources show high stability and no significant changes are detected even for fairly large variations of the incident pulse. Ministerio de Ciencia e Innovación (TEC2008-05490) and Generalitat Valenciana (GV/2007/043).

Investigation of ISIS and Brookhaven National Laboratory ion source electrodes after extended operation.

2012

Linac4 accelerator of Centre Européen de Recherches Nucléaires is under construction and a RFdriven H− ion source is being developed. The beam current requirement for Linac4 is very challenging: 80 mA must be provided. Cesiated plasma discharge ion sources such as Penning or magnetron sources are also potential candidates. Accelerator ion sources must achieve typical reliability figures of 95% and above. Investigating and understanding the underlying mechanisms involved with source failure or ageing is critical when selecting the ion source technology. Plasma discharge driven surface ion sources rely on molybdenum cathodes. Deformation of the cathode surfaces is visible after extended opera…

High-resolution deep view microscopy of cells and tissues

2020

Abstract Methods, experimental setups and perspectives of three-dimensional deep view imaging microscopy of cell or tissue samples are reported. Preliminary biophysical and clinically relevant examples are presented.