Search results for "Lytic"

showing 10 items of 11146 documents

Determination of mercury at picogram level in natural waters with inductively coupled plasma mass spectrometry by using 3D printed metal scavengers

2019

The determination of ultra-trace concentrations of Hg in natural water samples via preconcentration using 3D printed metal scavenger technique followed by inductively coupled plasma mass spectrometry (ICP-MS) was developed. The determination of Hg in certified reference material ERM-CA615 (groundwater) was performed with high accuracy and precision resulting in recovery of 100 ± 3% and RSD <2.5%, respectively. Selective laser sintering (SLS) 3D printing was used to fabricate the scavengers using a mixture of polyamide-12 powder with thiol-functionalized silica. The preconcentration procedure is based on the adsorption of Hg on the scavenger and followed by elution of the preconcentrated Hg …

3d printedmercuryelohopeavesichemistry.chemical_element02 engineering and technology01 natural sciencesBiochemistryAnalytical ChemistryMetalpreconcentration3D-tulostushaitalliset aineetEnvironmental Chemistryinductively coupled plasma mass spectrometryInductively coupled plasma mass spectrometrySpectroscopyvesistötNatural waterultra-trace concentration010401 analytical chemistry3D printing021001 nanoscience & nanotechnology0104 chemical sciencesMercury (element)spektrometriaCertified reference materialschemistryEnvironmental chemistryvisual_artvisual_art.visual_art_mediumnatural water0210 nano-technologyGroundwaterAnalytica Chimica Acta
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Estimation of the committed radiation dose resulting from gamma radionuclides ingested with food

2014

The objective of the study was to estimate the value of the radiation dose absorbed in consequence of consumption of popular food products for individual age groups. Potatoes, corn and sugar beet were selected for the study. Edible parts of these plants were collected in experimental fields of the KWS Lochow Polska Sp. z o.o. seeding company in Kondratowice (Poland). On the basis of the obtained study results, it can be stated that in consequence of consumption of the selected food products, people may receive increased doses from both natural and artificial radioactive isotopes. The doses calculated for several age groups do not show any health hazards in consequence of consumption of the …

40K137CsHealth Toxicology and MutagenesisArticleAnalytical ChemistryInorganic ChemistryToxicologyAge groupsRadiology Nuclear Medicine and imagingSpectroscopyRadionuclidebiologybusiness.industryEffective weighted doseRadiation dosedigestive oral and skin physiologyPublic Health Environmental and Occupational Healthfood and beveragesbiology.organism_classificationPollutionNuclear Energy and EngineeringFoodFood productsAbsorbed doseEnvironmental scienceSugar beetNuclear medicinebusinessJournal of Radioanalytical and Nuclear Chemistry
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Enabling Sociability When Using Virtual Reality Applications : A Design Science Research Approach

2019

Immersive virtual reality applications aim at providing an all-encompassing spatial experience where a user can feel like being in another world or dimension. The systems are inherently designed for individual use as the devices disconnect the user from the physical environment. However, the applications are seldom used alone. Specifically, when used for sales and marketing, the user often needs help from other people but also benefits from social interaction as a part of the experience. Design research methodology is applied to three iterative development versions of a virtual-reality application. The focus of the evaluation of the artifacts is in the social use emphasizing three sociabili…

4112 ForestryCustomer experienceEngineeringdigital servicespalvelutbusiness.industrydesign scienceeducationpäätöksentekoDesign scienceVirtual realitydigitalizationvirtuaalitodellisuusasiakkaattäydennetty todellisuusHuman–computer interactionmobiilipalvelutdecision analyticsDesign science research512 Business and Managementkäyttäjäkokemusbusinessdigitalisaatiolisätty todellisuus
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Magnetic dichroism in angle-resolved hard x-ray photoemission from buried layers

2011

This work reports the measurement of magnetic dichroism in angular-resolved photoemission from in-plane magnetized buried thin films. The high bulk sensitivity of hard x-ray photoelectron spectroscopy (HAXPES) in combination with circularly polarized radiation enables the investigation of the magnetic properties of buried layers. HAXPES experiments with an excitation energy of 8 keV were performed on exchange-biased magnetic layers covered by thin oxide films. Two types of structures were investigated with the IrMn exchange-biasing layer either above or below the ferromagnetic layer: one with a CoFe layer on top and another with a Co${}_{2}$FeAl layer buried beneath the IrMn layer. A pronou…

420Materials scienceMagnetic momentCondensed matter physicsAnalytical chemistryDichroismengineering.materialCondensed Matter PhysicsHeusler compoundElectronic Optical and Magnetic Materialscircularly polarized x-raysCondensed Matter::Materials ScienceX-ray photoelectron spectroscopyFerromagnetismX-ray magnetic circular dichroismmagnetic dichroismangular-resolved hard x-ray photoemissionengineeringThin filmExcitationPhysical Review B
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Preparation of polycrystalline TiO2 photocatalysts impregnated with various transition metal ions : characterization and photocatalytic activity for …

2002

A set of polycrystalline TiO2 photocatalysts loaded with various ions of transition metals (Co, Cr, Cu, Fe, Mo, V, and W) were prepared by using the wet impregnation method. The samples were characterized by using some bulk and surface techniques, namely X-ray diffraction, BET specific surface area determination, scanning electron microscopy, point of zero charge determination, and femtosecond pump-probe diffuse reflectance spectroscopy (PP-DRS). The samples were employed as catalysts for 4-nitrophenol photodegradation in aqueous suspension, used as a probe reaction. The characterization results have confirmed the difficulty to find a straightforward correlation between photoactivity and si…

431Materials scienceDiffuse reflectance infrared fourier transformScanning electron microscopeAnalytical chemistry436Surfaces Coatings and FilmsTransition metalSpecific surface areaMaterials ChemistryPoint of zero chargeCrystalliteDiffuse reflectionPhysical and Theoretical ChemistryPhotodegradationJournal of physical chemistry. B
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Effect of high temperature annealing (T > 1650 °C) on the morphological and electrical properties of p-type implanted 4H-SiC layers

2019

This work reports on the effect of high temperature annealing on the electrical properties of p-type implanted 4H-SiC. Ion implantations of Aluminum (Al) at different energies (30-200 keV) were carried out to achieve 300 nm thick acceptor box profiles with a concentration of about 10(20) at/cm(3). The implanted samples were annealed at high temperatures (1675-1825 degrees C). Morphological analyses of the annealed samples revealed only a slight increase of the surface roughness RMS up to 1775 degrees C, while this increase becomes more significant at 1825 degrees C (RMS = 1.2 nm). Room temperature Hall measurements resulted in a hole concentration in the range 0.65-1.34 x 10(18)/cm(3) and m…

4H-SiCMaterials scienceFabricationAnnealing (metallurgy)Analytical chemistrychemistry.chemical_element02 engineering and technologyActivation energy01 natural sciencesIonAluminium0103 physical sciencesSurface roughnessGeneral Materials ScienceElectrical measurements010302 applied physicsCondensed Matter - Materials ScienceMechanical EngineeringPhysics - Applied Physics021001 nanoscience & nanotechnologyCondensed Matter PhysicsAcceptorPost implantation annealingchemistryMechanics of MaterialsElectrical activationp-type implantation0210 nano-technologyMaterials Science in Semiconductor Processing
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Varying chiral ratio of Pinic acid enantiomers above the Amazon rainforest

2023

Chiral chemodiversity plays a crucial role in biochemical processes such as insect and plant communication. However, the vast majority of organic aerosol studies do not distinguish between enantiomeric compounds in the particle phase. Here we report chirally specified measurements of secondary organic aerosol (SOA) at the Amazon Tall Tower Observatory (ATTO) at different altitudes during three measurement campaigns at different seasons. Analysis of filter samples by liquid chromatography coupled to mass spectrometry (LC-MS) has shown that the chiral ratio of pinic acid (C9H14O4) varies with increasing height above the canopy. A similar trend was recently observed for the gas-phase precursor…

540 Chemistry and allied sciencesAtmospheric ScienceChemistryPhase (matter)540 ChemieAnalytical chemistryParticleMoleculeDegradation (geology)ParticulatesEnantiomerMass spectrometryAerosol
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Halogen activation in the plume of Masaya volcano: field observations and box model investigations

2020

Volcanic emissions are a source of halogens in the atmosphere. Rapid reactions convert the initially emitted hydrogen halides (HCl, HBr, and HI) into reactive species such as BrO, Br2, BrCl, ClO, OClO, and IO. The activation reaction mechanisms in the plume consume ozone (O3), which is entrained by ambient air that is mixed into the plume. In this study, we present observations of the oxidation of bromine, chlorine, and iodine during the first 11 min following emission, examining the plume from Santiago crater of the Masaya volcano in Nicaragua. Two field campaigns were conducted: one in July 2016 and one in September 2016. The sum of the reactive species of each halogen was determined by g…

540 Chemistry and allied sciencesOzoneBromine010504 meteorology & atmospheric sciencesHydrogenAnalytical chemistrychemistry.chemical_element01 natural scienceslcsh:QC1-999550 GeowissenschaftenPlumelcsh:Chemistrychemistry.chemical_compoundchemistryImpact craterlcsh:QD1-999550 Earth sciences540 ChemieHalogenChlorineEnvironmental scienceNOxlcsh:Physics0105 earth and related environmental sciences
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The maximum carbonyl ratio (MCR) as a new index for the structural classification of secondary organic aerosol components

2021

RATIONALE Organic aerosols (OA) account for a large fraction of atmospheric fine particulate matter and thus are affecting climate and public health. Elucidation of the chemical composition of OA is the key for addressing the role of ambient fine particles at the atmosphere-biosphere interface and mass spectrometry is the main method to achieve this goal. METHODS High-resolution mass spectrometry (HRMS) is on its way to becoming one of the most prominent analytical techniques, also for the analysis of atmospheric aerosols. The combination of high mass resolution and accurate mass determination allows the elemental compositions of numerous compounds to be easily elucidated. Here a new parame…

540 Chemistry and allied sciencesResolution (mass spectrometry)Chemistry010401 analytical chemistryOrganic ChemistryAnalytical chemistryFraction (chemistry)Structural classificationParticulatesOrbitrapMass spectrometry01 natural sciences0104 chemical sciencesAnalytical ChemistryAerosollaw.inventionlaw540 ChemieChemical compositionSpectroscopyRapid Communications in Mass Spectrometry
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Treatment of a stage III rima glottidis patient with the oncolytic virus Rigvir: A retrospective case report: Erratum.

2019

Abstract Rationale: Of all the parts of the larynx, the glottis has the highest frequency of cancer. With disease progression, the vocal cord movement is affected and for advanced stages its anatomical and functional preservation is rarely achievable, if at all. Patient concerns: Here we describe a 72-year-old patient who presented with hoarseness for a year and was only able to whisper. Diagnosis: A computed tomography (CT) scan of the vocal cords (without contrast) showed higher density tissue. Histological examination disclosed a well-differentiated verrucous squamous cell carcinoma of the glottis. Interventions: The patient was treated with the oncolytic ECHO-7 virus Rigvir without any …

5700Rigvirlaryngeal cancerglottisClinical Case ReportECHO-7 virusResearch Articleoncolytic virusMedicine
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