Search results for "MINERALOGY"
showing 10 items of 1516 documents
Excitonic luminescence in ZnO nanopowders and ceramics
2009
Abstract Fast photoluminescence spectra in the spectral region of 3.1–3.45 eV in ZnO and ZnO:Al ceramics were studied at 14 and 300 K. Ceramics with grains smaller than 100 nm were sintered from nanopowders by high pressure (8 GPa) and low temperature (350 °C). Ceramics with grain sizes 1–5 μm were sintered at 1400 °C. It is shown that excitonic luminescence spectra depend on the ceramics grain size, post preparing annealing and doping. The excitonic luminescence decay time was faster than 2 ns and the afterglow at 30 ns was ∼0.05%.
The time-resolved luminescence characteristics of Ce and Ce/Pr doped YAG ceramics obtained by high pressure technique
2012
Abstract Transparent Ce and Ce/Pr doped YAG ceramics were prepared under high pressures (up to 8 GPa) and relative low temperature (450 °C). Grain size of the ceramics is less than 50 nm. However unknown defects or disorders strains on grain boundaries caused the additional absorption in these ceramics. The luminescence intensity, spectra and the decay time dependence on pressure applied during ceramic preparation were studied. Concentration of some intrinsic point defect was reduced under the high pressure applied for sintering process. It is shown that formation time of the excited state of Ce luminescence depends on the pressure applied during ceramic sintering.
Cathodoluminescence and photoluminescence study of plastically deformed ZnTe bulk single crystals
2001
Samples of zinc telluride bulk single crystals, which were deformed in uniaxial compression, have been studied by photoluminescence (PL) and cathodoluminescence (CL). As a particular feature the deformed samples present a PL emission band peaked at 603 nm, whose intensity increases as the plastic deformation does. This band is related to the density of dislocations produced during the interaction of slip systems. This hypothesis is supported by CL images. which reveal the activation of the successive slip systems corresponding to different levels of deformation.
Comment on: Application of Raman Spectroscopy to Distinguish Metamorphic and Igneous Zircon (Xian et al., Anal. Lett. 2004, v. 37, p. 119)
2005
Abstract We critically discuss a recently proposed technique ((Xian et al. 2004)) used to distinguish igneous (i.e., magmatic) from metamorphic growth of the mineral zircon according to the intensity of the 1461 cm−1 band observed in those author's Raman spectra. The band evaluated by Xian et al. (2004) is actually due to laser‐induced photoluminescence of trace amounts of the trivalent rare earth element Er, which, as an analytical artefact, overlays the Raman spectrum when green Ar+ laser excitation is used. We demonstrate that this band is not a Raman band, and discuss why the intensity of Er3+ luminescence is not uniquely indicative of the geologic origin of a zircon crystal. The techni…
Luminescence of fluorine doped silica glass
2003
Abstract The role of fluorine doping on silica properties was studied by luminescence methods. Non-doped samples of the same preparation technology possess an absorption band at 7.6 eV on the level of 2 cm−1. A trace of this band in the fluorine-doped sample is on the level of 0.1 cm−1. In both samples 7.6 eV photons as well as ionizing irradiation (X-ray, electron beam) excite photoluminescence of so-called oxygen deficient centers with a blue (2.7 eV) and a UV band (4.4 eV). The luminescence of the fluorine doped sample increases with dose many times from the initial low level for the same excitation. Also, thermally stimulated luminescence appears after irradiation. The energetic yield u…
Photostimulable energy transfer in doped nanostructures of alkali halides
1998
Abstract In nanostructures of doped alkali halides, unrelaxed H-centres produced in the exciton decay are able to escape from the surface thus producing in the grains of polycrystalline film an excess concentration of F-centres, which has a great tendency to form an interacting F-centre chain or a canal. Role of this F-centre chain in photostimulable energy transfer is analysed. It is concluded that specific interaction of unrelaxed H-centres and electrons with the F-centre chain (or the canal) leads to the temperature-independent exciton or electron transport at any distance. Hence, the temperatureindependent photostimulated luminescence (PSL) response production and retrieval are experime…
Sedimentation and Fouling of Optical Surfaces at the ANTARES Site
2003
ANTARES is a project leading towards the construction and deployment of a neutrino telescope in the deep Mediterranean Sea. The telescope will use an array of photomultiplier tubes to detect the Cherenkov light emitted by muons resulting from the interaction with matter of high energy neutrinos. In the vicinity of the deployment site the ANTARES collaboration has performed a series of in-situ measurements to study the change in light transmission through glass surfaces during immersions of several months. The average loss of light transmission is estimated to be only ~2% at the equator of a glass sphere one year after deployment. It decreases with increasing zenith angle, and tends to satur…
Blue Moon: Is This a Property of Background Aerosol?
2010
Stellar extinction measurements made at three astronomical observatories showed that on ~50% of the nights the extinction due to aerosol light scattering increased rather than decreased with increasing wavelength (anomalous extinction) for wavelengths close to 500 nm. This extinction behavior is analyzed in this paper and limits are established for the aerosol characteristics necessary for this phenomenon to exist, including geometric standard deviations, imaginary part of refractive index, mean radius, and gaseous NO(2).
The First Precise Determination of an Optical–Far‐Ultraviolet Extinction Curve Beyond the Local Group ( \documentclass{aastex} \usepackage{amsbsy} \u…
2005
We present the optical-far-ultraviolet extinction curve of the dust in the lens galaxy of the gravitational lens system SBS 0909+532 (z = 0.83). Extending our previous optical-UV estimate (from λ ~ 2 to 5 μm-1) into the far ultraviolet (from λ ~ 5 to 8 μm-1) is crucial for comparing with the extinction curves measured for Local Group galaxies in the spectral region where the differences are greatest. The SBS 0909+532 curve is similar to that of the LMC2 supershell, with a weaker 2175 A feature and a steeper rise into the UV than that observed in the Milky Way. The shapes of the extinction curve inferred from the quasar continuum and emission lines are in very good agreement. There is, howev…
Sensitivity of UVER enhancement to broken liquid water clouds: A Monte Carlo approach
2016
The study uses a Monte Carlo radiative transfer model to examine the sensitivity of the UV erythemal radiation (UVER) enhancement to broken liquid water clouds of the cumulus and stratocumulus type. The model uses monochromatic radiation at 310 nm corresponding approximately to the peak of the product between irradiance and the erythemal curve. All scattering, absorption, extinction coefficients, and spectral albedos are tuned to this wavelength. In order of importance, fractional cloud cover, the area of individual cloud patches, and cloud thickness exert a strong influence on the enhancement, with smaller contributions from cloud optical depth, cloud base height, and solar zenith angle. I…