Search results for "Lyme"

showing 10 items of 10624 documents

Solution and solid-state studies on the halide binding affinity of perfluorophenyl-armed uranyl–salophen receptors enhanced by anion–π Interactions

2016

The enhancement of the binding between halide anions and a Lewis acidic uranyl-salophen receptor has been achieved by the introduction of pendant electron- deficient arene units into the receptor skeleton. The association and the occurrence of the elusive anion-p interaction with halide anions (as tetrabutylammonium salts) have been demonstrated in solution and in the solid state, providing unambiguous evidence on the interplay of the concerted interactions responsible for the anion binding.

anion–π interactions; halides; host–guest systems; lewis acid–base interactions; uranyl–salophen; chemistry (all)Solid-stateHalide010402 general chemistry01 natural sciencesCatalysisIonUranyl salophenPolymer chemistryOrganic chemistryReceptorAnion bindingta116Uranyl-salphenlewis acid–base interactionsanion–π interactionsuranyl–salophen010405 organic chemistryChemistryOrganic Chemistryhost–guest systemsGeneral Chemistryinteractions0104 chemical sciencesuranyl-salophen receptorshalideschemistry (all)halide recognitionanions
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Induction of the peroxisome proliferator activated receptor by fenofibrate in rat liver

1992

AbstractThe process of peroxisome proliferation in rodent liver by hypolipidemic compounds and related substances has recently been shown to be receptor-madiated. In the present study, we have examined the effect of oral administration of the strong peroxisome proliferator fenofibrate on the hepatic expression level of the peroxisome proliferator activated receptor (PPAR) in rats. Immunoblots of rat liver cytosols and nuclear extracs using antibodies raised against recombinant PPAR/β-galactosidase fusion proteins revealed a pronounced increase in the amount of PPAR protein in response to fenofibrate treatment. This induction could also be confirmed at the level or RNA by Northern blotting. …

Male1303 BiochemistryReceptors Cytoplasmic and Nuclear10050 Institute of Pharmacology and ToxicologyPeroxisome proliferator-activated receptorPPARMicrobodiesPolymerase Chain ReactionBiochemistryPPAR agonist1307 Cell BiologyMiceCytosol1315 Structural BiologyFenofibrateStructural Biologychemistry.chemical_classificationMice Inbred BALB CFenofibrateOligodeoxyribonucleotidesPeroxisome proliferator-activated receptor alphaFusion proteinmedicine.drugmedicine.medical_specialtyPeroxisome proliferator-activated receptor gammamRNAMolecular Sequence DataBiophysicsPeroxisome ProliferationReceptors Cell Surface610 Medicine & healthBiology1311 GeneticsInternal medicine1312 Molecular BiologyGeneticsmedicineAnimalsNorthern blotMolecular BiologyAntibodyHypolipidemic compoundCell NucleusMessenger RNABase SequenceImmune SeraCell BiologyBlotting NorthernRatsMice Inbred C57BLEndocrinologychemistry570 Life sciences; biologyTranscription Factors1304 BiophysicsFEBS Letters
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Development of a real-time PCR assay for detection and quantification of enterotoxigenic members of Bacillus cereus group in food samples

2009

A highly sensitive real-time PCR (qPCR) procedure, targeting the phosphatidylcholine-specific phospholipase C gene (pc-plc), was developed for specific detection and quantification of strains belonging to Bacillus cereus group. The target region was selected based on the enterotoxigenic profiles of 75 Bacillus strains. The inclusivity and exclusivity of the RTi-PCR assay were assessed with 59 isolates of the B. cereus group, 16 other Bacillus spp., and 4 non-Bacillus strains. The assay was also used to construct calibration curves for different food matrices, and it had a wide quantification range of 6 log units using both serial dilutions of purified DNA and calibrated cell suspensions of …

DNA BacterialSerial dilutionEggsMolecular Sequence DataColony Count MicrobialBacillus cereusFood ContaminationPolymerase Chain ReactionSensitivity and SpecificityMicrobiologyMicrobiologyEnterotoxinsBacillus cereusSpecies SpecificityHumansFood microbiologyDetection limitBacillus (shape)ChromatographybiologyfungiInfant NewbornInfantReproducibility of ResultsSequence Analysis DNAGeneral Medicinebiology.organism_classificationBacillalesInfant FormulaCereusCalibrationFood MicrobiologyFood ScienceFood contaminantInternational Journal of Food Microbiology
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Calix[4]arene-functionalized naphthalene and perylene imide dyes.

2002

[reaction: see text] Calix[4]arenes bearing one, two, or four 1,8-naphthyl imide groups at the wide rim and bis-calix[4]arenes connected via perylene-bisimide dye spacers have been synthesized. The low-temperature NMR spectrum of the tetranaphthylimide suggests, in agreement with a crystal structure, a C2-symmetrical pinched cone conformation stabilized via face-to-face pi-pi interactions between opposite naphthylimide groups. UV-vis and fluorescence studies have been carried out for the perylene bis-calix[4]arene dyes.

Molecular StructureChemistryOrganic ChemistryCrystal structureNuclear magnetic resonance spectroscopyNaphthalenesPhotochemistryImidesBiochemistryFluorescencechemistry.chemical_compoundPhenolsPolymer chemistryCalixareneMoleculePhysical and Theoretical ChemistryCalixarenesImideColoring AgentsPerylenePeryleneNaphthaleneFluorescent DyesOrganic letters
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TI: Cyclophosphazenes as polymer modifiers

2003

The utilization of cyclophosphazenes as polymer modifiers is reviewed, with particular concern to their exploitation as versatile chain extenders, possibly for recycle problems, crosslinkers, to enhance mechanical properties of polymeric materials, branchers, to selectively introduce ramifications in linear polymers, and compatibilizers, to favor the formation of blends between originally incompatible organic macromolecules. The great versatility of the synthetic methods put forward for these substrates, together with the ease of controlling their modification, functionalization and reactivity are important parameters for the evaluation of which type of use is more feasible for these trimer…

chemistry.chemical_classificationchain-extender2-oxazolineMaterials sciencePolymers and PlasticsPolymer scienceLinear polymerOrganic ChemistryPolymerCondensed Matter Physicschemistry.chemical_compoundSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialichemistryMaterials ChemistrycyclophosphazeneepoxideSurface modificationOrganic chemistrycompatibilizerReactivity (chemistry)AzideMacromolecule
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Bypassing hazard of housekeeping genes: their evaluation in rat granule neurons treated with cerebrospinal fluid of multiple sclerosis subjects

2015

Gene expression studies employing real-time PCR has become an intrinsic part of biomedical research. Appropriate normalization of target gene transcript(s) based on stably expressed housekeeping genes is crucial in individual experimental conditions to obtain accurate results. In multiple sclerosis (MS), several gene expression studies have been undertaken, however, the suitability of housekeeping genes to express stably in this disease is not yet explored. Recent research suggests that their expression level may vary under different experimental conditions. Hence it is indispensible to evaluate their expression stability to accurately normalize target gene transcripts. The present study ai…

GeneticsBeta-2 microglobulinbusiness.industryMultiple sclerosishousekeeping genesNormFinderTransferrin receptorComputational biologymedicine.diseasemultiple sclerosislcsh:RC321-571Housekeeping geneGeNormCellular and Molecular NeuroscienceReal-time polymerase chain reactionnormalizationReference genesGene expressionmedicinebusinesslcsh:Neurosciences. Biological psychiatry. NeuropsychiatryGeneOriginal ResearchNeuroscience
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Micro- to Nanoscale Bio-Hybrid Hydrogels Engineered by Ionizing Radiation

2021

Bio-hybrid hydrogels consist of a water-swollen hydrophilic polymer network encapsulating or conjugating single biomolecules, or larger and more complex biological constructs like whole cells. By modulating at least one dimension of the hydrogel system at the micro- or nanoscale, the activity of the biological component can be extremely upgraded with clear advantages for the development of therapeutic or diagnostic micro- and nano-devices. Gamma or e-beam irradiation of polymers allow a good control of the chemistry at the micro-/nanoscale with minimal recourse to toxic reactants and solvents. Another potential advantage is to obtain simultaneous sterilization when the absorbed doses are wi…

Materials sciencePolymerslcsh:QR1-502Nanotechnology02 engineering and technologyReview010402 general chemistry01 natural sciencesBiochemistrylcsh:MicrobiologyIonizing radiationradiation chemistrymicro-/nano-gel patternsHydrophilic polymersnanogelsTissue engineeringRadiation Ionizingradiation chemistry; micro-/nano-gel patterns; nanogels; bio-hybrid hydrogels; drug delivery; tissue engineeringMolecular BiologyNanoscopic scalechemistry.chemical_classificationBiomoleculeHydrogelsPolymer021001 nanoscience & nanotechnology0104 chemical scienceschemistrytissue engineeringSelf-healing hydrogelsDrug deliverydrug deliveryNanoparticlesbio-hybrid hydrogelsSettore CHIM/07 - Fondamenti Chimici Delle Tecnologie0210 nano-technology
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Comparative Investigation on the Soil Burial Degradation Behaviour of Polymer Films for Agriculture before and after Photo-Oxidation

2020

Polymer films based on biodegradable polymers, polyethylene (PE) and modified PE with oxo-degradable additive were prepared by film blowing. Carbon black (1%) was added to all the films. Commercial biodegradable Ecovio&reg

polyethyleneEcovio<sup>®</sup>Materials sciencemulch filmsPolymers and Plasticspolymer degradation02 engineering and technologyMater-Bi<sup>®</sup>010402 general chemistry01 natural sciencesArticlelcsh:QD241-441chemistry.chemical_compoundPolymer degradationlcsh:Organic chemistrySoil retrogression and degradationbiodegradable polymers; mulch films; soil burial test; Ecovio®; Mater-Bi®; polylactide; poly(butyleneadipate-co-butyleneterephtalate); polyethylene; polymer degradation; photooxidationchemistry.chemical_classificationsoil burial testGeneral ChemistryPolymerCarbon blackPolyethyleneBiodegradation021001 nanoscience & nanotechnologyBiodegradable polymerphoto-oxidation0104 chemical sciencesSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialichemistryChemical engineeringbiodegradable polymerspolylactidepoly(butyleneadipate-<i>co</i>-butyleneterephtalate)Biodegradable polymers Ecovio® Mater-Bi® Mulch films Photo-oxidation Poly(butyleneadipate-co-butyleneterephtalate) Polyethylene Polylactide Polymer degradation Soil burial testDegradation (geology)Ecovio®poly(butyleneadipate-co-butyleneterephtalate)0210 nano-technologyMater-Bi®Polymers
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Conformations and orientational ordering of semiflexible polymers in spherical confinement.

2017

Semiflexible polymers in lyotropic solution confined inside spherical nanoscopic “containers” with repulsive walls are studied by molecular dynamics simulations and density functional theory, as a first step to model confinement effects on stiff polymers inside of miniemulsions, vesicles, and cells. It is shown that the depletion effects caused by the monomer-wall repulsion depend distinctly on the radius R of the sphere. Further, nontrivial orientational effects occur when R, the persistence length ℓp, and the contour length L of the polymers are of similar magnitude. At intermediate densities, a “shell” of wall-attached chains is forming, such that the monomers belonging to those chains a…

Persistence lengthchemistry.chemical_classificationQuantitative Biology::BiomoleculesMaterials scienceShell (structure)General Physics and Astronomy02 engineering and technologyRadiusPolymer021001 nanoscience & nanotechnology01 natural sciencesCondensed Matter::Soft Condensed MatterMolecular dynamicschemistry.chemical_compoundCrystallographyARTICLESMonomerchemistryChemical physics0103 physical sciencesLyotropicDensity functional theoryPhysical and Theoretical Chemistry010306 general physics0210 nano-technologyThe Journal of chemical physics
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Thermal Analysis, Mechanical and Rheological Behaviour of Melt Manufactured Polyethylene/Liquid Crystal Polymer Blends

2011

Modification of properties of conventional thermoplastics with thermotropic liquid crystal polymers, from one hand, allows decrease their viscosities, substantially facilitating processing conditions, and, from another hand, allows increase their exploitation properties. Orientation of the labile structure of liquid crystal polymer in extrusion or injection moulding causes specific reinforcement (so-called self-reinforcement) to occur in the blends containing liquid crystal polymer. Up to now the effect of self-reinforcement is mostly investigated in the blends, containing considerable amount of liquid crystal polymer. In this research the effect of minor amounts of liquid crystalline co-po…

chemistry.chemical_classificationpolyethylenelcsh:TN1-997Hydroxybenzoic acidMaterials scienceThermoplasticthermotropic liquid crystalline polymersynthesisPolymerPolyethyleneThermotropic crystalchemistry.chemical_compoundrheological propertieschemistryLiquid crystalUltimate tensile strengthGeneral Materials ScienceInjection mouldingstructuremechanicalComposite materiallcsh:Mining engineering. MetallurgyMedžiagotyra
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