Search results for "Lithium"

Thermoluminescence study of irradiated lithium orthosilicate

1998

Abstract The thermoluminescental investigations of neutron and gamma irradiated lithium orthosilicate pellets were carried out. It has been shown that the addition of Cr 3+ and Fe 3+ ions with the total concentration up to 2.0 wt.% during preparation of lithium orthosilicate pellets, significantly reduces the formation of radiation defects in irradiated matrix. This phenomena can be explained by the reducing of the formation of primary radiation defects during irradiation due to stimulating the recombination processes by the ions of impurities. Several ion concentration combinations were studied. The thermoluminescental investigations of fast neutron irradiated lithium orthosilicate pellets…

Study of tritium and helium generation and release from lead-lithium eutectics Li15.7Pb under neutron irradiation

2019

Abstract This paper describes the experiments on study of tritium and helium generation and release processes from lead-lithium eutectics Li15.7Pb. The irradiation was performed at the IVG.1M research reactor at 6 MW of thermal power. The irradiation temperature increased step by step from 225 to 550 °C. A qualitative assessment of the experimental results showed that as the temperature rises above 390 °C, the tritium flux from the sample consisting of T2 and HT molecules decreases. It was concluded that the observed effect is similar to the previously observed one for lead-lithium eutectics with Li17Pb83 composition.

Nanostructured anode material for Li-ion batteries

2010

The present paper focuses on a nanostructured SnCo alloy electrochemically prepared by template method in view of its use as anode material alternative to graphite in lithium-ion batteries. The fabrication of SnCo nanowire arrays was carried out by potentiostatic co-deposition of the two metals by using nanostructured anodic alumina membranes as template. Electrochemical tests on lithiation-delithiation of these SnCo electrodes in conventional organic electrolyte (EC:DMC LiPF6) at 30°C showed that their specific capacity was stable for about the first 12 cycles at a value near to the theoretical one for Li22Sn5 and, hence, progressively decayed.

Optimization of spodumene identification by statistical approach for laser-induced breakdown spectroscopy data of lithium pegmatite ores

2021

Mapping with laser-induced breakdown spectroscopy (LIBS) can offer more than just the spatial distribution of elements: the rich spectral information also enables mineral recognition. In the present study, statistical approaches were used for the recognition of the spodumene from lithium pegmatite ores. A broad spectral range (280–820 nm) with multiple lines was first used to establish the methods based on vertex component analysis (VCA) and K-means and DBSCAN clusterings. However, with a view to potential on-site applications, the dimensions of the datasets must be reduced in order to accomplish fast analysis. Therefore, the capability of the methods in mineral identification was tested wi…

A Metallacryptand-Based Manganese(II)–Cobalt(II) Ferrimagnet with a Three-Dimensional Honeycomb Open-Framework Architecture

2008

Flash microwave synthesis of trevorite nanoparticles.

2008

Nickel ferrite nanoparticles have several possible applications as cathode materials for rechargeable batteries, named 'lithium-ion' batteries. In this study, NiFe{sub 2}O{sub 4} was prepared by microwave induced thermohydrolysis. The obtained nanoparticles were characterized by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), BET method, transmission electron microscopy (TEM) and small angle X-ray scattering (SAXS). All the results show that the microwave one-step flash synthesis leads in a very short time to NiFe{sub 2}O{sub 4} nanoparticles with elementary particles size close to 4-5 nm, and high specific surfaces (close to 240 m…

On the effect of stiffening plates configuration on the DEMO Water Cooled Lithium Lead Breeding Blanket module thermo-mechanical behaviour

2019

Abstract Within the framework of the pre-conceptual design of the EU-DEMO Breeding Blanket (BB) supported by EUROfusion action, results of the research activities carried out in the last years have highlighted that changes in the proposed Water Cooled Lithium Lead (WCLL) BB design have to be considered, especially as to the liquid breeder circulation path within the BB module. Therefore, in view of the definition of a final WCLL BB module layout, a parametric campaign of numerical analyses has been carried out at the University of Palermo in order to assess the impact of different SPs configurations on the module thermo-mechanical performances. To this purpose, attention has been focussed o…

Safety analysis of the DONES primary heat removal system

2020

Abstract The development of a neutron source able to reproduce the irradiation conditions typical of a nuclear fusion reactor, in order to test candidate structural materials, is the main goal of the Work Package Early Neutron Source (WPENS) of the EUROfusion action. This source, named Demo Oriented NEutron Source (DONES), is a facility where neutrons are produced by means of D-Li interactions. More in detail, a beam of 125 mA deuterium ions at the energy of 40 MeV strikes a lithium jet flowing in a purposely shaped channel in order to obtain an intense and stable neutron flux for the irradiation of material samples. In the framework of these activities, safety analyses are a key aspect in …

Lithium ion conducting PVdF-HFP composite gel electrolytes based on N-methoxyethyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)-imide ionic li…

2010

Blends of PVDF-HFP and ionic liquids (ILs) are interesting for application as electrolytes in plastic Li batteries. They combine the advantages of the gel polymer electrolytes (GPEs) swollen by conventional organic liquid electrolytes with the nonflammability, and high thermal and electrochemical stability of ILs. In this work we prepare and characterize PVDF-HFP composite membranes swollen with a solution of LiTFSI in ether-functionalized pyrrolidinium-imide (PYRA12O1). The membranes are filled in with two different types of silica: i) mesoporous SiO2 (SBA-15) and a commercial nano-size one (HiSilTM T700). The ionic conductivity and the electrochemical properties of the gel electrolytes ar…

On the Improved Current Pulse method for the thermal diffusive characterization of lithiated ceramic pebble beds

2012

Abstract Packed pebble beds are granular systems composed of small particles generally arranged in irregular lattices and surrounded by a gas filling their interstitial spaces. They show non-linear and coupled thermal and mechanical behaviours, which are under theoretical and experimental investigation to set-up a realistic constitutive model to be adopted for design-oriented purposes. At the Department of Nuclear Engineering (DIN) of the University of Palermo a realistic constitutive model of fusion-relevant pebble beds thermo-mechanical behaviour was developed adopting a “continuous” approach, based on the assumption that a pebble bed could be considered as a continuous, homogeneous and i…