Search results for "MINERALOGY"

Goldschmidt Abstracts 2010 – F

2010

We report on two novel procedures for the determination of several trace elements in seawater, including elements characterized by very low abundance (sub-0.1 to 1 ng l-1) in the ocean, such as REEs, Hf, and Th. Our methods are based on the procedure developed recently by Bayon et al. [1], and applied successfully to a wide range of geological samples. It involves addition of a Tm spike and pre-concentration using co-precipitation, prior to analysis by inductively coupled plasma-sector field mass spectrometry (ICP-SFMS). The addition of a small amount of Tm to the sample produces a positive Tm anomaly in the resulting REE pattern, which allows calculation of precise trace element concentrat…

On aperiodic trace languages

2005

Origin of SiO2-rich components in ordinary chondrites

2006

Abstract Silica-rich objects are common minor components in ordinary chondrites (OC), occurring as fragments and as chondrules. Their typical paragenesis is orthopyroxene + SiO 2 (with bulk SiO 2 >65 wt%) and occasionally with additional olivine and/or spinel. Individual silica-rich components (SRC) have previously been studied in various types of OCs, although there is only one comprehensive study of these objects by Brigham et al. [Brigham, C.A., Murrell, M.T., Yabuki, H., Ouyang, Z., El Goresy, A., 1986. Silica-bearing chondrules and clasts in ordinary chondrites. Geochim. Cosmochim. Acta 50, 1655–1666]. Several different explanations of how SRCs formed have been published. The main ques…

Compressibility and phase stability of iron-rich ankerite

2021

ABSTRACT: The structure of the naturally occurring, iron-rich mineral Ca₁․₀₈(₆)Mg₀.₂₄(₂)Fe₀.₆₄(₄)Mn₀.₆₄(₄)(CO₃)₂ ankerite was studied in a joint experimental and computational study. Synchrotron X-ray powder diffraction measurements up to 20 GPa were complemented by density functional theory calculations. The rhombohedral ankerite structure is stable under compression up to 12 GPa. A third-order Birch-Murnaghan equation of state yields V₀ = 328.2(3) ų, bulk modulus B₀ = 89(4) GPa, and its first-pressure derivative B'₀ = 5.3(8)-values which are in good agreement with those obtained in our calculations for an ideal CaFe(CO₃)₂ ankerite composition. At 12 GPa, the iron-rich ankerite structure …

Column-integrated aerosol optical properties in the free troposphere: case study-Sierra Nevada, Spain

2004

From spectral solar irradiance extinction measurements in the visible range carried out at Sierra Nevada (2950 m a.s.l.) during July 1998, the characteristics of the aerosol column in the free troposphere have been measured. The results show that in stable atmospheric conditions, the column-integrated aerosol takes an optical depth (AOD) at 500 nm of 0.02 /spl plusmn/ 0.02, and an average radius in the accumulation mode of 0.15 /spl mu/m, with a likely Atlantic origin. In unstable situations, the AOD at 500 nm can increase by more than an order of magnitude, and the aerosols' origin is uncertain, since air masses can arrive from different sources at different altitudes.

Dolomitization as an eventualdetermining factor in the colour alteration index (CAI)

1993

Abstract The Colour Alteration Index of conodonts (CAI) is indicative of the degree of alteration of organic material that exists in the interior of the conodonts. This CAI is used ordinarily in the determination of paleotemperatures. More frequent findings of abnormally high CAI values, equivalent to paleotemperatures that are not compatible with temperatures obtained by other more trustworthy methods, has taken us to use values not superior to 6 for the establishment of paleotemperatures. The CAI values measured in specimens proceding from dolostones in the Iberian Range (Spain) show in this way a certain degree of incompatibility with geological data. These anomalous values are the conse…

[Fe(sal2-trien)][Ni(dmit)2]: towards switchable spin crossover molecular conductors

2004

A cooperative spin transition behaviour with a wide hysteresis loop (30 K) around 240 K has been observed, for the first time, in a salt based on the redox active [Ni(dmit)2]¯, anion and the [Fe(sal2-trien)]+ spin crossover cation. Real Cabezos, Jose Antonio, Jose.A.Real@uv.es

Coexistence of ferro- and antiferromagnetic interactions in a metal-organic radical-based (6,3)-helical network with large channels.

2005

A metal–organic open-framework with an unprecedented (6,3)-helical topology, large channels and mixed ferro- and antiferromagnetic interactions has been synthesized using a three-connecting tricarboxylic polychlorotriphenylmethyl radical and Co(II) ions. Lloret Pastor, Francisco, Francisco.Lloret@uv.es

Amorphous calcium carbonate in the shells of adult Unionoida

2011

Shells of adult individuals from two different bivalve families, Hyriopsis cumingii and Diplodon chilensis patagonicus, were studied by Micro-Raman spectroscopy and Focussed Ion Beam-assisted TEM. The shells contain amorphous calcium carbonate in a zone at the interface between the periostracum and the prismatic layer. In this area, the initial prism structures protrude from the inner periostracum layer and it is demonstrated that these structures systematically consist of highly disordered and amorphous calcium carbonate. Within this zone, ordered and disordered areas are intermingled discounting the existence of a crystallization front and favouring models of domainal crystallization proc…

The role of pedogenic overprinting in the obliteration of parent material in some polygenetic landscapes of Sicily (Italy)

2016

Abstract Many soils older than the Holocene have experienced several changes, and possess properties that may be due to the complex effect of several stages of soil development; these soils are called polygenetic. It is still rather unclear, however, if, as time elapses, pedogenic processes tend to diverge generating different soils, or converge towards increasingly similar soils. We studied five pedons (37°60′N, 13°90′E) exposed to present weathering simultaneously since the Holocene but located on Upper Miocene or Holocene parent material. Their XRD and FTIR clay mineralogy reveal an overall homogeneity; smectites, calcite and gypsum reach the thermodynamic equilibrium, a slight undersatu…